The invention relates to a non-aqueous coating composition comprising a. a polyisocyanate, b. a polyol having an average functionality of more than 3 hydroxyl groups per molecule, c. a metal based curing catalyst for the addition reaction of isocyanate groups and hydroxyl groups, and d. a mercapto carboxylic acid,
wherein the coating composition does not contain a carboxylic acid wherein the carbonyl group of the carboxylic acid is in conjugation with a π-electron system.

A method of three-dimensional stereolithography printing a thiourethane polymer part using the vat resin. Adding a resin to a vat of a three-dimensional stereolithography printer, the resin a liquid mixture including: a first type of monomer including two or more thiol functional groups, a second type of monomer including two or more isocyanate functional groups, a photolatent base, an anionic step-growth polymerization reaction inhibitor and a light absorber. The photolatent base is decomposable upon exposure to a light to form a non-nucleophillic base catalyst having a pKa greater than 7. The anionic step-growth polymerization reaction inhibitor has an acidic group configured to form an acid-base pair with the non-nucleophillic base. The light absorber has an absorbance in the liquid mixture that is greater than an absorbance of the photolatent base at a wavelength of the light used for the exposure.

An adhesive film for surface protection and an optical member including the same are provided. An adhesive film for surface protection is formed of a composition for adhesive films including a curable component including a urethane-based binder, a curing agent, and a plasticizer, and has a peel strength variation rate of −50% to 20%, as calculated by Equation 1.

The present invention encompasses polyurethane adhesive compositions comprising aliphatic polycarbonate chains. In one aspect, the present invention encompasses polyurethane adhesives derived from aliphatic polycarbonate polyols and polyisocyanates wherein the polyol chains contain a primary repeating unit having a structure:. In another aspect, the invention provides articles comprising the inventive polyurethane compositions as well as methods of making such compositions.

The invention relates to a non-aqueous coating composition comprising a. a polyisocyanate, b. a polyol having an average functionality of more than 3 hydroxyl groups per molecule, c. a metal based curing catalyst for the addition reaction of isocyanate groups and hydroxyl groups, and d. a mercapto carboxylic acid, wherein the coating composition does not contain a carboxylic acid wherein the carbonyl group of the carboxylic acid is in conjugation with π-electron system.

Described herein is a coating material system which includes components (A) to (C) and (K) and also, optionally, further components, where all components (A) to (C) and (K) and also, where present, the further optional components are present separately from one another or are mixed wholly or at least partly with one another.

Component (A) includes at least one polyhydroxy group-containing compound, where the polyhydroxy group-containing compound of component (A) has an acid number of between 0 and 30 mg KOH/g, and component (B) includes at least one polyisocyanate-containing compound. Component (C) is a catalyst including bismuth (Bi) as metal component and at least one further metal component such as lithium (Li). Component (K) is at least one mercapto group-containing compound. Further components which may be present in the coating material system include, for example, hydroxyl-containing compounds (D), coating additives (F), pigments (H) and/or solvents (J).

There is provided a method for preparing a polyisocyanate composition capable of improving transparency of a product, by mixing a phenol-based stabilizer in an amount of 1 to 1000 ppmw, based on the total weight of aromatic diisocynate, and then, introducing polyhydric alcohol to conduct a polymerization reaction, thereby inhibiting coloration and whitening due to oxygen or moisture during synthesis and purification processes.

The invention relates to compounds and methods for extending the pot life of mixtures of isocyanates and isocyanate-reactive compounds when using acidic phosphoric acid ester as a mould release agent.

The present invention relates to a method that includes providing a formulation having an isocyanate-functional prepolymer and a curing component comprising an amino-functional aspartic ester of the general formula (I) ##STR00001##
applying the formulation to a cell tissue; and curing the formulation such that the loss of blood (haemostatic) or tissue fluids is staunched or leaks in cell tissues are sealed.

The present disclosure provides a liquid-state reactive polyurethane adhesive, which includes a polyurethane prepolymer. The polyurethane prepolymer is blocked by an isocyanate group, and the polyurethane prepolymer is obtained by a polymerization reaction, a reactive monomer of the polymerization reaction includes a polyisocyanate, a polyol, a stabilizer, a catalyst and a hydrophobic filler. A functionality of the polyisocyanate is 2.4 to 3. A molecular weight of the polyol is 1000 to 8000, and the polyol has hydrolysis resistance. The stabilizer has a structure represented by formula (I). The catalyst has a structure represented by formula (II). Formula (I) and formula (II) are as defined in the specification.