A coated article is disclosed that includes a metal substrate and a coating composition disposed on at least a portion of the metal substrate. The coating can be formed from a composition that includes an acrylic copolymer, which is preferably the reaction product of ethylenically unsaturated monomers and a functional monomer. The functional monomer can be the reaction product of a multifunctional isocyanate and an ethylenically unsaturated nucleophilic monomer. The functional monomer preferably includes a blocked isocyanate group. The articles can be useful for packaging foods and beverages.

The present invention provides a polyisocyanate composition comprising at least one isocyanate compound selected from the group consisting of an aliphatic isocyanate and an alicyclic isocyanate as a skeleton, wherein an average value of a total number of isocyanate groups blocked with a blocking agent and not blocked with a blocking agent per polyisocyanate molecule is 2 or more, and among the isocyanate groups in the polyisocyanate composition, 1 mol % or more and 99 mol % or less are blocked with a blocking agent, and the like.

The present invention provides a polyisocyanate composition comprising at least one isocyanate compound selected from the group consisting of an aliphatic isocyanate and an alicyclic isocyanate as a skeleton, wherein an average value of a total number of isocyanate groups blocked with a blocking agent and not blocked with a blocking agent per polyisocyanate molecule is 2 or more, and among the isocyanate groups in the polyisocyanate composition, 1 mol % or more and 99 mol % or less are blocked with a blocking agent, and the like.

The present invention relates to novel cast polyamides, to processes for production thereof and to the use thereof.

An inkjet composition for additive manufacturing includes at least one photocurable compound, at least one thermocurable compound and a photoinitiator, wherein the at least one photocurable compound and the at least one thermocurable compound are different compounds. A method for manufacturing a three-dimensional object includes dispensing and curing an inkjet composition.

A method for producing a shaped body, containing: producing the shaped body from a composition by a powder-based layer construction process, wherein the composition contains a thermoplastic polyurethane, obtained by reacting a polyisocyanate composition and a polyol composition, the thermoplastic polyurethane is solid at least in a temperature region below 50° C. and has end groups selected from the group consisting of first end groups and second end groups, wherein the first end groups are optionally eliminated at a first temperature, and the second end groups are optionally eliminated at a second temperature, to form reactive groups on the thermoplastic polyurethane that optionally enter into a reaction with functional groups of the thermoplastic polyurethane or functional groups of a further component of the composition, and wherein the first temperature and the second temperature are each greater than or equal to 60° C.

The present invention is directed to a liquid, storage stable isocyanate composition (Q) comprising monomeric diphenyl methane diisocyanate (MDI) as component (q1) and an amide with a molecular weight of less than 200 g/mol as component (q2) in an amount of 0.1 to 5 wt.-% based on the sum of the weight of components (q1) and (q2) which adds up to 100 wt.-%, wherein the NCO-content is in the range of from 29.5 to 40.0 wt.-% based on the total weight of the respective isocyanate composition (Q). The present invention is also directed to a process for the manufacture of said liquid, storage stable isocyanate composition (Q) as well as the use of an amide with a molecular weight of less than 200 g/mol for the liquification of at room temperature solid isocyanates. Further, the present invention is directed to the use of an isocyanate composition (Q) of the invention for the synthesis of polyurethane foams, compact polyurethane elastomers or thermoplastic polyurethanes.

An object of the present invention is to provide a preparation method for improving the edge part rust prevention property in the preparation of a cationic electrodeposition coating composition containing a bismuth compound as a curing catalyst. The present invention provides a method for preparing a cationic electrodeposition coating composition, including a step of preparing a resin emulsion (i) containing an aminated resin (A) and a blocked isocyanate curing agent (B), a step of preparing a pigment dispersion paste (ii) containing a bismuth-metal oxide mixture liquid (C) containing a bismuth compound (c1), a metal oxide (c2), a monohydroxycarboxylic acid (c3) having 3 to 5 carbon atoms in total and a solvent; a pigment dispersion resin (D); a polyvalent acid (E); and a pigment (F), and a step of mixing the resin emulsion (i) and the pigment dispersion paste (ii).

A lactam-functionalized polymer is disclosed. The dihydroxy lactam based polymer includes polyesters, polycarbonates, polyethers, poly (ester ethers), poly (ester amides), poly imides, polyamides, poly acrylates and poly (ester imides), and polyurethanes. The applications of the dihydroxy lactam based polymers are also disclosed.

Provided is a solventless two-component adhesive having excellent processed appearance and processability while exhibiting excellent adhesive strength even with aging at room temperature (around 25° C.) and in a short period of 12 hours. Provided are a two-component curable adhesive containing a polyisocyanate composition (X) containing a polyisocyanate (A) and a resin composition (Y) containing a polyol (B) as essential components, the two-component curable adhesive satisfying (1) to (3), as well as a laminated film and a packaging body produced using the two-component curable adhesive: (1) a tensile shear adhesive strength (N1) when provided between two bases and after a lapse of 30 minutes after pressure bonding is 0.5 N/cm.sup.2 or more; (2) the tensile shear adhesive strength (N1) when provided between two bases and after a lapse of 30 minutes after pressure bonding is three times or less a tensile shear adhesive strength (N2) after a lapse of 10 minutes after pressure bonding; and (3) a tensile shear adhesive strength (N3) when provided between two bases and after a lapse of 5 hours after pressure bonding is 20 N/cm.sup.2 or more.