A multicomponent adhesive composition comprises a composition A and a composition B. Composition A comprises at least one silyl polymer comprising at least one hydrolyzable alkoxysilane group and at least one tackifying resin. Composition B comprises at least one catalyst and at least one compound C chosen from a compound C1 with a number-average molecular mass ranging from 300 g/mol to 500 000 g/mol; and a compound C2 with a vapor pressure at 20° C. of greater than or equal to 0.08 kPa; and mixtures thereof. The composition A:composition B mass ratio ranges from 99.98:0.02 to 60:40. The total content of catalyst ranges from 0.01% to 10% relative to the total weight of said adhesive composition.

A multicomponent adhesive composition comprises a composition A and a composition B. Composition A comprises at least one silyl polymer comprising at least one hydrolyzable alkoxysilane group and at least one tackifying resin. Composition B comprises at least one catalyst and at least one compound C chosen from a compound C1 with a number-average molecular mass ranging from 300 g/mol to 500 000 g/mol; and a compound C2 with a vapor pressure at 20° C. of greater than or equal to 0.08 kPa; and mixtures thereof. The composition A:composition B mass ratio ranges from 99.98:0.02 to 60:40. The total content of catalyst ranges from 0.01% to 10% relative to the total weight of said adhesive composition.

The invention relates to an adhesive dual-component composition based on polyurethane, comprising an —NCO component and an —OH component such that: the —NCO component is a composition comprising: A) at least one polyurethane prepolymer comprising at least two NCO terminal groups obtained by the polyaddition reaction of at least one dissymmetric diisocyanate monomer and at least one diol, and B) at least one triisocyanate selected from isocyanurates, biurets, diisocyanate and triol adducts, and the mixtures thereof; the —OH component is a composition comprising at least one polyol; at least one of the polyols or diols is selected from polyether polyols (or polyether diols); at least one of the polyols or diols is selected from polyester polyols (or polyester diols); and the weight ratio of the quantity of polyether polyol(s) to the quantity of polyester polyol(s), defined as r.sub.4, ranges from 0.6 to 2.2.

The invention relates to an adhesive dual-component composition based on polyurethane, comprising an —NCO component and an —OH component such that: the —NCO component is a composition comprising: A) at least one polyurethane prepolymer comprising at least two NCO terminal groups obtained by the polyaddition reaction of at least one dissymmetric diisocyanate monomer and at least one diol, and B) at least one triisocyanate selected from isocyanurates, biurets, diisocyanate and triol adducts, and the mixtures thereof; the —OH component is a composition comprising at least one polyol; at least one of the polyols or diols is selected from polyether polyols (or polyether diols); at least one of the polyols or diols is selected from polyester polyols (or polyester diols); and the weight ratio of the quantity of polyether polyol(s) to the quantity of polyester polyol(s), defined as r.sub.4, ranges from 0.6 to 2.2.

The invention relates to a silylated polyurethane obtainable by reacting: d) at least one polyol having a number average molecular weight of from 1000 to 50,000 g/mol; e) at least one polyisocyanate, preferably diisocyanate; and f) at least one tertiary hydroxyl functional alkoxysilane of the general formula (I) ##STR00001##
wherein R.sup.1 is selected from the group consisting of hydrogen and a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R.sup.2 and R.sup.3 are same or different and are, independent from one another, selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R.sup.4 is selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R.sup.5 is selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R.sup.6 and R.sup.7 are same or different and are, independent from one another, selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; and n is 1, 2 or 3, a method for preparing thereof, a curable composition comprising the thereby obtained silylated polyurethane, and its use.

The invention relates to a silylated polyurethane obtainable by reacting: d) at least one polyol having a number average molecular weight of from 1000 to 50,000 g/mol; e) at least one polyisocyanate, preferably diisocyanate; and f) at least one tertiary hydroxyl functional alkoxysilane of the general formula (I) ##STR00001##
wherein R.sup.1 is selected from the group consisting of hydrogen and a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R.sup.2 and R.sup.3 are same or different and are, independent from one another, selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R.sup.4 is selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R.sup.5 is selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R.sup.6 and R.sup.7 are same or different and are, independent from one another, selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; and n is 1, 2 or 3, a method for preparing thereof, a curable composition comprising the thereby obtained silylated polyurethane, and its use.

The invention relates to curable coating compositions containing at least one surface modifying amphiphilic additive; and at least one siloxane-polyurethane coating composition. The invention also relates to methods of making and using the curable coating compositions of the invention. The invention also relates to objects coated with the curable coating composition of the invention. The invention also relates to methods for reducing or preventing biofouling of a surface exposed to an aqueous environment comprising the steps of coating the surface with the curable coating composition of the invention to form a coated surface, and curing the coating composition on the coated surface. The invention also relates to a marine fouling-release coating containing the curable coating composition of the invention.

The present invention relates to a moisture-crosslinkable composition comprising: at least one polymer (A) comprising at least one alkoxysilane group; at least 25% by weight of at least one carbonate filler (B) relative to the total weight of said composition; at least one compound chosen from bis(alkoxysilane)s or tri(alkoxysilane)s (C) having a molar mass ranging from 250 to 1000 g/mol; at least one crosslinking catalyst (D);
said composition being characterized in that it comprises a plasticizer content of less than or equal to 1% by weight relative to the total weight of the composition.

The present invention relates to a moisture-crosslinkable composition comprising: at least one polymer (A) comprising at least one alkoxysilane group; at least 25% by weight of at least one carbonate filler (B) relative to the total weight of said composition; at least one compound chosen from bis(alkoxysilane)s or tri(alkoxysilane)s (C) having a molar mass ranging from 250 to 1000 g/mol; at least one crosslinking catalyst (D);
said composition being characterized in that it comprises a plasticizer content of less than or equal to 1% by weight relative to the total weight of the composition.

A polyurethane composition includes, based on the total weight of the composition, A) 20-35 wt % of polyurethane prepolymer PU-1 which is a reaction product of ethylene oxide (EO)-terminated polyether triol with an aromatic polyisocyanate, and B) 0.2-3 wt % of polyurethane prepolymer PU-2 which is a reaction product of polyester polyol with an aromatic polyisocyanate. The composition has a low TVOC content, has a good adhesion without the need of primer, can cure rapidly with a high initial bonding strength, while keeping good mechanical properties.