A prepolymer of elastomer material for screw drilling tools and a preparation method thereof are provided. The prepolymer includes component A and component B, wherein the component A includes hydroxyl-terminated liquid rubber, polytetrahydrofuran diol, and polyether polyol; the component B includes at least one of an isocyanate, a cyanate, and a cyano compound; the mass ratio of the hydroxyl-terminated liquid rubber, polytetrahydrofuran diol, and polyether polyol is (0.2-1.0): (0.2-1.0): (0.2-1.0). Different molecular segments of different proportions are introduced through structural design, such that the molecular structure of the prepolymer has both rigid and flexible segments, thus to achieve an adjustable and controllable structure of the prepolymer; and the introduction of active groups makes the prepolymer to show good reactivity and processability. Therefore, a reactive elastomer material having excellent properties such as hardness, tear strength, and tensile strength can be obtained used as an elastomer material for screw drilling tools.

The present invention relates to a hydrophilic acrylic-modified polyurethane and a method for preparing same, and a water-based paint composition using same and a manufacturing method thereof and, more specifically, to a hydrophilic acrylic-modified polyurethane and a method for preparing same, and a water-based paint composition using same and a manufacturing method thereof, the hydrophilic acrylic-modified polyurethane comprising: a polymerization unit derived from an anhydrosugar alcohol-alkylene oxide adduct; a polymerization unit derived from polyisocyanate; and a polymerization unit derived from hydroxyalkyl (meth)acrylate, and capable of providing a water-based paint composition in which eco-friendliness, adhesiveness (adhesion), crack resistance and water resistance are all improved.

Disclosed are low-viscosity foamable polyurethane-forming compositions containing a polyol composition having monomeric and higher polyol components and optionally a polyhydroxylated aromatic compound; a polyisocyanate or latent polyisocyanate component or a combination thereof; a blowing agent; and optionally a cyclic carbonate having one or more hydroxyl groups. The monomeric and higher polyols each contain three or more hydroxyl groups, the higher polyol containing residues of the monomeric polyol and optionally residues of the polyhydroxylated aromatic compound, the residues being linked by one or more carbonate and/or ether groups. The Disclosed foamable polyurethane-forming compositions may contain the polyol compositions disclosed; an isocyanate functional component; and a blowing agent. The foamable compositions afford high strength, heat-resistant, low to moderate density foamed-polyurethane compositions useful in a variety of applications including construction, vehicle and packaging applications.

Polyurethane coating compositions are disclosed that include an isocyanate-reactive component that includes a polycyclic polyether polyol that is the reaction product of a reaction mixture that includes a polycyclic polyol starter, and an alkylene oxide, as well as an isocyanate-functional component that includes a non-aromatic polyisocyanate. The polyurethane coating compositions may be particularly useful as a gel coat in the manufacture of glass fiber reinforced plastics.

A method for preparing rigid polyurethane (PUR) foams or rigid polyisocyanurate (PIR) foams in which method the rigid PUR or PIR foam is prepared by reacting a composition (C) comprising: at least one isocyanate-reactive component (B1) having functional groups selected from hydroxyl, amine and thiol groups; at least one isocyanate component (A1) having an average functionality of less than 2.70; and at least one blowing agent [blowing agent (BA), herein after]; with the proviso that the overall average functionality [F.sub.n,avg(A), herein after] of all isocyanate components present in the composition (C) is less than 2.70; wherein the composition (C) is characterized by an isocyanate index X, wherein the rigid PUR or PIR foams are produced by depositing the composition (C) between two gas-tight facing sheets and wherein the rigid PUR or PIR foam is characterized by a difference Δλ between the initial thermal conductivity value λ.sub.ini and the aged thermal conductivity value λ.sub.aged of said rigid PUR or PIR foam wherein: when X≤200 then Δλ<1.35; and when X>200 then Δλ<[6.49−(4.46*F.sub.n,avg(A))−(0.02348*X)+(0.492*F.sub.n,avg(A)*F.sub.n,avg(A))+(0.01343*F.sub.n,avg(A)*X)+0.3].

A preparation method for an ultraviolet-responsive coumarin controlled-release and self-repairing anti-fouling paint includes: reacting double-end-group reactive polydimethylsiloxane, polyisocyanate, and an organic diluting solvent; adding a dihydroxycoumarin compound, a cross-linking agent and an organotin catalyst; adding a simple coumarin compound, and irradiating the mixture with 365 nm ultraviolet light to obtain the anti-fouling paint. An anti-fouling coat formed by the paint of the present invention has the advantages of controllable release of a coumarin green anti-fouling agent in response to external ultraviolet stimulation and self-repairing, and the problems that the release of the conventional anti-fouling agents in the anti-fouling coat is difficult to control, and that the low-surface-energy anti-fouling coat is difficult to repair after being damaged are solved. The anti-fouling application requirements of various shallow sea light-transmitting constructions can be met, the service life is prolonged, and the application performance in a complex real sea environment is enhanced.

A preparation method for an ultraviolet-responsive coumarin controlled-release and self-repairing anti-fouling paint includes: reacting double-end-group reactive polydimethylsiloxane, polyisocyanate, and an organic diluting solvent; adding a dihydroxycoumarin compound, a cross-linking agent and an organotin catalyst; adding a simple coumarin compound, and irradiating the mixture with 365 nm ultraviolet light to obtain the anti-fouling paint. An anti-fouling coat formed by the paint of the present invention has the advantages of controllable release of a coumarin green anti-fouling agent in response to external ultraviolet stimulation and self-repairing, and the problems that the release of the conventional anti-fouling agents in the anti-fouling coat is difficult to control, and that the low-surface-energy anti-fouling coat is difficult to repair after being damaged are solved. The anti-fouling application requirements of various shallow sea light-transmitting constructions can be met, the service life is prolonged, and the application performance in a complex real sea environment is enhanced.

The subject application relates to polyurethane foam and methods of forming the same. A polyurethane foam may include a polyurethane foam may include a first polyol component, a second polyol component, and a third polyol component. The first polyol component may include at least one component selected from the group of a polyether polyol and a polyester polyol. The second polyol component may include a polyether polyol. The third polyol component may include a grafted polyether polyol. The polyurethane foam may have a density of at least about 100 kg/m.sup.3 and not greater than about 800 kg/m.sup.3. The polyurethane foam may have an adjusted compression force deflection to density ratio of at least about 0.3.

Described herein are anti-microbial and UV-protective biological devices and extracts produced therefrom. The biological devices include microbial cells transformed with a DNA construct containing genes for producing proteins such as, for example, zinc-related protein/oxidase, silicatein, silaffin, and alcohol dehydrogenase. In some instances, the biological devices also include a gene for lipase. Methods for producing and using the devices are also described herein. Finally, compositions and methods for using the devices and extracts to kill microbial species or prevent microbial growth and to reduce or prevent UV-induced damage or exposure to materials, items, plants, and human and animal subjects are described herein. Also disclosed are biological devices producing polyactive carbohydrates and carbo sugars, as well as compositions and articles incorporating both extracts from these devices and the anti-microbial and UV-protective extracts.

A method of making polyesters and polyurethanes from biomass-derived polyols. The polyol is biomass-derived and has the structure: ##STR00001##
wherein dashed bonds are single or double bonds and R is selected from the group consisting of —OH and ═O. Polyurethanes are made by reacting the polyol with a diisocyanate. Polyesters are made by reacting the polyol with a dicarboxylic acid.