Patent classifications
C08G18/348
AQUEOUS POLYURETHANE RESIN COMPOSITION AND COATING MATERIAL USING THE COMPOSITION
Provided is an aqueous polyurethane resin composition which is excellent in finished appearance as well as excellent in impact resistance, such as chipping resistance, and adhesion.
The aqueous polyurethane resin composition includes a polyurethane resin obtained from at least (a) at least two types of organic diisocyanate compounds and/or polyisocyanate compounds which are different from each other, (b) a polyol compound; (c) an acidic group-containing compounds comprising at least two types of compounds which are a compound containing a carboxyl group as the acid group (a carboxyl group-containing compound) and a compound containing a sulfo group as the acid group (a sulfo group-containing compound); and (d) a chain extender of a polyamine compound, a diamine compound, a polyol compound and/or an alkanolamine compound with a molecular weight of not more than 400, in which the aqueous polyurethane resin composition has a viscosity of not less than 500 Pa.Math.s and not more than 50,000 Pa.Math.s when the polyurethane resin is contained in an amount of 65% by weight.
AQUEOUS POLYURETHANE RESIN COMPOSITION AND COATING MATERIAL USING THE COMPOSITION
Provided is an aqueous polyurethane resin composition which is excellent in finished appearance as well as excellent in impact resistance, such as chipping resistance, and adhesion.
The aqueous polyurethane resin composition includes a polyurethane resin obtained from at least (a) at least two types of organic diisocyanate compounds and/or polyisocyanate compounds which are different from each other, (b) a polyol compound; (c) an acidic group-containing compounds comprising at least two types of compounds which are a compound containing a carboxyl group as the acid group (a carboxyl group-containing compound) and a compound containing a sulfo group as the acid group (a sulfo group-containing compound); and (d) a chain extender of a polyamine compound, a diamine compound, a polyol compound and/or an alkanolamine compound with a molecular weight of not more than 400, in which the aqueous polyurethane resin composition has a viscosity of not less than 500 Pa.Math.s and not more than 50,000 Pa.Math.s when the polyurethane resin is contained in an amount of 65% by weight.
PREPARATION METHOD OF ULTRAVIOLET (UV)-RESISTANT AND TRANSPARENT LIGNIN-BASED POLYURETHANE (PU) ELASTOMER
The present disclosure discloses a preparation method of an ultraviolet (UV)-resistant and transparent lignin-based polyurethane (PU) elastomer. During the synthesis process, natural lignin-based polyols are directly used as an end-capping agent, isophorone diisocyanate and 2,2-dimethylolbutyric acid are used as a hard segment and polyether chain polyols are used as a soft segment, to synthesize a PU elastomer with a transparent brown appearance, excellent high elasticity and elastic recovery performance, as well as excellent mechanical properties, excellent UV resistance and repeatable processability. The lignin-based PU elastomer has a simple preparation process, and has great potential values for use in the fields such as PU elastomer film, fabric coating, and elastic fiber and biomass polymer materials.
PREPARATION METHOD OF ULTRAVIOLET (UV)-RESISTANT AND TRANSPARENT LIGNIN-BASED POLYURETHANE (PU) ELASTOMER
The present disclosure discloses a preparation method of an ultraviolet (UV)-resistant and transparent lignin-based polyurethane (PU) elastomer. During the synthesis process, natural lignin-based polyols are directly used as an end-capping agent, isophorone diisocyanate and 2,2-dimethylolbutyric acid are used as a hard segment and polyether chain polyols are used as a soft segment, to synthesize a PU elastomer with a transparent brown appearance, excellent high elasticity and elastic recovery performance, as well as excellent mechanical properties, excellent UV resistance and repeatable processability. The lignin-based PU elastomer has a simple preparation process, and has great potential values for use in the fields such as PU elastomer film, fabric coating, and elastic fiber and biomass polymer materials.
AMINATED PHOSPHORENE-BASED FLAME-RETARDANT WATERBORNE POLYURETHANE COATING AND PREPARATION METHOD THEREOF
This application relates to flame-retardant coatings, and more particularly to an aminated phosphorene-based flame-retardant waterborne polyurethane coating and a preparation method thereof. The aminated phosphorene-based flame-retardant waterborne polyurethane coating is prepared from a diisocyanate-terminated prepolymer, a neutralizer and an aminated phosphorene, where the diisocyanate-terminated prepolymer is prepared from polymeric diol with water-dispersible groups, aliphatic diisocyanate and carboxylic acid type hydrophilic diol under the catalysis of a catalyst for synthesizing waterborne polyurethane.
Coated substrates prepared with waterborne sealer and primer compositions
The present invention provides multilayer coated substrates, prepared using primer and/or sealer compositions comprising waterborne curable film-forming compositions, in turn comprising: a) an aqueous dispersion of a pigment and i) polymeric urethane-shell particles having a care-shell morphology and having hydroxyl functional groups, wherein the core is prepared from a monomer mixture comprising hydrophobic, ethylenically unsaturated monomers and the shell comprises a polyurethane or polyurethane-urea polymer; or ii) polymeric acrylic-shell particles having a core-shell morphology and having hydroxyl functional groups, wherein the core is prepared from a monomer mixture comprising hydrophobic, ethylenically unsaturated monomers and the shell is prepared from a monomer mixture comprising hydrophilic, ethylenically unsaturated monomers; b) a polyisocyanate crosslinking agent; and optionally c) a hydroxyl functional, water dispersible acrylic polymer.
Polyurethane-based UV absorber
A polyurethane-based UV absorber, obtained by reacting a UV absorber having a reactive hydrogen with a polyisocyanate and a diol or polyol; wherein the weight average molecular weight of the polyurethane-based UV absorber is in a range of 10,000 to 200,000.
CHEMICAL RESISTANT POLYURETHANE ADHESIVE
A pressure sensitive adhesive composition includes a polyurethane polymer that includes the reaction product of a polyisocyanate component and a polyol component. The polyol component has a total solubility parameter ranging from 10 to 14 (cal/cm.sup.3).sup.1/2.
Color protectant compositions
Provided herein are color protectant compositions for dyed human hair, and methods for determining the same.
Transparent conducting film laminate and processing method thereof
Provided are a transparent conducting film laminate to which a curl generated during a heating step and after the heating step can be controlled, and a method for processing the same. A transparent conducting film laminate comprises a transparent conducting film 20 and a carrier film 10 stacked thereon, wherein the transparent conducting film 20 comprises a transparent resin film 3, transparent conducting layer 4, and an overcoat layer 5 stacked in this order, the transparent resin film 3 having a thickness T.sub.1 of 5 to 25 μm and being made of an amorphous cycloolefin-based resin, the carrier film 10 is releasably stacked on the other main face, the face opposite to the face having the transparent conducting layer 4, of the transparent resin film 3 with an adhesive agent layer 2 therebetween, and a protection film 1 has a thickness T.sub.2 which is 5 times or more of the thickness T.sub.1 of the transparent resin film 3 and is 150 μm or less, and is made of polyester having an aromatic ring in its molecular backbone.