Water-based adhesive composition are disclosed, the compositions comprising an acrylic dispersion, an epoxy-terminated polyester incorporated into the acrylic dispersion, and a water-dispersible isocyanate. Methods for laminating a first substrate to a second substrate are also disclosed, the methods comprising (a) providing an acrylic dispersion, (b) providing an epoxy-terminated polyester, (c) mixing the acrylic dispersion and the epoxy-terminated polyester, (d) mixing the mixture of (c) with a water-dispersible isocyanate to form an adhesive composition, (e) coating the adhesive composition of (d) on a surface of the first substrate, (f) drying the adhesive compositions on the first substrate to remove water, and (g) bringing the adhesive composition on the surface of the first substrate into contact with a surface of a second substrate, thereby laminating the first substrate to the second substrate. Laminates prepared comprising the water-based adhesives and according to the disclosed methods are also disclosed.

A polyester polyol is formed in a polycondensation reaction between an aromatic dicarboxylic acid, a polyol, and an epoxy compound having a straight chain alkyl or alkenyl group having at least six carbon atoms. The polyester polyol exhibits excellent compatibility with hydrocarbon blowing agents. As such, it is a useful component in rigid polyurethane foam formulations that are contain hydrocarbon blowing agents.

A polyester polyol is formed in a polycondensation reaction between an aromatic dicarboxylic acid, a polyol, and an epoxy compound having a straight chain alkyl or alkenyl group having at least six carbon atoms. The polyester polyol exhibits excellent compatibility with hydrocarbon blowing agents. As such, it is a useful component in rigid polyurethane foam formulations that are contain hydrocarbon blowing agents.

Epoxy soybean oil polyol is firstly prepared by open-ring etherification of an epoxy soybean oil and a small molecular alcohol with an organic acid catalyst, and then the epoxy soybean oil polyol is further esterified with an organic acid under an esterification catalyst to prepare a polyester polyol with a high biomass ratio. The polyester polyol includes a compound having an Ñ-type structure and a compound having an Ò-type structure. A method for preparing the polyester polyol is provided, as well as a polyurethane controlled-release fertilizer envelope and a polyurethane controlled-release fertilizer prepared by cross-linking the polyester polyol and MDI on surfaces of the fertilizer. The epoxy soybean oil and the small molecular alcohol can be derived from biomass, so a biomass content is high, the synthesized product is environmentally safe, and product performance is excellent.

Polyether- or polyester-epoxide polymer (PEEP) compositions are disclosed. The compositions comprise reaction products of a polyepoxide compound and a polyol composition. The polyol composition has a melting point within the range of 20 C. to 100 C. and a hydroxyl number less than 35 mg KOH/g. The PEEP composition is a solid-solid phase-change material. As measured by differential scanning calorimetry (DSC) at a heating/cooling rate of 10 C./minute, the PEEP composition has a transition temperature within the range of 10 C. to 70 C., a latent heat at the transition temperature within the range of 30 to 200 J/g, and little or no detectable hysteresis or supercooling upon thermal cycling over at least five heating/cooling cycles that encompass the transition temperature. The PEEP compositions should enable formulators to manage thermal energy changes in many practical applications, including automotive, marine or aircraft parts, building materials, appliance insulation, electronics, textiles, garments, and paints or coatings.

Water-based adhesive composition are disclosed, the compositions comprising an acrylic dispersion, an epoxy-terminated polyester incorporated into the acrylic dispersion, and a water-dispersible isocyanate. Methods for laminating a first substrate to a second substrate are also disclosed, the methods comprising (a) providing an acrylic dispersion, (b) providing an epoxy-terminated polyester, (c) mixing the acrylic dispersion and the epoxy-terminated polyester, (d) mixing the mixture of (c) with a water-dispersible isocyanate to form an adhesive composition, (e) coating the adhesive composition of (d) on a surface of the first substrate, (f) drying the adhesive compositions on the first substrate to remove water, and (g) bringing the adhesive composition on the surface of the first substrate into contact with a surface of a second substrate, thereby laminating the first substrate to the second substrate. Laminates prepared comprising the water-based adhesives and according to the disclosed methods are also disclosed.

Polyether- or polyester-epoxide polymer (PEEP) compositions are disclosed. The compositions comprise reaction products of a polyepoxide compound and a polyol composition. The polyol composition has a melting point within the range of 20? C. to 100? C. and a hydroxyl number less than 35 mg KOH/g. The PEEP composition is a solid-solid phase-change material. As measured by differential scanning calorimetry (DSC) at a heating/cooling rate of 10? C./minute, the PEEP composition has a transition temperature within the range of ?10? C. to 70? C., a latent heat at the transition temperature within the range of 30 to 200 J/g, and little or no detectable hysteresis or supercooling upon thermal cycling over at least five heating/cooling cycles that encompass the transition temperature. The PEEP compositions should enable formulators to manage thermal energy changes in many practical applications, including automotive, marine or aircraft parts, building materials, appliance insulation, electronics, textiles, garments, and paints or coatings.

Epoxy soybean oil polyol is firstly prepared by open-ring etherification of an epoxy soybean oil and a small molecular alcohol with an organic acid catalyst, and then the epoxy soybean oil polyol is further esterified with an organic acid under an esterification catalyst to prepare a polyester polyol with a high biomass ratio. The polyester polyol includes a compound having an -type structure and a compound having an -type structure. A method for preparing the polyester polyol is provided, as well as a polyurethane controlled-release fertilizer envelope and a polyurethane controlled-release fertilizer prepared by cross-linking the polyester polyol and MDI on surfaces of the fertilizer. The epoxy soybean oil and the small molecular alcohol can be derived from biomass, so a biomass content is high, the synthesized product is environmentally safe, and product performance is excellent.