C08G18/6216

Composition for forming polyurethane film, polyurethane-film derived therefrom and article comprising the same

Disclosed is a composition for forming a polyurethane film with improved reaction stability, comprising an OH group-containing polymer; an isocyanate-based compound as a curing agent; and an alicyclic urea diol compound having two urea groups and an OH group at two terminals, and a polyurethane film with improved self-healable property from tear, derived from the composition.

REMOVAL OF MONOMERIC ALIPHATIC DIISOCYANATE IN AN ALIPHATIC POLYISOCYANATE USING SCAVENGERS

The present invention relates to a process for the effective removal of residual monomeric aliphatic isocyanate from a reaction mixture comprising aliphatic polyisocyanate comprising (i) providing a reactor containing a scavenger comprising a zeolitic material, wherein the zeolitic material comprises SiO.sub.2 and optionally X.sub.2O.sub.3 in its framework structure, wherein X is a trivalent element; (ii) providing a reaction mixture comprising aliphatic polyisocyanate and monomeric aliphatic isocyanate; (iii) contacting the scavenger in the reactor with the reaction mixture provided in (ii) at a temperature lower than the boiling point of the residual monomeric aliphatic isocyanate for obtaining a product comprising aliphatic polyisocyanate with a reduced monomeric aliphatic isocyanate content, wherein if the zeolitic material comprises X.sub.2O.sub.3, the zeolitic material has an SiO.sub.2 to X.sub.2O.sub.3 molar ratio higher than 2.8:1, preferably higher than 5:1, more preferably higher than 30:1.

POLYISOCYANATE COMPOSITION, FILM-FORMING COMPOSITION, FILM, FILM LAMINATE, ADHESIVE RESIN COMPOSITION AND ADHESIVE RESIN-CURED PRODUCT, COATING COMPOSITION AND COATING MATERIAL-CURED PRODUCT

The present invention provides a polyisocyanate composition comprising at least one isocyanate compound selected from the group consisting of an aliphatic isocyanate and an alicyclic isocyanate as a skeleton, wherein an average value of a total number of isocyanate groups blocked with a blocking agent and not blocked with a blocking agent per polyisocyanate molecule is 2 or more, and among the isocyanate groups in the polyisocyanate composition, 1 mol % or more and 99 mol % or less are blocked with a blocking agent, and the like.

AMPHIPHILIC BLOCK COPOLYMER

The invention relates to block copolymer comprising i) A first block wherein at least 65 mol-% of the repeating units of the first block are repeating units of the formula (I)—[CH.sub.2—CH.sub.2—O]—, ii) A second block wherein at least 90 mol-% of the repeating units of the second block are repeating units of at least one of formulae (II) or (III), wherein the groups R.sup.1, R.sup.2, and R.sup.3 independent of each occurrence are selected from hydrocarbyl groups having 1 to 40 carbon atoms, which are optionally substituted by ether or hydroxyl groups, and wherein the groups R.sup.1 and R.sup.2 are optionally linked to each other such that a nitrogen heterocyclic structure is present, iii) A third block which is different from the first block and the second block and which is more hydrophobic than the first block.

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GEL NAIL STICKER AND METHOD FOR MANUFACTURING THE SAME
20230148731 · 2023-05-18 ·

The present disclosure provides a method for manufacturing a gel nail sticker including: forming an adhesive layer by applying an adhesive on a first film layer 10; forming a base printing layer having at least one color on the first film layer; forming a first gel layer having flexibility on the base printing layer; and forming a second gel layer by mixing a resin composition having a —NCO functional group with a coating solution containing a resin composition having an —OH functional group and a UV curable composition on the first gel layer, in which the forming of the second gel layer includes forming the second gel layer including a urethane coating film having a urethane bond by causing a urethane reaction between the resin composition having the —OH functional group and the resin composition having the —NCO functional group.

Alternative crosslinking mechanisms for polyurethane-based systems

The present invention provides compositions comprising the reaction product of an aliphatic diisocyanate, and a reactive intermediate made from one selected from the group consisting of oxazolidinones, benzoic sulfimides (saccharins), 1H-indole-2,3-diones (isatins), succinamides, N-hydroxysuccinamides, 4-hydroxy-3-methoxybenzaldehydes (vanillins), α-ketoamides, piperazines, benzofuranones, 3,4-dihydroxycyclobut-3-ene-1,2-diones (squaric acids), squaric acid esters, α-ketoamides, anilines, and α-ketoamide, phenols. The aliphatic diisocyanate comprises one selected from the group consisting of isocyanurates, biurets, iminooxadiazine diones, urethanes, uretdiones, carbodiimides, and allophanates. The resulting compositions may be useful in producing coatings, adhesives, sealants, castings, composites and films having durability, color stability, high gloss, and chemical resistance properties similar to those made from polyurethane.

ELECTROPHOTOGRAPHIC MEMBER, METHOD OF PRODUCING THE SAME, PROCESS CARTRIDGE, AND ELECTROPHOTOGRAPHIC APPARATUS

Provided is an electrophotographic member that is excellent in charge-imparting performance for a toner, and that hardly causes tackiness on its surface even when placed under a high-temperature and high-humidity environment over a long time period. The electrophotographic member includes a substrate and a surface layer, in which the surface layer satisfies the following requirements (A) and (B): (A) the surface layer contains, in a region from its surface to a depth of up to 0.1 μm, a copolymer containing a constituent unit represented by the following structural formula (1), and at least one selected from the group consisting of a constituent unit represented by the following structural formula (2) and a constituent unit represented by the following structural formula (3); and (B) the concentration of a nitrogen atom derived from a nitrogen-containing aromatic heterocyclic amine structure in the copolymer is from 6.0 mass % to 30.0 mass %.

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WINDOW FILM FOR DISPLAY AND DISPLAY DEVICE INCLUDING SAME
20170322354 · 2017-11-09 ·

Provided are a window film for a display and a display device including the same, and the window film for a display comprises: a substrate layer; a coating layer formed on one side of the substrate layer; and an adhesive layer formed on the other side of the substrate layer, wherein the coating layer and/or the adhesive layer includes, relative to each layer, a UV absorbent of approximately 3 wt % to approximately 20 wt %, and the window film for a display has a transmittance of approximately 1% or less for a wavelength of 390 nm or less.

SELF-EMULSIFYING POLYISOCYANATE COMPOSITION, TWO-PACK TYPE COATING COMPOSITION AND COATING FILM

The present invention relates to a self-emulsifying polyisocyanate composition including a reaction mixture of (a) an anionic compound having a specific structure, (b) nonionic hydrophilic group-containing monofunctional alcohol having a specific structure, (c) organic polyisocyanate, and (d) tertiary amine, a two-part coating composition that contains the composition, and a coating film that can be obtained from the coating composition.

PRO GEL CAP STYLE MULTIFUNCTIONAL COMPOSITION
20210380818 · 2021-12-09 ·

A method for creating a multi-functional additive for fusion powder coating compositions that is made from a binder system platform so as to replace the need for multiple conventional additives. The method calls for the multi-functional additive to be provided to fusion powder coating compositions by way of a carrier system selected from (3-aminopropyl) trimethoxysilane (TMS), silicon dioxide (at 45 to 55% active levels), and a flow aid comprising a polyethylene resin, a polyester hydroxyl resin, a polymeric curative, degassing agent, ricinoleic acid, and glass flake.