Disclosed is a polyurethane hot-melt adhesive including: a thermoplastic polyurethane that is a reactant of a raw material including a polymer polyol, a polyisocyanate, and a chain extender, wherein X−Y≥15, where X represents a temperature (° C.) at which the polyurethane hot-melt adhesive has a melt viscosity of 2.0×10.sup.3 Pa.Math.s, and Y represents a temperature at which the polyurethane hot-melt adhesive has a melt viscosity of 1.0×10.sup.5 Pa.Math.s, and the polyurethane hot-melt adhesive has a 100% modulus of 2.5 MPa or more.

A reactive mixture and method for making a thermoplastic polyurethane (TPU) flexible foam having a predominantly open-cell structure (open-cell content of ≥50% by volume calculated on the total volume of the foam and measured according to ASTM D6226-10) and an apparent density below 200 kg/m.sup.3.

A reactive mixture and method for making a thermoplastic polyurethane (TPU) flexible foam having a predominantly open-cell structure (open-cell content of ≥50% by volume calculated on the total volume of the foam and measured according to ASTM D6226-10) and an apparent density below 200 kg/m.sup.3.

A composition contains a thermoplastic polyurethane (TPU-1), obtained or obtainable by reaction of an isocyanate composition (IZ) containing MDI with a polyol composition (PZ), and hollow glass microspheres. The polyol composition (PZ) contains at least one polyol (P1) selected from polytetrahydrofurans having an average molecular weight Mn in the range from 900 to 2,000 g/mol. The polyol composition (PZ) also contains a chain extender (KV1), selected from 1,2-ethandiol, 1,3-propanediol, 1,4-butanediol and 1,6-hexanediol. Ski shoes, preferably ski boots, particularly preferably the outer shell of a ski boot, can be based on such a thermoplastic polyurethane. Corresponding processes can be used for producing ski shoes.

The present invention is drawn to an aqueous polyurethane dispersion comprising: —anionic polyurethane particles comprising both free pending carboxylate groups of formula —COO.sup.−M.sup.+ where M.sup.+ is a cation resulting from neutralization of carboxylic acid groups with a base, and pending carboxylate ester groups resulting from esterification of free carboxylic acid groups with an epoxysilane, —crosslinking particles made of water-insoluble transition metal compounds. It is also drawn to a method of coating a substrate comprising applying such an aqueous polyurethane dispersion onto a substrate and letting it dry, preferably without applying any heat or radiation.

A method for preparing a thermoplastic polyurethane elastomer material with micro air holes is provided. The method comprises the following steps: (1) is feeding liquid raw materials such as diisocyanate molecules and solid additives into a double-screw reactor to trigger a polymerization type chain extension reaction and then obtain a macromolecular weight hot melt. (2) is pushing the macromolecular weight hot melt into a mixing extruder and allowing the reaction to continue to obtain a macromolecular thermoplastic polyurethane melt. (3) is continuously adding the obtained macromolecular thermoplastic polyurethane melt together with polymer particles into a foaming extruder, and extruding the high-pressure hot melt from a mold head into an underwater granulation chamber. (4) is delivering the particles obtained after granulation into a separator by process water via a multi-stage pressure-release process water pipeline, separating, screening and drying the required particles to obtain the target product.

Embodiments of the present disclosure are directed towards formulated polyol compositions that include a sucrose propoxylated, a propoxylated homopolymer triol, and an amine-initiated polyether alcohol.

A one component spray polyurethane foam formulation containing a polymeric isocyanate with nominal functionality of 2.5 to 3.5, a polyol component that is at least 85 percent aliphatic and having a mole ratio of polyol with three or more functionality to total polyol of 0.2 to 0.75, 15-30 wt % of a plasticizer, 1.5-3.5 wt % phosphorous, 5.5 to 11.5 halogen and 1.5 to 5 millimoles of blowing agent per gram of formulation and that is free of expandable graphite achieves a B2 rating in DIN 4102 testing.

A process for preparing a polyurethane product, and polyurethane compositions and products of the process. The process includes preparing a catalyst composition comprising at least one tertiary amine salt, wherein the at least one tertiary amine salt is a contact product of at least one carboxylic acid and at least one tertiary amine, wherein the at least one tertiary amine is selected from the group consisting of N-hydroxyethylpiperidine and tris(dimethylaminomethyl)phenol; and reacting at least one isocyanate, at least one polyol and the catalyst composition to form a polyurethane product.

Embodiments of the present disclosure are directed towards formulated polyol compositions that include a sucrose propoxylated polyol, a polyether triol, and a propoxylated homopolymer triol.