The present invention provides multilayer coated substrates, prepared using primer and/or sealer compositions comprising waterborne curable film-forming compositions, in turn comprising: a) an aqueous dispersion of a pigment and i) polymeric urethane-shell particles having a care-shell morphology and having hydroxyl functional groups, wherein the core is prepared from a monomer mixture comprising hydrophobic, ethylenically unsaturated monomers and the shell comprises a polyurethane or polyurethane-urea polymer; or ii) polymeric acrylic-shell particles having a core-shell morphology and having hydroxyl functional groups, wherein the core is prepared from a monomer mixture comprising hydrophobic, ethylenically unsaturated monomers and the shell is prepared from a monomer mixture comprising hydrophilic, ethylenically unsaturated monomers; b) a polyisocyanate crosslinking agent; and optionally c) a hydroxyl functional, water dispersible acrylic polymer.

A multi-layer coating system includes: a first basecoat layer formed from a first coating composition including a free polyisocyanate having a weight average molecular weight of less than 600 g/mol and hydroxyl functional polymeric core-shell particles, where an amount of free polyisocyanate having a weight average molecular weight of less than 600 g/mol is 3.5 weight % or greater; a second basecoat layer formed from a second coating composition including carboxylic acid functional polymeric core-shell particles; and a topcoat layer formed from a coating composition including a free polyisocyanate and a film-forming resin reactive with the free polyisocyanate.

The present invention relates to a composition for 3D printing and a preparation method therefor. The present invention can provide a composition for 3D printing, which is eco-friendly and has improved biocompatibility, and thus can be used for various applications including microfluidic materials, tooth and blood vessel mimicking materials, wearable device materials, robotic materials, and various other products.

Described herein is a method of manufacturing a one-pack polyurethane dispersion, where the dispersion includes a polyurethane containing hydroxyl groups and at least one group selected from the group consisting of acid groups and polyalkoxylene groups, the acid groups of the polyurethane, if present, being neutralized to an extent from 0 to 100 mol-% of the acid groups; and a fully blocked polyisocyanate; where the method includes obtaining a mixture A; reacting a hydroxy-functional polymer with mixture A, thus-obtaining a mixture B; and neutralizing 0 to 100 mol-% of the acid groups, if contained in mixture B, based on the total amount of acid groups in mixture B. Also described herein are one-pack polyurethane dispersions obtainable according to the method, one-pack coating materials including the same and coated substrates including cured coating materials.

Corrosion resistance coatings and dicyclopentadiene modified ester oligomers useful in corrosion resistant coatings. The corrosion resistant coatings exhibit improved corrosion resistance, improved adhesion, lower toxicity, unlimited pot life, and/or lower volatile organic compounds (VOCs).

The radical curable resin composition contains as essential raw materials a vinyl ester resin (A), an unsaturated monomer (B) with a flash point of 100° C. or higher, a polyisocyanate (C), a polymerization initiator (D), a stabilizer (E), and a polymerization inhibitor (F), the stabilizer being a nitroxy radical, and the polymerization inhibitor being at least one or more compounds represented by General Formula (1) or (2). This radical curable resin composition is excellent in handleability, flexibility, and curability during molding and excellent in storage stability with little change over time in the curability during molding, and can thus be suitably used for molding materials and molded articles obtained therefrom. In General Formulae (1) and (2). R.sup.1 represents a hydrogen atom or a C.sub.1-4 alkyl group, and X.sup.1 and X.sup.2 each independently represent a hydrogen atom, a C.sub.1-4 alkyl group, a hydroxy group, or a methoxy group.

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The laminate adhesive contains a polyisocyanate component and a polyol component. The polyol component contains polyurethane polyol of a reaction product of polyol and a polyisocyanate derivative with an average functional group of more than 2. The polyisocyanate derivative is an araliphatic diisocyanate derivative and/or alicyclic diisocyanate derivative.

Provided is a resin composition for carbon fiber-reinforced plastic molding, which contains a radical curable resin (A) having a hydroxy group, an unsaturated monomer (B), and isophorone diisocyanate. The resin composition for carbon fiber-reinforced plastic molding shows little change in viscosity over time, is excellent in storage stability, and can be used to obtain a molded article excellent in various physical properties such as flexural strength, flexural modulus, and interlayer shear strength by various molding methods. Therefore, the molded article can be suitably used in automobile members, railway vehicle members, aerospace vehicle members, watercraft members, housing equipment members, sports members, vehicle members, construction civil engineering members, casings of office automation equipment, and the like.

The invention relates to a method for producing polyurethanes containing silane groups, to products that can be obtained by means of said method, and to the use of said products for producing cross-linkable binders, in particular for coatings, sealant raw materials, or glue raw materials.

Corrosion resistance coatings and dicyclopentadiene modified ester oligomers useful in corrosion resistant coatings. The corrosion resistant coatings exhibit improved corrosion resistance, proved adhesion, lower toxicity, unlimited pot life, and/or lower volatile organic compounds (VOCs).