A process for producing an object from a precursor comprises the steps of: I) depositing a free-radically crosslinked resin atop a carrier to obtain a ply of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; II) depositing a free-radically crosslinked resin atop a previously applied ply of the construction material to obtain a further ply of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied ply; III) repeating step II) until the precursor is formed; IV) treating the precursor obtained after step III) under conditions sufficient to at least partially trimerize to isocyanurate groups NCO groups present in the free-radically crosslinked resin of the obtained precursor to obtain the object.

The present invention relates to polymerizable compositions which contain components that can be crosslinked both via isocyanurate bonds and by a radical reaction mechanism. The invention further relates to methods by way of which polymers can be produced from said compositions.

Methods, compositions, and kits for adhering polymers and other materials to another material, and in particular to bone or bone-like structures or surfaces. A composition of matter includes a urethane dimethacrylate-methyl methacrylate copolymer with a plurality of first polymer regions based on urethane dimethacrylate and a plurality of second polymer regions based on methyl methacrylate. The method includes placing an orthopedic joint implant having an attachment surface in a joint space, applying a first non-urethane-containing precursor, a second urethane-containing precursor, and a initiator to the attachment surface; contacting the first and second precursors and the initiator with the joint surface; and copolymerizing the first and second precursors and forming an adhesive copolymer and attaching the implant to the joint.

A process comprises (i) providing an isocyanate component A that is a reaction product of an aliphatic polyisocyanate, an aromatic polyisocyanate, an aliphatic polyester polyol, and a polyether polyol; (ii) providing a polyol component B comprising an aliphatic polyester polyol and a polyether polyol; (iii) mixing A and B to form a solventless adhesive (SLA) composition component A and component B each comprises an aliphatic polyester polyol having a viscosity from 800 to 6000 mPa.Math.s at 25° C. and a hydroxyl number from 60 to 180 mg KOH/g; the SLA composition has (a) an initial viscosity at 40° C. from 500 to 1600 mPa.Math.s, (b) an increasing viscosity ratio from 100% to 112% of the initial viscosity after the SLA composition stands at 40° C. for 10 min, and (c) an end viscosity at 40° C. from 120% to 210% of the initial viscosity at 40 min after forming the SLA composition.

Described herein is a polyurethane having an isocyanate group and having C—C double bonds on a side chain, a process for preparing such a polyurethane, and an UV-moisture dual cure polyurethane reactive hotmelt including the polyurethane.

The present invention provides an electron beam curable coating composition comprising: an electron beam curable component (A) which contains 10% by mass or more of a multifunctional (meth)acrylate; and a room temperature curable component (B) which contains 1 to 15% by mass of an isocyanate group and is not cured by electron beam irradiation, wherein a solid content mass ratio of the component (B) to a total amount of the components (A) and (B) is 20 to 55% by mass.

Methods, compositions, and kits for adhering polymers and other materials to another material, and in particular to bone or bone-like structures or surfaces. A composition of matter includes a urethane dimethacrylate-methyl methacrylate copolymer with a plurality of first polymer regions based on urethane dimethacrylate and a plurality of second polymer regions based on methyl methacrylate. The method includes placing an orthopedic joint implant having an attachment surface in a joint space, applying a first non-urethane-containing precursor, a second urethane-containing precursor, and a initiator to the attachment surface; contacting the first and second precursors and the initiator with the joint surface; and copolymerizing the first and second precursors and forming an adhesive copolymer and attaching the implant to the joint.

The disclosure provides a polymerizable composition for optical materials that can achieve a cured product with a high refractive index and a small yellowness index ΔYI even though an aromatic polyisocyanate is used, a transparent resin and a method for producing the same using the polymerizable composition, a lens base material and a method for producing the same using the polymerizable composition, and the like. A polymerizable composition for optical materials, at least including an aromatic polyisocyanate, a polyene compound having two or more ethylenically unsaturated double bonds, and 30 to 80% by mass of a polythiol having three or more mercapto groups; wherein the polymerizable composition has a mercapto group/(isocyanate group+ethylenically unsaturated double bond) equivalent ratio of 1.10 to 1.70.

The present application relates to polyurethane polymers produced by polymerizing a reactant mixture comprising triglycerides of Physaria fendleri, one or more polyisocyanates, and one or more polyols, wherein the triglycerides of Physaria fendleri have a hydroxyl value ranging from 90 milligrams of potassium hydroxide per gram of the triglycerides of Physaria fendleri to 250 milligrams of potassium hydroxide per gram of the triglycerides of Physaria fendleri. The present application also relates to polyester polymers produced by polymerizing a reactant mixture comprising triglycerides of Euphorbia Lagascae, and one or more dicarboxylic acids. Also disclosed are the methods of formation of the polyurethane and polyester polymers, and their use as adhesives.

Provided is a prepreg including: a urethane (meth)acrylate that is a reaction product of a polyisocyanate compound comprising a polymethylene polyphenyl polyisocyanate as an essential component with a hydroxyl group-containing compound comprising, as an essential component, a compound having a hydroxyl group and a (meth)acryloyl group; a polymerization initiator; and carbon fibers. The prepreg is excellent in workability and molding property and can form molded products excellent in various physical properties such as interlayer shear strength and heat resistance. Thus, the prepreg is suitable for use in various molded articles including automotive members.