An embodiment includes a polymer composition comprising a thermoplastic polymer that: (a) is bonded to iodine, (b) includes a vinyl group, and (c) includes urethane linkages. Other embodiments are described herein.

A vat resin for three-dimensional stereolithography printing of a thiourethane polymer part comprising a liquid mixture including a first type of monomer, a second type of monomer, a photolatent base decomposable upon exposure to a light to form a non-nucleophillic base catalyst having a pKa greater than 7, an anionic step-growth polymerization reaction inhibitor having an acidic group configured to form an acid-base pair with the non-nucleophillic base and a light absorber having an absorbance in the liquid mixture that is greater than an absorbance of the photolatent base at a wavelength of the light used for the exposure. Methods of preparing the vat resin and three-dimensional stereolithography printing a thiourethane polymer part using the vat resin are also disclosed.

A method of three-dimensional stereolithography printing a thiourethane polymer part using the vat resin. Adding a resin to a vat of a three-dimensional stereolithography printer, the resin a liquid mixture including: a first type of monomer including two or more thiol functional groups, a second type of monomer including two or more isocyanate functional groups, a photolatent base, an anionic step-growth polymerization reaction inhibitor and a light absorber. The photolatent base is decomposable upon exposure to a light to form a non-nucleophillic base catalyst having a pKa greater than 7. The anionic step-growth polymerization reaction inhibitor has an acidic group configured to form an acid-base pair with the non-nucleophillic base. The light absorber has an absorbance in the liquid mixture that is greater than an absorbance of the photolatent base at a wavelength of the light used for the exposure.

A pre-treatment composition comprising water, reactive crosslinking agents and polyurethane particles polyurethane particles including sulfonated- or carboxylated-diamine groups, isocyanate-generated amine groups, and polyalkylene oxide side-chains. Also disclosed is a pre-treated printable medium comprising a base substrate and the pre-treatment composition, such as described herein, that is applied over, at least, one side of the base substrate, forming an image-receiving surface. Also disclosed is the method for making such printable medium.

An ink composition for ink jet recording includes resin particles of a urethane resin colored with a disperse dye, and the acid value of the urethane resin is 1 KOHmg/g or more and less than 100 KOHmg/g.

A pre-treatment composition comprising water, reactive crosslinking agents and polyurethane particles polyurethane particles including sulfonated- or carboxylated-diamine groups, isocyanate-generated amine groups, and polyalkylene oxide side-chains. Also disclosed is a pre-treated printable medium comprising a base substrate and the pre-treatment composition, such as described herein, that is applied over, at least, one side of the base substrate, forming an image-receiving surface. Also disclosed is the method for making such printable medium.

A method for producing a polyurethane resin includes a reaction step of obtaining a primary product by reacting a polyisocyanate component containing a bis(isocyanatomethyl)cyclohexane with a polyol component containing a low molecular weight polyol having a number average molecular weight of 400 or less and a high molecular weight polyol having an average molecular weight of 2500 or more and 4000 or less under the presence of a bismuth catalyst, and a heat treatment step of heat treating the primary product to obtain a polyurethane resin. The bismuth catalyst content in the polyurethane resin is 0.1 ppm or more and 1000 ppm or less, and the heat treatment conditions in the heat treatment step are 50 C. or more and 100 C. or less and three days or more and ten days or less.

The present disclosure is drawn to reactive polyurethane dispersions. In one example, a reactive polyurethane dispersion can include a polymer strand having a polymer backbone that has two ends terminating at a first capping unit and a second capping unit. The polymer backbone can include polymerized monomers including a reactive diol and a diisocyanate. The reactive diol can be an acrylate-containing diol, a methacrylate-containing diol, an acrylamide-containing diol, a methacrylamide-containing diol, or combination thereof. The first capping unit can be an acrylamide-containing monoalcohol or methacrylamide-containing monoalcohol reacted with an isocyanate group of the diisocyanate. The second capping unit can be an ionic stabilizing group.

The embodiments relate to a polythiol composition for a plastic optical lens and a polythiourethane-based plastic optical lens prepared therefrom. In the embodiments, a first polythiol compound having an ester group and a mercapto group only as a hydrogen-bondable functional group and a second polythiol compound having an ester group and a hydrogen-bondable functional group other than a mercapto group are used in an appropriate amount. Thus, it is possible to control the viscosity of a polymerizable composition at the initial stage of polymerization at a low temperature of 5 to 15 C. and to stabilize the rate of increase in the viscosity of the composition and the reaction rate thereof, thereby preventing the generation of striae, bubbles, and the like. Further, various plastic lenses such as eyeglass lenses, camera lenses, and the like having excellent appearance characteristics (without striae and bubbles) and excellent optical characteristics can be obtained from the composition.

The present invention provides a polyaspartic composition comprising a polyaspartate comprising a reaction product of a polyamine and a diester, and a C.sub.2 to C.sub.12 diol. The inventive polyaspartic compositions may be combined with polyisocyanates to produce polyurea coatings, adhesives, sealants, composites, castings, and films.