A polyurethane resin composition includes a reaction product of an aliphatic polyisocyanate derivative having an average number of isocyanate groups of 2 or more; a long-chain active hydrogen compound including a hydrocarbon group having 12 or more and 30 or less carbon atoms and an active hydrogen group in combination; a cationic active hydrogen compound including an active hydrogen group and a cationic group in combination; and an acid compound capable of a salt with the cationic group. The concentration of the hydrocarbon group is 30% or more and 85% or less.

A urethane compound (A) including units formed from (A1) an isocyanate and (A2) a long-chain alcohol represented by the formula HO—Z(Y—R).sub.n [wherein the R moieties are each independently —O—, —NH—, —O—C(═O)—, —NH—C(═O)—, —C(═O)—NH—, —O—C(═O)—NH—, —NH—C(═O)—O—, —NH—C(═O)—NH—, —NH—S(═O).sub.2—, —S(═O).sub.2—NH—, —NH—(CH.sub.2).sub.m—NH—S(═O).sub.2—, —NH—(CH.sub.2).sub.m—S(═O).sub.2—NH—, etc. (m is an integer of 1-5), Z is a direct bond or a di- or trivalent hydrocarbon group having 1-5 carbon atoms, and n is 1 or 2]. Also disclosed is a urethane mixture containing the urethane compound (A), and at least one selected from the polyisocyanate (A1), the long-chain alcohol (A2), a blocking agent (A3) and an alcohol compound (A4); an aqueous urethane composition; a method for producing the aqueous urethane composition; a method of treating a substrate; and a treated textile product.

The invention relates to a composition for preparing a flexible foam and its application. The composition comprises the following components: a. an isocyanate mixture; b. a polymer polyol mixture; c. an isocyanate-reactive group-containing compound having a number average molecular weight of 32-400 g/mol; d. an aqueous alkali metal salt and/or ammonium bicarbonate solution, having a concentration of greater than or equal to 1.5 wt % and less than 30 wt %, and a pH value of less than 9.5; and e. a metal catalyst; wherein the amount of the tertiary amine catalyst in the composition is not more than 0.1 wt %, and the isocyanate index of the composition is 70-120. The composition has a high reaction efficiency and can meet the quantitative production requirements of the textile industry. The flexible foam prepared from the composition has a good phenolic yellowing resistance, and can meet the comprehensive requirements of the textile industry for a high rebound resilience, a good gas permeability, a ultraviolet yellowing resistance and the like of the foam.

In a structural polyurethane adhesive, a polyisocyanate component contains a first prepolymer component containing a first isocyanate group-terminated urethane prepolymer which is a reaction product of a first material polyisocyanate consisting of an aromatic polyisocyanate, and a first material polyol containing a macropolyol; and a second prepolymer component containing a second isocyanate group-terminated urethane prepolymer which is a reaction product of a second material polyisocyanate consisting of an araliphatic polyisocyanate and/or an aliphatic polyisocyanate, and a second material polyol containing a polyether polyol having a number average molecular weight of 160 or more and 4800 or less. A ratio of the second prepolymer component with respect to the total amount of the first prepolymer component and the second prepolymer component is 2% by mass or more and 35% by mass or less.

The invention relates to a method for producing an object from a construction material, the construction material comprising radically crosslinkable groups, NCO groups and groups having Zerewitinoff active H atoms, and the object being a three-dimensional object and/or a layer. During and/or after the production of the object, the construction material is heated to a temperature of >50° C., and the construction material comprises one or more cyclic tin compounds of formula F-I, F-II and/or F-III.

An object of the present invention is to provide a coating composition capable of forming a coating film which can maintain its appearance and gloss over a long period and which has high film hardness and high flexibility and exhibits excellent adhesion with respect to an epoxy resin anticorrosive coating film. An acrylic polysiloxane resin coating composition of the invention includes (A) a silicone resin, (B) a compound having one or more functional groups capable of undergoing Michael addition reaction with an unsaturated double bond in an acryloyloxy group, and having one or more alkoxy groups bonded to silicon, (C) a trifunctional or polyfunctional aliphatic urethane acrylate oligomer having a cyclic structure, and (D) a bifunctional acrylate monomer having no ether structures (except an ether structure in an acryloyloxy group) and no aromatic rings, the mass ratio of the total amount of (A) and (B) to the total amount of any acrylate oligomer(s) and any acrylate monomer(s) being 40:60 to 70:30.

A process for producing an object from a precursor comprises the steps of: I) depositing a free-radically crosslinked resin atop a carrier to obtain a ply of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; II) depositing a free-radically crosslinked resin atop a previously applied ply of the construction material to obtain a further ply of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied ply; III) repeating step II) until the precursor is formed; IV) treating the precursor obtained after step III) under conditions sufficient to at least partially trimerize to isocyanurate groups NCO groups present in the free-radically crosslinked resin of the obtained precursor to obtain the object.

The invention relates to a crystallization stable polyester prepolymers for producing HDI- and PDI-based, solvent free two component (2K)-polyurethane- and/or polyurea coating agents.

An adhesive includes: a urethane prepolymer (A) obtained by reacting a polyol (a) with a polyisocyanate (b) under such conditions that the molar ratio of NCO/OH is 0.5-0.9 and having a molecular-weight dispersion degree [(weight-average molecular weight (Mw))/(number-average molecular weight (Mn)); hereinafter referred to also as Mw/Mn] of 4-12; a polyfunctional polyol (B), and an isocyanate curing agent (C).

An adhesive includes: a urethane prepolymer (A) obtained by reacting a polyol (a) with a polyisocyanate (b) under such conditions that the molar ratio of NCO/OH is 0.5-0.9 and having a molecular-weight dispersion degree [(weight-average molecular weight (Mw))/(number-average molecular weight (Mn)); hereinafter referred to also as Mw/Mn] of 4-12; a polyfunctional polyol (B), and an isocyanate curing agent (C).