The invention relates to a crystallization stable polyester prepolymers for producing HDI- and PDI-based, solvent free two component (2K)-polyurethane- and/or polyurea coating agents.

A multi-layer coating system includes: a first basecoat layer formed from a first coating composition including a free polyisocyanate having a weight average molecular weight of less than 600 g/mol and hydroxyl functional polymeric core-shell particles, where an amount of free polyisocyanate having a weight average molecular weight of less than 600 g/mol is 3.5 weight % or greater; a second basecoat layer formed from a second coating composition including carboxylic acid functional polymeric core-shell particles; and a topcoat layer formed from a coating composition including a free polyisocyanate and a film-forming resin reactive with the free polyisocyanate.

Polyurethane coating compositions are disclosed that include an isocyanate-reactive component that includes a polycyclic polyether polyol that is the reaction product of a reaction mixture that includes a polycyclic polyol starter, and an alkylene oxide, as well as an isocyanate-functional component that includes a non-aromatic polyisocyanate. The polyurethane coating compositions may be particularly useful as a gel coat in the manufacture of glass fiber reinforced plastics.

The invention relates to a catalyst component for isocyanate modification, comprising at least one cyclic ammonium salt having a cation of the formula I wherein Y is a linear or branched C.sub.2-C.sub.20 segment which is substituted by a hydroxyl group in the 2 position to the charge-bearing nitrogen atom and optionally bears further substituents and is optionally interrupted by heteroatoms from the group of oxygen, sulfur, nitrogen and aromatic rings and optionally has further rings, and the N-bonded substituents R.sup.1 and R.sup.2 are either independently identical or different, substituted or unsubstituted, optionally branched, aliphatic C.sub.1-C.sub.20 radicals, aromatic C.sub.6-C.sub.20 radical or araliphatic C.sub.7-C.sub.20 radicals or the N-bonded substituents R.sup.1 and R.sup.2 form a ring segment X with one another for which the same or different definition given above for Y is applicable, with the proviso that X has a hydroxyl group as substituent in the 2 position to the charge-bearing nitrogen atom or does not have a hydroxyl group as substituent in the 2 position to the charge-bearing nitrogen atom.

A moisture-curable polyurethane hot melt adhesive composition having good oleic acid resistance, especially when exposed to 100% pure oleic acid under aging condition of 65° C. and 90% relative humidity, wherein the adhesive composition comprises, consists essentially of or consists of a moisture-curable polyurethane prepolymer, the prepolymer being a reaction product of at least one amorphous polyester polyol containing an aromatic group and at least one polyisocyanate, preferably at least one polyisocyanate containing an aromatic group, wherein the aromatic group is comprised in the polyurethane prepolymer in a content of no less than 23 wt. %, preferably no less than 25 wt. %, more preferably no less than 30 wt. %.

A method of producing a reinforced polymer composite includes placing reinforcement solids a die defining a die cavity. A liquid reaction mixture including an aromatic polyisocyanate and initiating reaction of said aromatic polyisocyanate is infused with a catalyst composition forming an aromatic isocyanurate based polymer reaction mixture impregnates the reinforcing solids with using the cavity for forming the aromatic isocyanurate based polymer reaction mixture. The cavity defined by the die is heated to at least 80° C. for a period required to form a polymer reaction product producing the reinforced polymer composite.

The present invention relates to a process for the effective removal of residual monomeric aliphatic isocyanate from a reaction mixture comprising aliphatic polyisocyanate comprising (i) providing a reactor containing a scavenger comprising a zeolitic material, wherein the zeolitic material comprises SiO.sub.2 and optionally X.sub.2O.sub.3 in its framework structure, wherein X is a trivalent element; (ii) providing a reaction mixture comprising aliphatic polyisocyanate and monomeric aliphatic isocyanate; (iii) contacting the scavenger in the reactor with the reaction mixture provided in (ii) at a temperature lower than the boiling point of the residual monomeric aliphatic isocyanate for obtaining a product comprising aliphatic polyisocyanate with a reduced monomeric aliphatic isocyanate content, wherein if the zeolitic material comprises X.sub.2O.sub.3, the zeolitic material has an SiO.sub.2 to X.sub.2O.sub.3 molar ratio higher than 2.8:1, preferably higher than 5:1, more preferably higher than 30:1.

Described herein are silane-based coating compositions, particularly clearcoat compositions, including a metal alkoxide catalyst. Also described herein are silane-based coating compositions, particularly clearcoat compositions, including a silane-based compound having two different alkoxysilane moieties. Further, described herein are a method of coating substrates with such coating compositions and coated substrates obtained by said method. Finally, described herein are multilayer coatings and substrates coated with said multilayer coatings.

The present disclosure provides a two-part composition polymeric material including a first part and a second part. The first part includes an inorganic filler and a polymeric material including a polymerized reaction product of a polymerizable composition including components. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; and an optional second hydroxyl-containing compound having a single OH group. The second part includes a polythiol having an average sulfhydryl group functionality of 2 or greater. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymerized product of the two-part composition and a battery module. Advantageously, two-part compositions can be used as coatings and adhesive systems including high loadings of inorganic filler, such as thermally conductive filler, with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.

The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components and an inorganic filler. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; and an optional second hydroxyl-containing compound having a single OH group. The present disclosure also provides a two-part composition, in which the polymeric material is included in the first part and the second part includes at least one amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymerized product of the two-part composition and a battery module. Advantageously, two-part compositions can be used as coatings and adhesive systems including high loadings of inorganic filler, such as thermally conductive filler, with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.