A polyurethane adhesive composition that includes a polyurethane prepolymer that includes the reaction product of a first polyol component that includes glycerol monoester and a polyisocyanate, and a second polyol. A polyurethane prepolymer that includes the reaction product of glycerol monoester, a hydroxy functional triglyceride, and a poly isocyanate.

The present invention relates to curable polyurethane polymers made from renewable materials. In particular hydroxylated oleaginous materials derived from plant oils, such as soybean oil, are used. These renewable materials may be formed into curable polyurethane polymers having different chemical functionalities and cure mechanisms.

The invention relates to a method of making parts of construction materials by using a mold coated with multiple resin-based layers comprising at least an epoxy resin-based primer and a polyurethane resin-based demolding layer, wherein the mold can be used for multiple cycles after curing and demolding. The invention also relates to the resin-coated mold and the cured parts of construction materials having smooth surface made thereof.

The present invention relates to curable polyurethane polymers made from renewable materials and having polymerization accelerator groups built into the polymer. In particular hydroxylated oleaginous materials derived from plant oils, such as soybean oil, are used. These renewable materials may be formed into curable polyurethane polymers having different chemical functionalities and cure mechanisms.

This invention relates to a composition for a preparation of polyurethane dispersion, comprising bio-based polyol as shown in structure (I) and polyhydroxy fatty acid compound as shown in structure (II): wherein, R represents a polyhydric alcohol unit that is selected from aliphatic polyhydric alcohol, alicyclic polyhydric alcohol, cyclic polyhydric alcohol, aromatic polyhydric alcohol, or optionally, cyclic polyhydroxyl having heteroatom; R\ represents a hydrocarbon unit obtained from a molecular chain of unsaturated fatty acid having 14-24 carbon atoms and having from 1-6 pairs of vicinal diol group per one molecular chain of such unsaturated fatty acid; n represents an integer from 2 to 8 of an ester group obtained from a reaction of polyhydric alcohol and unsaturated fatty acid; wherein said composition is prepared from a process comprising the steps of: i. mixing fatty acid comprising unsaturated fatty acid and polyhydric alcohol at a ratio of 1 mole equivalent or more of carboxylic group from unsaturated fatty acid per a hydroxy group from polyhydric alcohol; ii. adding organic acid and peroxide compound into the mixture from step i.; iii. adding nucleophilic substance into the mixture from step ii. under acidic condition. ##STR00001##

This invention relates to a composition for a preparation of polyurethane dispersion, comprising bio-based polyol as shown in structure (I) and polyhydroxy fatty acid compound as shown in structure (II): wherein, R represents a polyhydric alcohol unit that is selected from aliphatic polyhydric alcohol, alicyclic polyhydric alcohol, cyclic polyhydric alcohol, aromatic polyhydric alcohol, or optionally, cyclic polyhydroxyl having heteroatom; R\ represents a hydrocarbon unit obtained from a molecular chain of unsaturated fatty acid having 14-24 carbon atoms and having from 1-6 pairs of vicinal diol group per one molecular chain of such unsaturated fatty acid; n represents an integer from 2 to 8 of an ester group obtained from a reaction of polyhydric alcohol and unsaturated fatty acid; wherein said composition is prepared from a process comprising the steps of: i. mixing fatty acid comprising unsaturated fatty acid and polyhydric alcohol at a ratio of 1 mole equivalent or more of carboxylic group from unsaturated fatty acid per a hydroxy group from polyhydric alcohol; ii. adding organic acid and peroxide compound into the mixture from step i.; iii. adding nucleophilic substance into the mixture from step ii. under acidic condition.

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A polyurethane is obtained by continuously reacting a polyurethane prepolymer in an asphalt or asphalt mixture material system under high temperature. The prepolymer is prepared by: adding a polymerization inhibitor, catalyst and isocyanate component in a reaction container, adding a polyol to the reactor while stirring at room temperature under nitrogen, increasing the temperature to 50-80 C., and maintaining the temperature to react for 0.5-6 hours. A polyurethane modified asphalt, a mixture material containing the polyurethane and a polyurethane modified asphalt pavement structure can be prepared. The synthesis condition of the polyurethane is mild, and a secondary reaction with the air and an active hydrogen component in the asphalt can occur during maintenance and formation to further increase the strength of a mixture material. The standard Marshall stability at 60 C. meets the petroleum asphalt requirement, such that a service life of the asphalt pavement can be increased.

The present invention relates to curable polyurethane polymers made from renewable materials and having polymerization accelerator groups built into the polymer. In particular hydroxylated oleaginous materials derived from plant oils, such as soybean oil, are used. These renewable materials may be formed into curable polyurethane polymers having different chemical functionalities and cure mechanisms.

The present invention relates to the synthesis of porous polymer scaffold from polyethyleneglycol-polyurethane having castor oil linkages under controlled conditions and their use as stem cell delivery vehicles thereby accelerating the tissue regeneration process. The present invention further studies the biodegradability, stability and biocompatibility of porous polymer scaffolds in various cell lines and primary bone marrow stem cells. Particularly the present invention further relates to the physio-chemical characterization of the porous polymer scaffolds.

The present invention relates to a method for producing flexible polyurethane foams, wherein an isocyanate component (component B) which comprises fatty acid derivatives comprising hydroxyl groups is used as starting substance. The flexible polyurethane foams according to the invention have a bulk density according to DIN EN ISO 3386-1-98 in the range of 10 kg/m.sup.3 to 150 kg/m.sup.3, preferably 20 kg/m.sup.3 to 70 kg/m.sup.3, and in general their compressive strength according to DIN EN ISO 3386-1-98 is in the range of 0.5 kPa to 20 kPa (at 40% deformation and 4th cycle). The invention also provides an NCO-terminated prepolymer comprising urethane groups obtainable by reaction of one or more polyisocyanates (B1) with one or more fatty acid derivatives comprising hydroxyl groups (B2).