A silicate modified polymer foam material for filling and sealing contains prepolymerized isocyanate and a silicate modified aqueous solution with a mass ratio in a range of 1:(1.2-1.4). In the prepolymerized isocyanate, a mass percentage of P is 4.4%, a mass percentage of N is 7.9%, and a mass percentage of —NCO is 11.9%. The silicate modified aqueous solution includes liquid sodium silicate, small molecule alcohol, water and a catalyst, wherein the liquid sodium silicate, the small molecule alcohol, the water and the catalyst account for 63-66%, 17-20%, 14-17% and 1.5-2.5% of the weight of the silicate modified aqueous solution respectively. A method of preparing the silicate modified polymer foam material for filling and sealing includes mixing the prepolymerized isocyanate with the silicate modified aqueous solution.

The present invention relates to a silicate-modified high-toughness and low-heat polymer grouting material for reinforcement, which belongs to the technical field of materials. About 60% by weight of the raw materials of the silicate modified grouting material of the present invention is the silicate modified aqueous solution, and about 40% is the structural flame retardant isocyanate, and main components of the polymer grouting material are classified into inorganic components according to the main total proportion. The silicate-modified high-toughness and low-heat polymer grouting material for reinforcement of the present invention has excellent flame retardancy and compressive performance, wherein a compressive strength is ≥60 MPa, an oxygen index is ≥30%, and a maximum reaction temperature is ≤100° C., an odor grade (80° C.) is ≤3.5, a fog test is ≤5 mg (no physical additive flame retardant diffuses to the environment), bonding is ≥3 MPa, a shear strength is ≥20 MPa, and a tensile strength is ≥20 MPa.

Two-component solventless polyurethane adhesive compositions comprising an isocyanate component and an isocyanate-reactive are disclosed, the compositions comprising an isocyanate component comprising an isocyanate-terminated prepolymer and an isocyanate-reactive component comprising a hydroxy-terminated polyurethane resin, a polyether polyol, a phosphate ester adhesion promoter, and, optionally, a bio-based polyol. Methods for forming laminate structures are also disclosed, the methods comprising forming an adhesive composition by mixing an isocyanate adhesive component comprising an isocyanate-terminated prepolymer and an isocyanate-reactive adhesive component comprising a hydroxy-terminated polyurethane resin, a polyether polyol, a phosphate ester adhesion promoter, and optionally, a bio-based polyol, applying the adhesive composition to a surface of a first substrate, and bringing a surface of a second substrate into contact with the adhesive composition on the surface of the first substrate, thereby forming the laminate structure. Laminate structures are also disclosed.

Provided is a method for producing a resin lens, comprising: A) mixing a polyisocyanate, a modified isocyanate, a catalyst and a release agent, and performing vacuum defoaming at 0˜30° C. for 10˜90 min to obtain a material a; B) mixing the material a with a sulfur-containing compound, and performing vacuum defoaming at 15˜20° C. for 20˜120 min to obtain mixed monomers; and C) completing casting of the mixed monomers, and curing to obtain a resin lens. The present disclosure uses polyisocyanate and a modified isocyanate at the same time to prepare a resin lens with higher glass transition temperature and higher surface hardness without producing bank mark and edge fogging. The present disclosure further provides a method for producing modified isocyanate. The obtained modified isocyanate used with polyisocyanate further improves the glass transition temperature and surface hardness of the resin lens without producing bank mark and edge fogging.

A polymerizable composition for an optical material containing two or more different monomers for an optical material, and a polymerization catalyst, in which at least one of the two or more different monomers for an optical material is an isocyanate compound containing an aromatic ring, a content of the polymerization catalyst with respect to a total of 100 parts by mass of the two or more different monomers for an optical material is from 0.010 parts by mass to 0.50 parts by mass, and the viscosity measured by a B-type viscometer at 25° C. and 60 rpm is from 10 mPa.Math.s to 1,000 mPa.Math.s.

Disclosed are (2,2-dimethyl-1,3-dioxolan-4-yl)methyl 2-bromo-2,2-difluoroacetate, a waterborne polyurethane, and preparation methods thereof. The (2,2-dimethyl-1,3-dioxolan-4-yl)methyl 2-bromo-2,2-difluoroacetate could be used as a modified monomer for preparing a waterborne polyurethane, and substituents at a C2 position of the (2,2-dimethyl-1,3-dioxolan-4-yl)methyl 2-bromo-2,2-difluoroacetate are two fluorine atoms and one bromine atom. When it is used for preparing the waterborne polyurethane, fluorine and bromine groups are introduced into the structure of the waterborne polyurethane, and the resultant waterborne polyurethane exhibits good moisture resistance and flame retardance.

A polymerizable composition for an optical material containing two or more different monomers for an optical material, and a polymerization catalyst, in which at least one of the two or more different monomers for an optical material is an isocyanate compound containing an aromatic ring, a content of the polymerization catalyst with respect to a total of 100 parts by mass of the two or more different monomers for an optical material is from 0.010 parts by mass to 0.50 parts by mass, and the viscosity measured by a B-type viscometer at 25° C. and 60 rpm is from 10 mPa.Math.s to 1,000 mPa.Math.s.

The invention relates to compounds and methods for extending the pot life of mixtures of isocyanates and isocyanate-reactive compounds when using acidic phosphoric acid ester as a mould release agent.

An isocyanate compound containing a phosphate functional group obtainable or obtained by the reaction of at least one selected from the group consisting of an isocyanate monomer, an isocyanate adduct and combinations thereof, with a phosphate functional polyol is provided. Also provided are an adhesive composition comprising the isocyanate compound, cured adhesive compositions, methods of producing cured laminates, the so produced cured laminates and use of the isocyanate compound in a two-component solvent-based adhesive composition.

A crosslinked polymeric composition comprising A, B, C, D, and E units having the following structures, respectively:

##STR00001##

##STR00002##

##STR00003##

##STR00004##

##STR00005##

wherein dashed bonds represent optional bonds; the asterisks (*) in C units represent covalent bond connection points with asterisks in A units and E units; the asterisks (*) in D units represent covalent bond connection points with asterisks in B units and E units; wherein a portion of E units are bound to C units, a portion of E units are bound to D units, and a portion of E units are bound to both C and D units; and the composition contains a multiplicity of A, B, C, D, and E units. Also described is a method for producing the crosslinked polymeric composition by reacting epoxy-containing molecules (A molecules), isocyanate-containing molecules (B molecules), and disulfide-containing molecules (C molecules).