Embodiments of the disclosure generally provide compositions and methods related to oligomeric and polymeric urethane materials that contain hydrolyzable polythioaminal groups for use in biomedical applications.

Embodiments of the disclosure generally provide compositions and methods related to oligomeric and polymeric urethane materials that contain hydrolyzable polythioaminal groups for use in biomedical applications.

A roll excellent in abrasion resistance, which contains: a resin layer containing a first atom group having a plurality of sulfur atoms, a plurality of second atom groups having a carbon chain that has a plurality of carbon atoms arranged in a line and has an end bonded to any one of the plurality of sulfur atoms, and a plurality of third atom groups each of which has a urethane bond and is bonded to any one of the plurality of second atom groups; and a cylindrical foamed resin having an outer surface covered with the resin layer.

Thermally vulcanisable, meltable adhesives and processes have a meltable polybutadiene-polyurethane, ground sulphur and optionally at least one vulcanisation accelerator, at least one filling material, at least one epoxide resin, at least one tackifier resin, bitumen, at least one softener and further auxiliary and additive materials, wherein said adhesives and processes can be thermally vulcanised within a temperature range of 130° C. to 230° C., such that same, as well as an adhesive strip produced from same, can be used for adhesion and/or sealing in the automotive industry, as well as in structural work on oiled sheet metal, and in the painting line on e-coated or otherwise painted sheet metal, for example, for crimp fold adhesion, for crimp fold sealing, for seam sealing, for lining adhesion, for hole closure and much more.

Thermally vulcanisable, meltable adhesives and processes have a meltable polybutadiene-polyurethane, ground sulphur and optionally at least one vulcanisation accelerator, at least one filling material, at least one epoxide resin, at least one tackifier resin, bitumen, at least one softener and further auxiliary and additive materials, wherein said adhesives and processes can be thermally vulcanised within a temperature range of 130° C. to 230° C., such that same, as well as an adhesive strip produced from same, can be used for adhesion and/or sealing in the automotive industry, as well as in structural work on oiled sheet metal, and in the painting line on e-coated or otherwise painted sheet metal, for example, for crimp fold adhesion, for crimp fold sealing, for seam sealing, for lining adhesion, for hole closure and much more.

The present invention pertains to: a functionalized thermoplastic polyurethane containing a novel chain extender having functionality capable of chemically bonding to a prepolymer polymerized by reacting a polyol (P) with a diisocyanate (R); a functional composite material containing one or more monomers or polymers selected from the group consisting of an anionic functional group, an amphoteric functional group, a perfluorinated compound, a hydrogel, and a silicone polymer; a method for producing same; and an article including same.

The invention relates to a high-strength and permanently elastic curable adhesive for bonding at least two surfaces, of which at least one surface is a surface of a permanently elastic plastic, wherein the adhesive is an adhesive that cures in at least two different hardening mechanisms, wherein the first hardening mechanism comprises a chemical reaction to form a chemical bond including a sulphur atom, and the second hardening mechanism comprises the formation of crystalline structures from amorphous polymers. The invention also relates to a method for high-strength and permanently elastic bonding of at least two surfaces to one another, of which at least one surface is that of a permanently elastic plastic, by means of such an adhesive, said method comprising the steps of: applying the adhesive to at least a first of the surfaces to be connected, ensuring conditions under which at least the first hardening mechanism of the adhesive can take place, bringing the first surface into contact with the second surface, and ensuring conditions under which the second hardening mechanism of the adhesive can take place.

The invention relates to a high-strength and permanently elastic curable adhesive for bonding at least two surfaces, of which at least one surface is a surface of a permanently elastic plastic wherein the adhesive is an adhesive that cures in at least two different hardening mechanisms, wherein the first hardening mechanism comprises a chemical reaction to form a chemical bond including a sulphur atom, and the second hardening mechanism comprises the formation of crystalline structures from amorphous polymers. The invention also relates to a method for high-strength and permanently elastic bonding of at least two surfaces to one another, of which at least one surface is that of a permanently elastic plastic, by means of such an adhesive, said method comprising the steps of: applying the adhesive to at least a first of the surfaces to be connected, ensuring conditions under which at least the first hardening mechanism of the adhesive can take place, bringing the first surface into contact with the second surface, and ensuring conditions under which the second hardening mechanism of the adhesive can take place.

An object of the present invention is to provide a polyurethane urea elastic fiber with high elasticity and excellent textile property stability over time by modifying the ends of the polyurethane urea polymer molecular chain, and to provide a method for producing such a polyurethane urea elastic fiber. Another object of the present invention is to provide a polyurethane urea elastic fiber that allows for easier inventory control and processing condition management of fibers when it is used, and that can be used to obtain fabrics with stable fabric characteristics and fabric quality, and to provide a method for producing such a polyurethane urea elastic fiber.

[Solution] A polyurethane urea elastic fiber comprising: polyurethane urea polymer A having a molecular chain using a polymer diol, a diisocyanate, and an organic amine as starting materials, and having a primary or secondary amino group at both ends of the molecular chain; and polyurethane urea polymer B having a molecular chain using a polymer diol, a diisocyanate, and an organic amine, and having a sulfonic acid amine salt on at least one end of the molecular chain.

An object of the present invention is to provide a polyurethane urea elastic fiber with high elasticity and excellent textile property stability over time by modifying the ends of the polyurethane urea polymer molecular chain, and to provide a method for producing such a polyurethane urea elastic fiber. Another object of the present invention is to provide a polyurethane urea elastic fiber that allows for easier inventory control and processing condition management of fibers when it is used, and that can be used to obtain fabrics with stable fabric characteristics and fabric quality, and to provide a method for producing such a polyurethane urea elastic fiber.

[Solution] A polyurethane urea elastic fiber comprising: polyurethane urea polymer A having a molecular chain using a polymer diol, a diisocyanate, and an organic amine as starting materials, and having a primary or secondary amino group at both ends of the molecular chain; and polyurethane urea polymer B having a molecular chain using a polymer diol, a diisocyanate, and an organic amine, and having a sulfonic acid amine salt on at least one end of the molecular chain.