C08G2261/212

Hydrogenated norbornene ring-opened polymer, and method of producing the same
11807712 · 2023-11-07 · ·

Disclosed is a hydrogenated norbornene ring-opened polymer, wherein a proportion of a norbornene-derived repeating unit is 90% by mass or more, a meso diad fraction of the norbornene-derived repeating unit is 80% or more, and in an X-ray diffraction pattern measured at 25° C. using a CuKα radiation source, an X-ray diffraction peak is observed which has a peak top positioned in a diffraction angle (2θ) range of 17° or more and 18° or less.

Cyclopentene monomers and methods of polymerization

Cyclopentene monomers and methods of polymerization, including the polymerization of the cyclopentene monomers. The cyclopentene monomers include allylic substituted cyclopentene monomers that may be racemic or enantiopure. The methods of polymerization may permit the resulting polymers to have one or more desirable structural features.

COMPOSITE MATERIAL, CONDUCTIVE MATERIAL, CONDUCTIVE PARTICLES, AND CONDUCTIVE FILM
20210193347 · 2021-06-24 ·

The present invention provides a composite material having excellent dispersibility in a solvent and increased conductivity. The composite material comprises a carbon material and a conductive dispersant physically or chemically bonded to the carbon material, the conductive dispersant is constituted by a conductive polymer, and the conductive polymer has a number average molecular weight of 2000 or more and 100000 or less.

Fluorine substitution influence on benzo[2,1,3]thiodiazole based polymers for field-effect transistor applications

Four conjugated copolymers with a donor/acceptor architecture including 4,4-dihexadecyl-4H-cyclopenta[1,2-b:5,4-b]dithiophene as the donor structural unit and benzo[2,1,3]thiodiazole fragments with varying degrees of fluorination have been synthesized and characterized. It has been shown that the HOMO levels were decreased after the fluorine substitution. The field-effect charge carrier mobility was similar for all polymers with less than an order of magnitude difference between different acceptor units.

HYDROGENATED NORBORNENE RING-OPENED POLYMER, AND METHOD OF PRODUCING THE SAME
20200399422 · 2020-12-24 · ·

Disclosed is a hydrogenated norbornene ring-opened polymer, wherein a proportion of a norbornene-derived repeating unit is 90% by mass or more, a meso diad fraction of the norbornene-derived repeating unit is 80% or more, and in an X-ray diffraction pattern measured at 25 C. using a CuK radiation source, an X-ray diffraction peak is observed which has a peak top positioned in a diffraction angle (2) range of 17 or more and 18 or less.

Coaxial semiconductive organic nanofibers and electrospinning fabrication thereof

A coaxial nanocomposite including a core, which includes fibers of a first organic polymer, and a shell, which includes fibers of a second organic polymer, the first polymer and the second polymer forming a heterojunction.

FLUORINE SUBSTITUTION INFLUENCE ON BENZO[2,1,3]THIODIAZOLE BASED POLYMERS FOR FIELD-EFFECT TRANSISTOR APPLICATIONS

Four conjugated copolymers with a donor/acceptor architecture comprising 4,4-dihexadecyl-4H-cyclopenta[1,2-b:5,4-b]dithiophene as the donor structural unit and benzo[2,1,3]thiodiazole fragments with varying degrees of fluorination have been synthesized and characterized. It has been shown that the HOMO levels were decreased after the fluorine substitution. The field-effect charge carrier mobility was similar for all polymers with less than an order of magnitude difference between different acceptor units.

Solution process for fabricating high-performance organic thin-film transistors

The present invention relates to a solution or ink composition for fabricating high-performance thin-film transistors. The solution or ink comprises an organic semiconductor and a mediating polymer such as polyacrylonitrile, polystyrene, or the like or mixture thereof, in an organic solvent such as chlorobenzene or dichlorobenzene. The percentage ratio by weight of semiconductor:mediating polymer ranges from 5:95 to 95:5, and preferably from 20:80 to 80:20. The solution or ink is used to fabricate via solution coating or printing a semiconductor film, followed by drying and thermal annealing if necessary to provide a channel semiconductor for organic thin-film transistors (OTFTs). The resulting OTFT device with said channel semiconductor has afforded OTFT performance, particularly field-effect mobility and current on/off ratio that are superior to those OTFTs with channel semiconductors fabricated without a mediating polymer.

Method of selective separation of semiconducting carbon nanotubes, dispersion of semiconducting carbon nanotubes, and electronic device including carbon nanotubes separated by using the method

According to example embodiments, a method includes dispersing carbon nanotubes in a mixed solution containing a solvent, the carbon nanotubes, and a dispersant, the carbon nanotubes including semiconducting carbon nanotubes, the dispersant comprising a polythiophene derivative including a thiophene ring and a hydrocarbon sidechain linked to the thiophene ring. The hydrocarbon sidechain includes an alkyl group containing a carbon number of 7 or greater. The hydrocarbon sidechain may be regioregularly arranged, and the semiconducting carbon nanotubes are selectively separated from the mixed solution. An electronic device includes semiconducting carbon nanotubes and the foregoing described polythiophene derivative.

Cyclopentene Monomers and Methods of Polymerization
20190185603 · 2019-06-20 ·

Cyclopentene monomers and methods of polymerization, including the polymerization of the cyclopentene monomers. The cyclopentene monomers include allylic substituted cyclopentene monomers that may be racemic or enantiopure. The methods of polymerization may permit the resulting polymers to have one or more desirable structural features.