A process for manufacturing an aromatic diether, including the reaction of a compound A including at least two halogenated aromatic groups with a compound B, B being an aromatic alkoxide, optionally in the presence of a compound C acting as reaction solvent, the molar proportion of compound B to compound A being at least 2:1 and the molar amount of compound C to compound A being, where appropriate, not more than 10:1. Also, a process for manufacturing a polyaryl ether ketone.

A method for producing polyether ketone ketone at a high yield is disclosed. According to the method, a catalyst injection rate is controlled during production to suppress scale formation, whereby the yield can be improved. A polyether ketone ketone produced by the method is disclosed. The method makes it possible to maintain an intrinsic viscosity (IV) of the polymer without a significant change and adjust a particle size of polyether ketone ketone by preventing an aggregation between resin particles, thereby suppressing scale formation.

A method for forming a polyaryletherketone is described. More particularly, a reaction mixture is initially supplied to the reactor vessel that contains one or more precursor monomers. A heteroaryl compound is also added to the reaction mixture. The reaction can be carried out according to, e.g., an electrophilic aromatic substitution reaction or a nucleophilic aromatic substitution reaction. The heteroaryl compound can serve as a dispersant to the polymer as it is formed. This minimizes the likelihood of gelling of the product polymer within the reactor vessel and limits the impact of process disruptions on the production of the polyaryletherketone.

Aspects of the present disclosure generally describe polyarylether ketones and methods of use. In some aspects, a composition includes one or more polymers of formulae (I), (II), or (III):

##STR00001##

Aspects of the present disclosure generally describe polyarylether ketones and methods of use. In some aspects, a composition includes one or more polymers of formula (IV):

##STR00001##

A method for manufacturing 1,4-bis(4-phenoxybenzoyl)benzene, including: reacting terephthaloyl chloride with diphenyl ether in a reaction solvent and in the presence of a Lewis acid, so as to obtain a product mixture including a 1,4-bis(4-phenoxybenzoyl)benzene-Lewis acid complex; contacting the product mixture with an aqueous solution, so as to obtain an aqueous phase containing the Lewis acid and an organic phase containing 1,4-bis(4-phenoxybenzoyl)benzene; heating at least the second phase up to a maximum temperature, followed by cooling the second phase down to a separation temperature; subjecting at least the second phase to a solid/liquid separation step at the separation temperature, so as to recover solid 1,4-bis(4-phenoxybenzoyl)benzene.

Aspects of the present disclosure generally describe polyarylether ketones and methods of use. In some aspects, a composition includes one or more polymers of formula (IV): ##STR00001##

Poly(ether ketone ketone) (PEKK) composites include reinforcing fibers in a PEKK polymer matrix that includes a PEKK polymer. It was surprisingly discovered that by washing unneutralized PEKK polymer powder with an acid or base, the melt stability of the PEKK polymers can be improved, as compared with PEKK polymers prepared by conventional methods. The PEKK composites are especially well-suited for fabrication of thick composite parts where melt stability is especially important.

Melt stable polyaryletherketoneketone are prepared from a reactive, lower molecular weight polyaryletherketoneketone having an ultraviolet absorbance at 455 nm of at least 0.185 when measured in 0.1% solution in dichloroacetic acid.

A method for manufacturing 1,4-bis(4-phenoxybenzoyl)benzene, including: reacting terephthaloyl chloride with diphenyl ether in a reaction solvent and in the presence of a Lewis acid, so as to obtain a product mixture comprising a 1,4-bis(4-phenoxybenzoyl)benzene-Lewis acid complex; putting the product mixture in contact with a protic solvent, so as to obtain a first phase containing the Lewis acid and a second phase containing 1,4-bis(4-phenoxybenzoyl)benzene; heating at least the second phase up to a maximum temperature, followed by cooling the second phase down to a separation temperature; subjecting at least the second phase to a solid/liquid separation step at the separation temperature, so as to recover solid 1,4-bis(4-phenoxybenzoyl)benzene.