Methods of forming a porphene polymeric material are provided. The resulting material can be a porphene or a metalloporphene polymeric material. The structure of the polymer can be selected based on a material provided in the monomer material. Methods of using the polymeric material are also provided.

A multiply fused, conjugated, porphyrin polymer film coated on a substrate, wherein the porphyrin monomer repeating units are di-meso-substituted porphyrins; and including a metal cation selected from the group consisting of Mg(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Ru(II), Pd(II), Ag(II), Pt(II) and Au(III), or mixtures thereof; the porphyrin units are multiply fused, including doubly-fused and/or triply-fused; including a substituent R attached to the meso position of the porphyrin monomer, the substituent R being an aromatic group presenting at least one free ortho position among; at least one of the two free ortho positions of the aromatic substituent is fused to the 13 position of the porphyrin monomer, the porphyrin polymer film being a porous porphyrin polymer film with mean pore diameters within the range of from 2 nm to 100 nm, and exhibiting a density not greater than 2 g/cm.sup.3. The invention also relates to a process for obtaining the multiply fused porphyrin polymer film coated on a substrate.

The present invention addresses a first problem of providing a polymer that has electrochromic characteristics, and that can form a sheet which seems more transparent when applied to an electrochromic element and is decolored. The present invention for solving the problem is a polymer obtained by forming a complex between, and binding together, compound A represented by formula 1: BP1-L1-BP2 and at least one specific metal ion selected from the group consisting of first metal ions having a coordination number of 4, second metal ions having a coordination number of 6, and third metal ions having a coordination number of 4 and 6. In the formula, L1 represents a single bond or a divalent group, and BP1 and BP2 may be identical or different from each other and each independently represent a bipyridine derivative.

The present invention disclosed a novel squaraine linked metalloporphyrin based 2D sheet polymer catalyst of formula (I), process for preparation thereof and use of said catalyst for efficient photo- and electro-catalytic splitting of water. ##STR00001##

Methods of forming a porphene polymeric material are provided. The resulting material can be a porphene or a metalloporphene polymeric material. The structure of the polymer can be selected based on a material provided in the monomer material. Methods of using the polymeric material are also provided.

The present invention disclosed a novel squaraine linked metalloporphyrin based 2D-sheet polymer catalyst of formula (I), process for preparation thereof and use of said catalyst for efficient photo- and electro-catalytic splitting of water.

The present invention addresses a first problem of providing a polymer that has electrochromic characteristics, and that can form a sheet which seems more transparent when applied to an electrochromic element and is decolored. The present invention for solving the problem is a polymer obtained by forming a complex between, and binding together, compound A represented by formula 1: BP1-L1-BP2 and at least one specific metal ion selected from the group consisting of first metal ions having a coordination number of 4, second metal ions having a coordination number of 6, and third metal ions having a coordination number of 4 and 6. In the formula, L1 represents a single bond or a divalent group, and BP1 and BP2 may be identical or different from each other and each independently represent a bipyridine derivative.