This application discloses a white-light hyperbranched conjugated polymer, a method for preparing the same and its use. The polymer uses a red phosphorescent Ir(III) complex as a core and polyfluorene derivative blue fluorescent materials as a framework which either contains or does not contain carbazole derivatives, and the white light hyperbranched polymers realize white-light emission by adjusting the content of the red phosphorescent Ir(III) complex connected using the complementation of blue and red color. The electroluminescent spectrum of the conjugated polymer in the present application covers the whole visible light emission area and is close to the pure white light emission, by which the conjugated polymer could be used as a material used in light-emitting layer to prepare the organic electroluminescent devices.

A composition comprising a phosphorescent compound of formula (I) and a polymer comprising a repeat unit of formula (II) Ar.sup.1 is an aryl or heteroaryl group. R.sup.2 is a substituent. A is independently in each occurrence N or CR.sup.3 wherein R.sup.3 is H or a substituent. M is a transition metal or metal ion. x is a positive integer of at least 1. y is 0 or a positive integer. L.sup.1 is a mono- or polydentate ligand. R.sup.1 is a substituent. z is 0 or a positive integer. X is O or S. The phosphorescent compound of formula (I) may be mixed with the polymer or may be covalently bound thereto. The composition may be used in the light-emitting layer of an organic light-emitting device.

An organic light-emitting device (100) comprising an anode (103); a cathode (109); a first light-emitting layer (107) comprising a first light-emitting material between the anode and the cathode; and a hole-transporting layer (105) comprising a hole-transporting polymer between the anode and the first light-emitting layer and adjacent to the first light-emitting layer, wherein a HOMO level of the first light-emitting material is closer to vacuum than a HOMO level of the hole-transporting polymer and wherein more than 50 mol % of the repeat units of the hole-transporting polymer are hole-transporting repeat units.

Metallopolymers of formula (I) where R.sup.1 and R.sup.1′; and R.sup.2 and R.sup.2′ are independently of each other, a C.sub.2-C.sub.10 alkyl group; X is CR3R3′ or NR4; R.sup.3 and R.sup.3′ are, independently of each other, as is R.sup.4, a C.sub.2-C.sub.10 alkyl group; L is a C.sub.4-C.sub.10 alkylene group; Ln.sup.1 and Ln.sup.2 are, independently of each other, chosen from the lanthanide cations; L.sup.1 and L.sup.2 are, independently of each other, chosen from the α-diketonate ligands; T is a neutral bidentate Lewis base including two coordinating nitrogen atoms; .fwdarw. represents a coordination of group T via the two nitrogen atoms of T to Ln.sup.1 and Ln.sup.2 respectively; Ln.sup.1 and Ln.sup.2 are, independently of each other, chosen from the lanthanide cations; L.sup.1 and L.sup.2 are, independently of each other, chosen from the β-diketonate, picolinate or dipicolinate monoanionic ligands; 0.01<x<0.50; 0<y<0.49, with x+y=0.50.

A composition suitable for use in an organic light-emitting layer (103) of an organic light-emitting device having an anode (101) and a cathode (105), the composition comprising a fluorescent light-emitting material, a first triplet-accepting material and a second triplet-accepting material that is different from the first triplet-accepting material. The fluorescent light-emitting material may be a repeat unit of a light-emitting polymer, and the first and second triplet-accepting materials may independently be repeat units of the light-emitting polymer or may be mixed with the fluorescent light-emitting material.

The present invention relates to copolymers containing indenocarbazole derivatives having electron- and hole-transporting properties, in particular for use in the interlayer, emission layer and/or charge-transport layer of electroluminescent devices. The invention furthermore relates to a process for the preparation of the compounds according to the invention and to electronic devices comprising these compounds.

A problem to be solved of the invention is to provide a package of a liquid composition for an organic electroluminescent device including a phosphorescent material and a solvent with extended storage lifetime, which may be produced with high working efficiency. A solving means of the problem is a package of a liquid composition for an organic electroluminescent device having a liquid composition for an organic electroluminescent device including a phosphorescent material and a solvent, and a container that contains the liquid composition for an organic electroluminescent device, wherein the package of a liquid composition for an organic electroluminescent device has a transmittance of light, that is a wavelength component of from 500 nm to 780 nm, from outside of the package to inside of the container of 15% or less.

A polymer comprising units α, β, γ and δ wherein: unit α is present at 30 mole % to 60 mole % and is an optionally substituted arylene; unit β is present at 1 mole % to 30 mole % and is a unit comprising an optionally substituted fluorene; unit γ is present at 1 mole % to 40 mole % and comprises aryl substituted nitrogen, or an optionally substituted triazine; unit δ is present at 0.5 mole % to 15 mole % and comprises an iridium complex; and optionally up to 20 mole % of other units if the total of α, β, γ and δ is less than 100 mole %.

A polymer comprising repeat units of formula (I) and one or more co-repeat units: ##STR00001## Ar.sup.1 in each occurrence independently represent an aryl or heteroaryl group; R.sup.1 and R.sup.2 in each occurrence independently represent a substituent; p independently in each occurrence is 0 or a positive integer; Sp represents a spacer group comprising at least one carbon or silicon atom spacing the two groups Ar.sup.1 apart; and each group Ar.sup.1 is bound to an aromatic group of a co-repeat unit. The polymer may form a charge-transporting layer of an OLED or may be a host material used with a luminescent dopant in a light-emitting layer of an OLED.

Light-Emitting Compound A composition comprising a light-emitting compound having a peak wavelength of at least 650 nm and a material comprising a group of formula (I): wherein Ar.sup.1, Ar.sup.2 and Ar.sup.3 in each occurrence are independently selected from a C.sub.6-20 aromatic group and a 6-20 membered heteroaromatic group of C and N ring atoms and at least one of Ar.sup.1, Ar.sup.2 and Ar.sup.3 is a 6-20 membered heteroaromatic group of C and N ring atoms; x, y and z are each independently at least 1; n, m and p are each independently 0 or a positive integer; and R.sup.1, R.sup.2 and R.sup.3 in each occurrence is independently a substituent or a single bond to a polymer chain, wherein the group of formula (I) has no more than 3 single bonds to a polymer chain. The composition may be used in the light-emitting layer of an infrared organic light-emitting device. ##STR00001##