A PEDOT:PSS film having enhanced thermoelectric properties is doped with DMSO and a binary secondary dopant, such as PEO. The composition of such film causes the ratios of PEDOT in bipolaron states to be increased. As a result, the Seebeck coefficient, the electrical conductivities, and power factor of the film are increased, thereby increasing the efficiency of the film. Thus, a thermoelectric device that uses the film is able to achieve enhanced operating performance.

A thermoelectric conversion element includes: a thermoelectric conversion layer containing a thiophene polymer, in which a peak intensity of a diffraction angle (2θ) of 7.9° is 5 times or more a peak intensity of a diffraction angle (2θ) of 25.8° in an X-ray diffraction spectrum of the thermoelectric conversion layer.

The present disclosure relates to functionally graded thermoelectric materials including an organic conducting polymer. In particular, the material includes a molecular dopant that can be spatially distributed in a controlled pattern within the material. Methods of making such materials and devices including such materials are also described herein.

A thermoelectric conversion element includes: a thermoelectric conversion layer containing a thiophene polymer, in which a peak intensity of a diffraction angle (2θ) of 7.9° is 5 times or more a peak intensity of a diffraction angle (2θ) of 25.8° in an X-ray diffraction spectrum of the thermoelectric conversion layer.

A PEDOT:PSS film having enhanced thermoelectric properties is doped with DMSO and a binary secondary dopant, such as PEO. The composition of such film causes the ratios of PEDOT in bipolaron states to be increased. As a result, the Seebeck coefficient, the electrical conductivities, and power factor of the film are increased, thereby increasing the efficiency of the film. Thus, a thermoelectric device that uses the film is able to achieve enhanced operating performance.

A thermoelectric conversion element (1) having, on a substrate (12), a first electrode (13), a thermoelectric conversion layer (14), and a second electrode (15), wherein a nano conductive material and a low band gap material are contained in the thermoelectric conversion layer (14); an article for thermoelectric power generation and a power supply for a sensor using the thermoelectric conversion element (1); and a thermoelectric conversion material containing the nano conductive material and the low band gap material.

A thermoelectric conversion element (1) having, on a substrate (12), a first electrode (13), a thermoelectric conversion layer (14), and a second electrode 15, wherein a nano conductive material and a low band gap material are contained in the thermoelectric conversion layer (14); an article for thermoelectric power generation and a power supply for a sensor using the thermoelectric conversion element (1); and a thermoelectric conversion material containing the nano conductive material and the low band gap material.