Patent classifications
C08G2261/59
ORGANIC SEMICONDUCTOR ELEMENT, MANUFACTURING METHOD THEREOF, COMPOUND, ORGANIC SEMICONDUCTOR COMPOSITION, ORGANIC SEMICONDUCTOR FILM, AND MANUFACTURING METHOD THEREOF
Objects of the present invention are to provide an organic semiconductor element in which carrier mobility is high, variation of mobility is suppressed, and temporal stability under high temperature and high humidity is excellent, and a manufacturing method thereof, to provide a novel compound suitable for an organic semiconductor, and to provide an organic semiconductor film in which mobility is high, variation of mobility is suppressed, and temporal stability under high temperature and high humidity is excellent, a manufacturing method thereof, and an organic semiconductor composition that can suitably form the organic semiconductor film.
The organic semiconductor element according to the present invention is an organic semiconductor layer containing a compound having a constitutional repeating unit represented by Formula 1 and having a molecular weight of 2,000 or greater.
D-A (1)
Materials for electronic devices
The present application relates to a polymer containing at least one structural unit of a formula (I) and at least one further structural unit selected from structural units A, B and C. The present application further relates to the use of the polymer in an electronic device and to a process for preparing the polymer. The present application further relates to an electronic device comprising the polymer.
Polymerizable composition and method of production of resin shaped article
A polymerizable composition comprised of a mixture of a norbornene-based monomer and a metathesis polymerization catalyst which is solidified by cooling is provided. Preferably, the norbornene-based monomer has a freezing point of 20° C. or more, more preferably the metathesis polymerization catalyst is a ruthenium-carbene complex. According to the present invention, it is possible to provide a polymerizable composition which is excellent in storage stability and which enables industrial production of small resin shaped articles which are excellent in stability of quality.
Polymers based on naphthodiones
The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula (I), and compounds of formula (III), wherein Y, Y.sup.15, Y.sup.16 and Y.sup.17 are independently of each other a group of formula and their use as IR absorber, organic semiconductor in organic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers and compounds according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers and compounds according to the invention are used in organic field effect transistors, organic photovoltaics and photodiodes. ##STR00001##
Conductive polymer dispersion and method for preparing same, and method for manufacturing conductive film
A conductive polymer dispersion of this disclosure includes: a conductive composite containing a n-conjugated conductive polymer and a polyanion; an isocyanurate-based compound; and a dispersion medium for dispersing the conductive composite.
CONDUCTIVE POLYMER DISPERSION AND METHOD FOR PREPARING SAME, AND METHOD FOR MANUFACTURING CONDUCTIVE FILM
A conductive polymer dispersion of this disclosure includes: a conductive composite containing a π-conjugated conductive polymer and a polyanion; an isocyanurate-based compound; and a dispersion medium for dispersing the conductive composite.
Polyphenylene compound
This is to provide a non-halogen containing compound excellent in proton conductivity and capable of suitably being used for a polymer electrolytic fuel cell The compound of the present invention has a structure represented by the following general formula (I). ##STR00001## (In the above-mentioned general formula (I), “l” and “n” are molar fractions when l+n=1.0, and 0≤l<1.0 and 0<n≤1.0, A represents a structure represented by the following general formula (II) or (III), B represents a structure represented by the following general formula (VII), the respective structural units are random copolymerized, and at least one benzene ring in the formula (I) has at least one sulfo group.) ##STR00002## (In the above-mentioned general formula (II) or (III), R.sup.1 to R.sup.4 are each independently selected from hydrogen and an alkyl group having 1 to 3 carbon atoms, le and R.sup.2 form together with the carbon atom, they are attached to, an aromatic ring or a fused aromatic ring and R.sup.3 and R.sup.4 form together with the carbon atom, they are attached to, an aromatic ring or a fused aromatic ring, or R.sup.1, R.sup.3 and R.sup.4 are hydrogens and R.sup.2 is a single bond and bonded to the carbon of “c”, X is a single bond, or a structure represented by the following formula (IV), the following formula (V) or the following formula (VI), when X is a single bond, bonds “a”s are both bonded at ortho positions or both bonded at meta positions relative to the carbons bonded to X, when X is a structure represented by the following formula (IV), bonds “a”s are both bonded at para positions relative to the carbons bonded to X, and when it is a structure represented by the following formula (V), bonds “a”s are both bonded at para positions or both bonded at meta positions relative to the carbons bonded to x, when X is a structure represented by the following formula (VI), the bonds “a”s in the above-mentioned general formula (II) or (III) exist only one of these, and A binds to other structure or a structural unit by one of the bonds “a”s and the bond “b”.) ##STR00003##
Conductive polymer dispersion and method for preparing same, and method for manufacturing conductive film
A conductive polymer dispersion of this disclosure includes: a conductive composite containing a π-conjugated conductive polymer and a polyanion; an isocyanurate-based compound; and a dispersion medium for dispersing the conductive composite.
Material for forming underlayer film for lithography, composition for forming underlayer film for lithography, underlayer film for lithography and production method thereof, and resist pattern forming method
The present invention provides a material for forming an underlayer film for lithography, containing at least any of a compound represented by following formula (1) or a resin including a structural unit derived from a compound represented by the following formula (1), ##STR00001##
wherein R.sup.1 represents a 2n-valent group having a 1 to 60 carbon atoms, or a single bond, each R.sup.2 independently represents a halogen atom, a straight, branched or cyclic alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an alkoxy group having 1 to 30 carbon atoms, a thiol group, or a hydroxyl group, and may be the same or different in the same naphthalene ring or benzene ring, n is an integer of 1 to 4, structural formulae of n's structural units in square brackets [ ] may be the same or different when n is an integer of 2 or more, X represents an oxygen atom, a sulfur atom, or a non-bridging group, each m2 is independently an integer of 0 to 7, in which at least one m.sup.2 is an integer of 1 to 7, and each q is independently 0 or 1, provided that at least one selected from the group consisting of R.sup.1 and R.sup.2 is a group having an iodine atom.
POLYPHENYLENE COMPOUND
This is to provide a non-halogen containing compound excellent in proton conductivity and capable of suitably being used for a polymer electrolytic fuel cell
The compound of the present invention has a structure represented by the following general formula (I).
##STR00001##
(In the above-mentioned general formula (I), l and n are molar fractions when l+n=1.0, and 0l<1.0 and 0<n1.0, A represents a structure represented by the following general formula (II) or (III), B represents a structure represented by the following general formula (VII), the respective structural units are random copolymerized, and at least one benzene ring in the formula (I) has at least one sulfo group.)
##STR00002##
(In the above-mentioned general formula (II) or (III), R.sup.1 to R.sup.4 are each independently selected from hydrogen and an alkyl group having 1 to 3 carbon atoms, le and R.sup.2 form together with the carbon atom, they are attached to, an aromatic ring or a fused aromatic ring and R.sup.3 and R.sup.4 form together with the carbon atom, they are attached to, an aromatic ring or a fused aromatic ring, or R.sup.1, R.sup.3 and R.sup.4 are hydrogens and R.sup.2 is a single bond and bonded to the carbon of c, X is a single bond, or a structure represented by the following formula (IV), the following formula (V) or the following formula (VI), when X is a single bond, bonds as are both bonded at ortho positions or both bonded at meta positions relative to the carbons bonded to X, when X is a structure represented by the following formula (IV), bonds as are both bonded at para positions relative to the carbons bonded to X, and when it is a structure represented by the following formula (V), bonds as are both bonded at para positions or both bonded at meta positions relative to the carbons bonded to x, when X is a structure represented by the following formula (VI), the bonds as in the above-mentioned general formula (II) or (III) exist only one of these, and A binds to other structure or a structural unit by one of the bonds as and the bond b.)
##STR00003##