Provided are a photocurable resin composition that can be suitably used for an optical three-dimensional shaping method, and a cured product obtained by photocuring the composition and a three-dimensional shaped object including the cured product. The photocurable resin composition contains a compound represented by the formula (1) and a compound containing two or more epoxy groups. ##STR00001##

The present invention relates to a process for preparing polyoxyalkylene polyester polyols by reacting a starter compound having Zerewitinoff-active H atoms, a cyclic dicarboxylic acid anhydride and a fatty acid ester with an alkylene oxide in the presence of a basic catalyst. The invention further relates to polyoxyalkylene polyester polyols resulting from the method and to a preparation method for polyurethanes by reaction of the polyoxyalkylene polyester polyols according to the invention.

The invention provides a method for sequence controllable block copolymerization of a cyclic ester monomer and an epoxy monomer, including: in an inert atmosphere, adding the epoxy monomer and/or the cyclic ester monomer into a catalytic initiating system including an organic base and an alkyl borane for reaction, so as to obtain a sequence controllable polyether-polyester block copolymer of the cyclic ester monomer and the epoxy monomer, i.e. a polyester-b-polyether or a polyether-b-polyester. The invention can prepare various polyether-polyester block copolymers of which the molecular weights, block sequences, block ratios and pendant group combinations can be flexibly adjusted. The invention provides a method for continuously preparing an aliphatic polyester-polyether block copolymer by a one-pot method utilizing a catalytic system of a metal-free Lewis acid-base pair.

The invention contemplates certain polyethers, polyether derivatives, and methods of making and using those same polymers. For example, the starting materials can, e.g., citronellol, prenol, isocitronellol and isoprenol.

Provided is a synthesis process for the one-step production of a monomeric polyether for polycarboxylic acid water reducing agents, wherein the monomeric polyether is synthesized in one step by mixing an initator and a catalyst at a temperature and a pressure, and then introducing same into a reaction kettle together with an epoxide at a certain ratio for ring opening polymerization. The synthesis process of the present invention realizes continuous production without the need of first synthesizing a prepolymer and then synthesizing a macromolecular monomeric polyether step by step, thereby improving the production efficiency. By separating four links, i.e. displacement, polymerization, curing and neutralization, in conventional monomeric polyether production processes, the present invention more effectively controls each of the links and increases the utilization efficiency of the reaction kettle; in addition, the process is easy to control, the structure of the product is stable, and the retention of double-bonds is high.

Vinyl-functional alcohols are silylated by reaction with a hydrolysable silyl hydride compound. The starting alcohol is heated and then combined with the silyl hydride and catalyst and allowed to heat exothermically. Cooling is applied when the conversion of vinyl groups is between 90-99%. In some embodiments, specified amounts of water are present. The cooling regimen and control of water content reduces certain side reactions, leading to greater yields to desired product.

The present specification relates to a compound comprising an aromatic ring, a polyelectrolyte membrane comprising the same, a membrane-electrode assembly comprising the polyelectrolyte membrane, a fuel cell comprising the membrane-electrode assembly, and a redox flow battery comprising the polyelectrolyte membrane.

The invention contemplates certain polyethers, polyether derivatives, and methods of making and using those same polymers. For example, the starting materials can, e.g., citronellol, prenol, isocitronellol and isoprenol.

Hydrogel compositions including a polymer uniformly embedded with a loading agent are provided. Also provided are methods for extrusion printing hydrogel compositions to provide extruded hydrogel compositions, which can be crosslinked to provide crosslinked hydrogel structures. Also provided are methods for using crosslinked hydrogel structures in chemical processes.

A process for preparing non-naturally-occurring defined monomer sequence polymers is provided, and in which a high degree of synthetic control is obtained by the use of solvent resistant diafiltration membranes. Also provided is a process for separating non-naturally-occurring defined monomer sequence polymers from synthetic by-products or excess reagents using solvent resistant diafiltration membranes, and a use of a solvent resistant diafiltration membrane in processes for preparing and separating non-naturally-occurring defined monomer sequence polymers.