Patent classifications
C08J11/12
METHODS AND SYSTEMS FOR CO-FEEDING WASTE PLASTICS INTO A REFINERY
The present application provides a method and a system for recycling a polymer. The method includes introducing polymer into a primary melting extruder, producing a polymer melt that is combined with a fluid oil to at least partially dissolve the polymer melt. A secondary mixing extruder mixes these to form a polymer solution that is introduced into a refinery oil stream, producing a polymer-comprising oil stream, which is fed into a refinery process unit. The system includes a primary melting extruder for forming a polymer melt from polymer. A secondary mixing extruder receives the polymer melt. One or more hydrocarbon inflow conduits for providing a fluid oil to the primary melting extruder and/or the secondary mixing extruder are configured to form a polymer solution from the fluid oil and the polymer melt. There is a feed system outlet for feeding the polymer solution to a refinery oil stream.
METHOD FOR THE DEVULCANIZATION OF A VULCANIZED RUBBER MIXTURE, DEVICE FOR CARRYING OUT THE METHOD AND USE OF THE DEVICE FOR THE DEVULCANIZATION OF A VULCANIZED RUBBER MIXTURE
The invention relates to a process for devulcanizing a vulcanized rubber mixture, comprising the following steps: A) providing or producing a vulcanized rubber mixture, B) comminuting the vulcanized rubber mixture to a granular material composed of vulcanized rubber particles, where the vulcanized rubber particles have a maximum particle diameter of 100 mm, C) extruding the vulcanized rubber particles produced in step B) in a twin-screw extruder at a shear rate of less than 100 s.sup.−1, where the temperature of the vulcanized rubber particles during extrusion is less than 200° C., to give a devulcanized rubber mixture having a temperature above 100° C., D) cooling the devulcanized rubber mixture in a further kneading unit, so as to give a devulcanized rubber mixture having a temperature in the range from 50° C. to 100° C. The invention further relates to an apparatus for performing the process and to the use of the apparatus for devulcanization of a vulcanized rubber mixture.
METHOD FOR THE DEVULCANIZATION OF A VULCANIZED RUBBER MIXTURE, DEVICE FOR CARRYING OUT THE METHOD AND USE OF THE DEVICE FOR THE DEVULCANIZATION OF A VULCANIZED RUBBER MIXTURE
The invention relates to a process for devulcanizing a vulcanized rubber mixture, comprising the following steps: A) providing or producing a vulcanized rubber mixture, B) comminuting the vulcanized rubber mixture to a granular material composed of vulcanized rubber particles, where the vulcanized rubber particles have a maximum particle diameter of 100 mm, C) extruding the vulcanized rubber particles produced in step B) in a twin-screw extruder at a shear rate of less than 100 s.sup.−1, where the temperature of the vulcanized rubber particles during extrusion is less than 200° C., to give a devulcanized rubber mixture having a temperature above 100° C., D) cooling the devulcanized rubber mixture in a further kneading unit, so as to give a devulcanized rubber mixture having a temperature in the range from 50° C. to 100° C. The invention further relates to an apparatus for performing the process and to the use of the apparatus for devulcanization of a vulcanized rubber mixture.
Methods for making recyclable and depolymerizable polymer network materials via thiourethane dynamic chemistry
Polythiourethane polymer networks that can be processed and/or recycled are provided. Also provided are methods of forming the polythiourethane polymer networks using excess thiol and/or a dual catalyst system and methods for reprocessing and recycling the polyurethane polymer networks. The polythiourethane polymer networks are based on thiourethane dynamic chemistry.
Methods for making recyclable and depolymerizable polymer network materials via thiourethane dynamic chemistry
Polythiourethane polymer networks that can be processed and/or recycled are provided. Also provided are methods of forming the polythiourethane polymer networks using excess thiol and/or a dual catalyst system and methods for reprocessing and recycling the polyurethane polymer networks. The polythiourethane polymer networks are based on thiourethane dynamic chemistry.
A METHOD FOR PYROLYSING PLASTIC MATERIAL AND A SYSTEM THEREFOR
A method for pyrolysing plastic material. The method comprises the steps of: heating and densifying plastic material; transporting the plastic material to one or more reactors; and pyrolysing the plastic material in the one or more reactors. The plastic material is maintained in a heated state during the transporting step. A system for pyrolysing plastic material is also provided.
A METHOD FOR PYROLYSING PLASTIC MATERIAL AND A SYSTEM THEREFOR
A method for pyrolysing plastic material. The method comprises the steps of: heating and densifying plastic material; transporting the plastic material to one or more reactors; and pyrolysing the plastic material in the one or more reactors. The plastic material is maintained in a heated state during the transporting step. A system for pyrolysing plastic material is also provided.
PRE-TREAMENT OF POLYOLEFIN WASTE TO IMPROVE DEPOLYMERIZATION
Pre-treatment methods for polyolefin-based feed streams before depolymerization are described. Polyolefins are separated from other material in the polyolefin-based feed stream using density differences in an aqueous solution, which allows for a pre-treatment method that does not affect the depolymerization catalyst. By removing the non-polyolefin materials from the feed stream, the depolymerization of the polyolefin material can proceed at lower temperatures for longer cycles. This results in a more efficient process with a smaller carbon footprint.
METHOD FOR THE DEVULCANISATION OF A VULCANISAED RUBBER MIXTURE, DEVICE FOR CARRYING OUT THE METHOD, AS WELL AS A RUBBER MIXTURE AND VEHICLE PNEUMATIC TYRE, COMPRISING A COMPONENT MADE OF THE RUBBER MIXTURE
The invention relates to a process for devulcanizing a vulcanized rubber mixture, comprising the following steps: A) providing or producing a vulcanized rubber mixture, B) comminuting the vulcanized rubber mixture into a granulate of vulcanized rubber particles, C) extruding the vulcanized rubber particles produced in step B) in a twin-screw extruder to form a devulcanized rubber mixture, wherein, during the extruding in step C) at least one regeneration reagent is added to the extruded rubber particles, wherein the regeneration reagent comprises at least one silane, at least one plasticizer, at least one aging stabilizer or mixtures thereof. The invention also comprises an apparatus for performing the method and the uses of the apparatus, and a rubber mixture and also a pneumatic vehicle tyre or a technical rubber article comprising a component composed of the rubber mixture.
METHOD FOR THE DEVULCANISATION OF A VULCANISAED RUBBER MIXTURE, DEVICE FOR CARRYING OUT THE METHOD, AS WELL AS A RUBBER MIXTURE AND VEHICLE PNEUMATIC TYRE, COMPRISING A COMPONENT MADE OF THE RUBBER MIXTURE
The invention relates to a process for devulcanizing a vulcanized rubber mixture, comprising the following steps: A) providing or producing a vulcanized rubber mixture, B) comminuting the vulcanized rubber mixture into a granulate of vulcanized rubber particles, C) extruding the vulcanized rubber particles produced in step B) in a twin-screw extruder to form a devulcanized rubber mixture, wherein, during the extruding in step C) at least one regeneration reagent is added to the extruded rubber particles, wherein the regeneration reagent comprises at least one silane, at least one plasticizer, at least one aging stabilizer or mixtures thereof. The invention also comprises an apparatus for performing the method and the uses of the apparatus, and a rubber mixture and also a pneumatic vehicle tyre or a technical rubber article comprising a component composed of the rubber mixture.