Patent classifications
C08J2201/0543
NOVEL POROUS POLYMER MONOLITHS ADAPTED FOR SAMPLE PREPARATION
A porous polymer monolith comprises a polymer body having macroporous through-pores that facilitate fluid flow through the body and an array of mesopores adapted to bind from the fluid flow molecules of a predetermined range of sizes, wherein the surface area of the monolith is predominantly provided by the mesopores. Also disclosed is a method of making a porous polymer monolith. The method includes forming a polymer body by phase separation out of a solution containing at least a monomer, a crosslinker and a primary porogen, whereby the body contains multiple macroporous through-pores, wherein the solution further contains a secondary porogen comprising oligomers inert with respect to the monomer and cross-linker but chemically compatible with the monomer so as to form mesostructures within the polymer body during said phase separation, and washing the mesostructures from the body to provide an array of mesopores such that the surface area of the monolith is predominantly provided by the mesopores.
Cationomeric polyolefin compositions and methods for production and use thereof
Although polyolefin elastomers are widely employed commodity polymers, there are shortcomings of this class of polymers for certain applications. For example, the rheological properties of some polyolefin elastomers may be insufficient to provide the green strength or low shear viscosity necessary to form stable foams, or to provide sufficient viscosity modification effects when present in a solvent. Cationomeric modification of polyolefin elastomers may alleviate these difficulties. Such polyolefin elastomers may feature a random cationomeric polyolefin copolymer comprising at least a first monomer and a second monomer, in which the first monomer is a neutral monomer and the second monomer has a side chain bearing a cationic moiety. The polyolefin elastomers may be present in foamed polyolefin compositions comprising a gas component and/or in liquid compositions comprising a solvent in which the polyolefin elastomer is dissolved.
HIGHLY FLUORINATED NANOSTRUCTURED POLYMER FOAMS FOR PRODUCING SUPER-REPELLENT SURFACES
The present invention relates to a highly fluorinated nanostructured polymer foam as well as to its use as a super-repellent coating of substrates. Furthermore, the present invention relates to a composition and to a method for producing the highly fluorinated nanostructured polymer foam.
Polymer for separation of analytes and methods for preparation and use of same
A polymer for liquid chromatography or solid phase extraction is provided. The polymer is prepared by polymerizing styrene and divinylbenzene to form a styrene-divinylbenzene copolymer; soaking the styrene-divinylbenzene copolymer in a swelling agent to form nano-scale micropores; and soaking the microporous styrene-divinylbenzene copolymer in methanol. When packed in a chromatographic column, the polymer can be used to produce produce natural health or medicinal products from Cannabis species, for example, industrial hemp.
FABRICATION OF AEROGELS AND AEROGEL COMPOSITES BY AMBIENT PRESSURE SUBLIMATION OF FROZEN SOLVENTS
Drying polar solvents which do not form hydrogen bonds with a wet gel or aerogel, or eutectics or solvent mixtures with the drying solvents, are utilized in a solvent exchange with wet gels used in the formation of aerogels. Preferably the drying solvents are non-polar solvents. The drying solvent or solvent mixtures results in profoundly less shrinkage, thereby allowing for the production of aerogels of preferred materials properties.
Method of producing porous molded body
A molded body is produced from a molding material including a continuous phase and a dispersed phase by a three-dimensionalization step, a curing step, and a peeling step. The continuous phase of the molding material is a water phase containing a curable compound. In the three-dimensionalization step, the molding material is placed in a container. In the curing step, the curable compound is cured to form a cured product after the three-dimensionalization step. In the peeling step, the container and the cured product are separated after the curing step. In the dispersed phase removal step, the dispersed phase of the cured product is removed after the curing step.
POLYOLEFIN MICROPOROUS MEMBRANE, METHOD FOR PRODUCING SAME, AND BATTERY SEPARATOR
A polyolefin microporous membrane is disclosed. The polyolefin microporous membrane includes a polyolefin resin, where the polyolefin resin contains at least 80 mass % polypropylene resin, and where the polyolefin microporous membrane has a maximum pore size of less than 30.0 nm and a mean flow pore size of less than 20.0 nm.
METHOD FOR PREPARING POLYIMIDE AEROGEL HAVING LOW DIELECTRIC PROPERTIES, HIGH INSULATION, AND HIGH STRENGTH, AND POLYIMIDE AEROGEL PRODUCED THEREFROM
The present invention relates to: a method for producing a polyimide aerogel having low dielectric properties, high insulation, and high strength; and a polyimide aerogel prepared therefrom. The present invention has the technical gist of a method for producing a polyimide aerogel having low dielectric properties, high insulation, and high strength, and a polyimide aerogel prepared therefrom, the method including: a first step of preparing a solvent; a second step of preparing a polyamic acid resin by reacting a diamine-based monomer with an acid anhydride monomer in a solvent; a third step of preparing a polyimide resin solution by imidizing the polyamic acid resin at 150 to 200° C.; a fourth step of preparing a polyimide wet gel by mixing a crosslinking agent and an acid with the polyimide resin solution; and a fifth step of preparing a polyimide aerogel by replacing the solvent contained in the polyimide wet gel with a main substitution solvent and a minor substitution solvent and then drying, wherein, in the fifth step, the main substitution solvent and the minor substitution solvent are each added to the polyimide wet gel in a stepwise manner to produce a polyimide aerogel having the porosity of 80 to 85 vol % while forming a skeletal structure having nano-pores through solvent-exchange.
POROUS CO-POLYMERIC GEL COMPOSITIONS, POROUS CARBON COMPOSITIONS, AND METHODS FOR SYNTHESIS THEREOF
The present invention discloses novel porous polymeric compositions comprising random copolymers of amides, imides, ureas, and carbamic-anhydrides, useful for the synthesis of monolithic bimodal microporous/macroporous carbon aerogels. It also discloses methods for producing said microporous/macroporous carbon aerogels by the reaction of a polyisocyanate compound and a polycarboxylic acid compound, followed by pyrolytic carbonization, and by reactive etching with CO.sub.2 at elevated temperatures. Also disclosed are methods for using the microporous/macroporous carbon aerogels in the selective capture and sequestration of carbon dioxide.
POROUS SILICONE BODY AND METHOD FOR PRODUCING POROUS SILICONE BODY
The present invention relates to a porous silicone body having communicating pores and a three-dimensional network silicone skeleton that forms the pores, wherein the silicone skeleton is formed by polymerization of a bifunctional alkoxysilane and a trifunctional alkoxysilane, and the proportion of unreacted parts in the silicone skeleton is 10 mol % or less. The porous silicone body of the present invention has high flexibility and high heat resistance, and further has excellent recoverability of heat-resistant cushioning properties.