The present disclosure provides Lazarev reactor that sustains reaction of two dimensional polymerization on the interface of two immiscible solutions A and B carrying components of reaction to the interface where reaction takes place and produces film of two dimensional polymer layers that are pulled out of reactor and rolled up on roll after drying excess of solvent out.

The aim of the invention is to provide polyester/primer/metallic coating composite films having good adherence of the metallic coating in dry and humid conditions. Said films also form a good gas barrier: oxygen permeability less than or equal to 0.8 cc/m2/d; water vapour permeability less than or equal to 0.3 g/m2/d. To this end, the invention concerns a composite film comprising a polyester substrate, at least one coating adhering on at least one of the faces of the substrate and at least one layer of primer for cross-linked adhesion between the substrate and the coating. Said primer comprises at least one acrylic and/or methacrylic polymer P1, at least one acrylic and/or methacrylic polymer P2 different from P1, at least one cross-linking agent, and, preferably, at least one polyester that is soluble or dispersible in water: —P1 having a gel content TG1>70% by dry weight with respect to P1; —P2 having a gel content TG2≤TG1 and ≤20% by dry weight, with respect to P2; —P1 having a surface-grafted free weak acid content≥0.8 in meq/g of polymer; —[P2]≤60% by weight on dry by weight in respect to P1+P2. The method for producing said film, the adhering primer, and the articles obtained using said film, also form part of the present invention.

The present disclosure provides Lazarev reactor that sustains reaction of two dimensional polymerization on the interface of two immiscible solutions A and B carrying components of reaction to the interface where reaction takes place and produces film of two dimensional polymer layers that are pulled out of reactor and rolled up on roll after drying excess of solvent out.

The aim of the invention is to provide polyester/primer/metallic coating composite films having good adherence of the metallic coating in dry and humid conditions. Said films also form a good gas barrier: oxygen permeability less than or equal to 0.8 cc/m2/d; water vapour permeability less than or equal to 0.3 g/m2/d. To this end, the invention concerns a composite film comprising a polyester substrate, at least one coating adhering on at least one of the faces of the substrate and at least one layer of primer for cross-linked adhesion between the substrate and the coating. Said primer comprises at least one acrylic and/or methacrylic polymer P1, at least one acrylic and/or methacrylic polymer P2 different from P1, at least one cross-linking agent, and, preferably, at least one polyester that is soluble or dispersible in water: P1 having a gel content TG1>70% by dry weight with respect to P1; P2 having a gel content TG2TG1 and 20% by dry weight, with respect to P2; P1 having a surface-grafted free weak acid content >0.8 in meq/g of polymer; [P2]60% by weight on dry by weight in respect to P1+P2. The method for producing said film, the adhering primer, and the articles obtained using said film, also form part of the present invention.

Provided is an advantageous production method for a curable resin composition. A resin composition in accordance with the present disclosure is a resin composition that contains a compound (A) having a benzoxazine ring and an aldehyde group and an aromatic amine compound (B), wherein the resin composition contains the aldehyde group in an amount of not less than 50 mol %, and the resin composition contains a solvent in an amount of not less than 0% by weight and not more than 68% by weight, where 100 mol % represents a total amount of the aldehyde group and an imino group in the resin composition.

The invention relates to a method for forming blasthole stemming for mining, which comprises charging a blasthole with a two-component mixture of resin and catalyst, wherein the two-component mixture produces a stiff foam in situ, and once hardened, the two-component mixture is then detonated. The invention also relates to a system for forming blasthole stemming for mining in order to carry out the method; the mixture used as blasthole stemming for mining that comprises the two-component mixture of resin and catalyst, wherein the resins are based on formaldehyde; and to a method for charging and detonating a mining blasthole by using the two-component mixture.