There is provided a method of coating a substrate comprising applying a first mixture where the first mixture reacts to form covalent bonds to the substrate surface and where the unreacted parts of the first mixture undergo diffusive mixing with a second layer, which is applied on top of the first mixture. This avoids creation of a weak layer, which may otherwise give lower adhesion. The adhesion as well as mechanical properties including the scratch resistance are improved.

The disclosure provides a cationic curing composition for a plastic substrate, a coating material including the composition and an application of the composition in the field of energy curing. The cationic curing composition includes a polyhydroxy resin, an epoxy compound, an oxetanyl-containing compound, and a cationic initiator, the polyhydroxy resin is a polyester resin, an acrylic resin and/or a phenolic resin, and the molar ratio of a hydroxyl, a three-membered epoxy group to a four-membered epoxy group in the cationic curing composition is 1:(3-20):(1-25). A plastic product includes the plastic substrate and a coating layer, and the coating layer is formed by curing the cationic curing composition.

The present invention provides a multi-phase structured UV-curable powder coating resin and a preparation method thereof, comprising (1) obtaining an emulsion of a liquid UV resin by heating the liquid UV resin and an emulsifier, dispersing, and adding deionized water for emulsification; (2) melting and dispersing a solid UV resin, a phase change agent, an emulsifier, and deionized water; adding the emulsion of the liquid UV resin with stirring to thoroughly mix; temperature is lowered during the stirring to obtain a suspension; (3) press filtering the suspension of the UV-curable powder coating resin to obtain a filter cake; (4) drying and classifying the filter cake to obtain the multi-phase structured UV-curable powder coating resin. The multi-phase structured UV-curable powder coating resin is prepared from the aforementioned method. The present disclosure has the properties of both the liquid and solid UV resin and can be sprayed as a powder coating.

A thin plate molding material includes a resin composition containing a resin component and a filling material, and a reinforced fiber with a predetermined fiber length. The content ratio of the reinforced fiber is a predetermined ratio. The mixing ratio of the resin component is a predetermined ratio.

A cured article includes a cured thermoset resin matrix defining an article surface. Hollow glass microspheroids are dispersed in the cured thermoset resin matrix. A low profile additive package is dispersed in the cured thermoset resin matrix. A plurality of carbon fiber bundles are present and wet by the cured thermoset resin matrix. The matrix formed from a prepolymer and styrenic monomer. A free radical initiator is provided to cure the thermoset resin matrix and having limited decomposition products with a boiling point of between 160-210° C.; wherein the article emits less than 250 parts per million (ppm) of volatiles as measured after heating to 185° C. at a rate of 14° C./min and held for 1 minute.

The present disclosure describes thermoformable sheets capable of retaining an absorbing stain, pigmented sealer or clear sealer. The unique resin binder formulations and products include porosity-promoting agents that result in the resin binder having a porous surface capable of being stained, while still having the favorable properties of traditional Thermofoil products. The methods of the invention produce a Thermofoil product that can be stained with a variety of stains and colorants after manufacturing to suit the individual builder's or homeowner's preference.

An object of the present invention is to more conveniently provide a copolyester for a polyester film which exhibits excellent dimensional stability and in particular excellent dimensional stability against environmental changes in, for example, temperature and humidity, and has a small film elongation percentage at 110° C. A copolyester of the present invention comprises: (A) an aromatic dicarboxylic acid component; (B) an alkylene glycol component; and (C1) a dimer acid component and/or (C2) a dimer diol component, wherein the copolyester contains, with reference to a molar number of a total dicarboxylic acid component, 0.5 to 3.5 mol % of the dimer acid component (C1) and/or 0.3 to 5.0 mol % of the dimer diol component (C2).

A two-part masterbatch comprising: a first part comprising an unsaturated thermoplastic polymer, wherein the first part (typically, the unsaturated thermoplastic polymer of the first part) has an iodine value of at least 10; and a second part comprising an oxygen scavenging catalyst; packaging articles (e.g., preforms and plastic containers), and methods.

The present invention provides a multi-phase structured UV-curable powder coating resin and a preparation method thereof, comprising (1) obtaining an emulsion of a liquid UV resin by heating the liquid UV resin and an emulsifier, dispersing, and adding deionized water for emulsification; (2) melting and dispersing a solid UV resin, a phase change agent, an emulsifier, and deionized water; adding the emulsion of the liquid UV resin with stirring to thoroughly mix; temperature is lowered during the stirring to obtain a suspension; (3) press filtering the suspension of the UV-curable powder coating resin to obtain a filter cake; (4) drying and classifying the filter cake to obtain the multi-phase structured UV-curable powder coating resin. The multi-phase structured UV-curable powder coating resin is prepared from the aforementioned method. The present disclosure has the properties of both the liquid and solid UV resin and can be sprayed as a powder coating.

The present teachings include powder coating including a plurality of core/shell particles. Each particle of plurality of core/shell particles has a size of from about 3 microns to about 100 microns. Each particle of the plurality of core/shell particles has a core including a cross-linkable crystalline polyester resin having a melting temperature of less than about 150° C. Each particle of the plurality of core/shell particles has a shell including a cross-linkable amorphous polyester resin having a glass transition temperature greater than 40° C. Each particle of the plurality of core/shell particles includes a thermal initiator.