Deterioration of gas barrier properties due to sedimentation of aggregates in a coating liquid is decreased or minimized. A coating liquid for producing a gas barrier laminate contains a carboxy group-containing polymer, polyvalent metal-containing particles, a high molecular weight dispersant with an acidic group, and an organic solvent, and has a pH in a range of 4 to 6 at 25° C.

Deterioration of gas barrier properties due to sedimentation of aggregates in a coating liquid is decreased or minimized. A coating liquid for producing a gas barrier laminate contains a carboxy group-containing polymer, polyvalent metal-containing particles, a high molecular weight dispersant with an acidic group, and an organic solvent, and has a pH in a range of 4 to 6 at 25° C.

A method of manufacturing a film having an oxygen transmission rate (OTR) value in the range of 0.1 to 200 cc/m.sup.2*24 h at 23° C., 50% relative humidity (RH), and an OTR value in the range of 0.1 to 2000 cc/m.sup.2*24 h at 38° C. at 85% RH, comprising at least 60% by weight nanocellulose based on the weight of the total amount of fibers in the film, wherein the method comprises the steps of, providing an aqueous suspension comprising said nanocellulose; forming a web from said aqueous suspension; calendering said web at a line load of at least 40 kN/m, and at a temperature of at least 60° C. wherein said film is formed and said web has an OTR value in the range of 50 to 10 000 cc/m.sup.2*24 h at 23° C., 50% RH before said calendering step, or more preferably in the range of 500 to 5000 cc/m.sup.2*24 h at 23° C., 50% RH before said calendering step.

The present invention provides coated films and packages formed from such films. In one aspect, a partially coated film comprises (a) a film having two outer surfaces, wherein a first outer surface is provided by a film layer that comprises from 70 to 100 percent by weight of a polyolefin having a density of 0.860 to 0.965 g/cm.sup.3; and (b) a coating on the first outer surface of the film comprising polyurethane, wherein the coating covers less than 25% of the surface area of the first outer surface of the film and wherein the coated portion of the film exhibits an Elmendorf tear in at least one of the machine direction or cross direction that is at least 20% less than the Elmendorf tear of the uncoated portion in the same direction, with the Elmendorf tear being measured in accordance with ASTM D1922.

The present invention provides coated films and packages formed from such films. In one aspect, a partially coated film comprises (a) a film having two outer surfaces, wherein a first outer surface is provided by a film layer that comprises from 70 to 100 percent by weight of a polyolefin having a density of 0.860 to 0.965 g/cm.sup.3; and (b) a coating on the first outer surface of the film comprising polyurethane, wherein the coating covers less than 25% of the surface area of the first outer surface of the film and wherein the coated portion of the film exhibits an Elmendorf tear in at least one of the machine direction or cross direction that is at least 20% less than the Elmendorf tear of the uncoated portion in the same direction, with the Elmendorf tear being measured in accordance with ASTM D1922.

A tire has a material diffusion barrier, and a method produces the same. In an embodiment, a method for producing a material diffusion barrier on a tire comprises exposing a surface of the tire to a cationic solution to produce a cationic layer on the surface. The method further comprises exposing the cationic layer to an anionic solution to produce an anionic layer on the cationic layer, wherein a layer comprises the cationic layer and the anionic layer. The layer comprises the material diffusion barrier.

According to at least one embodiment, there is provided a hard coat laminate film having a total light transmittance of 80% or more and having (γ) a hard coat on at least one surface of (α) an aromatic-polycarbonate resin film containing 30 mol % or more of a structural unit derived from 4,4′-(3,3,5-trimethylcyclohexane-1,1-diyl)diphenol when the total of the structural units derived from aromatic dihydroxy compounds is 100 mol %. According to another embodiment, there is provided a hard coat laminate film having a total light transmittance of 80% or more and having (γ) a hard coat on at least one surface of a transparent laminate film constituted of (α) an aromatic-polycarbonate resin film containing 30 mol % or more of a structural unit derived from 4,4′-(3,3,5-trimethylcyclohexane-1,1-diyl)diphenol, when the total of the structural units derived from aromatic dihydroxy compounds is 100 mol %, and (β) a poly(meth)acrylimide resin film.

A laminated film including a resin substrate, and a coating layer on the resin substrate. The coating layer contains a water-soluble polymer, at least one of a silane coupling agent and a hydrolysate thereof, at least one of a metal alkoxide and a hydrolysate thereof, and an inorganic layered compound.

An object of the present invention is to provide a barrier film whose gas barrier properties hardly deteriorate even after a retort treatment and after a Gelboflex test. The barrier film of the present invention includes a barrier coat layer, an inorganic oxide deposition layer, and a substrate layer, in this order, wherein the barrier coat layer has a hardness of 1.10 GPa or more and 1.55 GPa or less, and a plastic deformation rate of 21.0% or more.

An object of the present invention is to provide a moisture barrier laminate including a moisture trapping layer that maximizes its moisture trapping performance and exhibits an excellent moisture barrier property. The moisture barrier laminate of the present invention includes a gas barrier film substrate A having a gas barrier layer a1 and a moisture trapping layer B formed on the film substrate A as a base. On a surface of the moisture trapping layer B opposite to the film substrate A, a protective resin layer C having a moisture permeability in a range of 4.0×10 to 5.0×10.sup.4 g/m.sup.2.Math.day at 40° C. and 90% RH is laminated.