Modified plastic surfaces with perfluoropolymers are provided, whereby plastic surfaces that are intended for use under tribological conditions have substantially improved assembly properties and/or sliding friction properties and exhibit a very low degree of wear. Accordingly, modified plastic surfaces with perfluoropolymers are provided in which, after a reactive conversion under mechanical stress at room temperature, at least the reactive —NH groups and/or —OH groups present at the surface of plastics are present in a chemically covalently coupled manner with the perfluoropolymer carboxylic acid halide present at least in the surface-proximate region of modified perfluoropolymer (micro)powders and/or with the grafted (meth)acrylic acid halide present via perfluoropolymer (peroxy) radicals of the perfluoropolymer (micro)powders and/or (meth)acrylic acid that has been modified into (meth)acrylic acid halide before the reactive conversion.

IMPROVING RECYCLED PLASTICS AND METHODS THEREOF The present invention provides methods for reducing extractables from plastic articles made from recycled plastic. The method includes the steps of: (a) providing a plastic article in a chamber; and (b) providing a fluorination gas in the chamber, thereby exposing the plastic article to the fluorination gas. The method results in the reduction of the extractables from the plastic article

The present invention provides methods for reducing extractables from plastic articles and improving barrier properties of such plastic articles. The method includes the steps of: (a) providing a plastic article in a chamber; and (b) providing a fluorination gas and a second gas, such as oxygen or another halogen other than fluorine, in a chamber, thereby exposing the plastic article to the fluorination gas and the second gas. The method produces a treated plastic article that is both low in extractable components and suitable for use in packaging formulations containing an organic ingredient.

A method for preparing a retreaded tire, the method comprising (a) providing a tire casing; (b) providing a pre-cured tire tread; (c) applying a primer composition to the tire casing, the pre-cured tread, or both the tire casing and the pre-cured tread therefore form at least one primer layer, where the primer composition includes a halogenating agent and a solvent; (d) applying a urethane-based adhesive composition to at least one of the tire casing, an adhesive layer, the pre-cured tread, or the at least one primer layer; (e) mating the pre-cured tread to the tire casing to thereby sandwich the adhesive layer between the pre-cured tread and the tire casing and form a pre-cured composite: and (f) allowing the adhesive layer of the pre-cured composite to cure and thereby form a retreaded tire.

Methods for forming a coating can include preparing a nanocomposite film including surface modified silicon dioxide nanoparticles, applying an oxygen plasma treatment to the nanocomposite film to form a treated nanocomposite film, and applying a fluorosilane solution to the treated nanocomposite film to form the coating. A coating can include a nanocomposite film including surface modified silicon dioxide nanoparticles, the nanocomposite film having an oxygen plasma treated surface, and a monolayer of a fluoro alkyl chain

The present invention provides an optical member comprising a silicone material having excellent antifouling property while having good light transmittance, heat resistance, and strength, and an optical semiconductor device and illumination apparatus having excellent antifouling property. The present invention is an optical member comprising a silicone material containing a fluorinated surface, the proportion of F atoms being from 0.1 to 45 at % and/or the ratio of F atoms relative to C atoms being from 0.01 to 1.00 in the atomic composition percentage according to X-ray photoelectron spectroscopy (XPS) of the fluorinated surface.

A method for the direct fluorination of plastics and articles made from plastics is presented. The novel method includes ensuring extremely low oxygen and moisture content in the chamber before the primary fluorination step, ramping the fluorine concentration during the fluorination step, and providing a quenching step for improved shelf-life. Containers processed by the novel method demonstrate a marked improvement in barrier properties for organic solutions.

A method for rendering material surfaces inert is provided. Exemplary surfaces include ceramic, metal or plastic surfaces. The method is accomplished with functionalized perfluorinated compounds for the formation of hyperhydrophobic structures on the surfaces to create inert surfaces. The inert surfaces produced or can be produced in this way have an extremely low surface energy, are resistant to deposits of substances or cells and have a very low coefficient of friction. Practical uses of the inert surfaces are also provided.

A laminate body of a rubber layer and a resin layer made of a resin, wherein the rubber layer includes a surface-treated superficial layer 4 directly united with the resin layer without any intervening adhesive layer.

An elastomeric article is formed from a blend of nitrile rubber and polychloroprene rubber. The elastomeric article can be a glove, such as a medical exam glove. The elastomeric article is softer than a conventional nitrile elastomeric article. The elastomeric article is formed from a blended rubber latex emulsion of nitrile and polychloroprene. The blended rubber latex emulsion may be free of sulfur and vulcanization accelerators.