A chemical modification process for a polymer component comprising at least one polymer comprising, as reactive groups, amine groups and/or hydroxyl groups, the process comprising a step of covalent reaction between some or all of the reactive groups and at least one functional compound comprising at least one group able to react in a covalent manner with said reactive groups, the functional compound(s) being selected from epoxide compounds, anhydride compounds, acyl halide compounds, silyl ether compounds and mixtures thereof, characterised in that the covalent reaction step is carried out in the presence of at least one supercritical fluid.

A chemical modification process for a polymer component comprising at least one polymer comprising, as reactive groups, amine groups and/or hydroxyl groups, the process comprising a step of covalent reaction between some or all of the reactive groups and at least one functional compound comprising at least one group able to react in a covalent manner with said reactive groups, the functional compound(s) being selected from epoxide compounds, anhydride compounds, acyl halide compounds, silyl ether compounds and mixtures thereof, characterised in that the covalent reaction step is carried out in the presence of at least one supercritical fluid.

Disclosed herein is a composite material comprising a substrate coated with a block copolymer brush, where the block copolymer brush comprises a first block of a hydrophobic polymer conjugated to a nitric oxide source, where the first block of the hydrophobic polymer is covalently bonded to a surface of the substrate or a first block of a cationic polymer covalently bonded to a surface of the substrate and a second block of a hydrophilic polymer, extending from the first block to form an outer surface of the block copolymer brush.

Solid-state branching and/or crosslinking of aliphatic polyamide or polyester articles is achieved using a topical approach. A surface of the article is coated with a composition that includes a polyene and a free radical initiator. The article and applied coating are then heated to induce branching and/or crosslinking in the polyamide or polyester. This is performed below the crystalline melting temperature of the polyamide or polyester, or in the case of a fabric, below the melting temperature of the fibers in the fabric. Fabrics treated in this manner exhibit reduced or even no dripping in vertical flame tests.

Disclosed herein is a composite material suitable for inhibiting biofilm growth, the composite material comprising a substrate material and a random copolymeric material covalently bonded to a surface of the substrate material. The random copolymer contains repeating units having at least one functional group bearing a cationic charge and repeating units having at least one functional group bearing an anionic charge, where the repeating units are derived from compatible monomers that belong to different monomer classes having differing polymerisation kinetics. Specifically, the random copolymeric material is poly(AMPTMA-ran-SPM), wherein AMPTMA is (3-acrylamidopropyl) trimethylammonium chloride and SPM is 3-sulfopropyl methacrylate potassium. Also disclosed are methods of manufacturing said material and applications thereof.

Disclosed herein is a composite material suitable for inhibiting biofilm growth, the composite material comprising a substrate material and a random copolymeric material covalently bonded to a surface of the substrate material. The random copolymer contains repeating units having at least one functional group bearing a cationic charge and repeating units having at least one functional group bearing an anionic charge, where the repeating units are derived from compatible monomers that belong to different monomer classes having differing polymerisation kinetics. Specifically, the random copolymeric material is poly(AMPTMA-ran-SPM), wherein AMPTMA is (3-acrylamidopropyl) trimethylammonium chloride and SPM is 3-sulfopropyl methacrylate potassium. Also disclosed are methods of manufacturing said material and applications thereof.

Provided is a hard coat laminate having excellent abrasion resistance and heat resistance. The hard coat laminate includes: a substrate; and a base layer disposed on one main surface side of the substrate, in which the base layer contains inorganic nanoparticles, the base layer contains oxygen atoms, carbon atoms, and silicon atoms, the base layer has, on a surface side opposite to the substrate, a first region in which a compositional ratio of carbon atoms to all elements excluding hydrogen decreases as a distance from the substrate increases, in a region other than the first region of the base layer, a compositional ratio of carbon atoms to all elements excluding hydrogen is 5 atom % to 40 atom %, and a compositional ratio of carbon atoms on a surface of the first region is 1 atom % or less.

Forming a two-dimensional polymeric sheet includes translating a portion of a flexible substrate through a first liquid precursor to coat the portion of the flexible substrate with the first liquid precursor, thereby yielding a precursor-coated portion of the flexible substrate. The precursor-coated portion of the flexible substrate is translated through an interface between the first liquid precursor and a second liquid precursor, thereby reacting the first liquid precursor on the precursor-coated portion of the flexible substrate with the second liquid precursor to yield a polymer-coated portion of the flexible substrate.

A processing method of a base material sheet includes winding out the base material sheet wound up by a first core and a first porous sheet wound up by a second core, winding up by a third core the base material sheet and the first porous sheet to be overlapped with each other, and processing the base material sheet by a first processing liquid held in the first porous sheet; and winding out the base material sheet and the first porous sheet overlappingly wound up by the third core, winding up the first porous sheet by the second core, and winding up the base material sheet by the first core.

A processing method of a base material sheet includes winding out the base material sheet wound up by a first core and a first porous sheet wound up by a second core, winding up by a third core the base material sheet and the first porous sheet to be overlapped with each other, and processing the base material sheet by a first processing liquid held in the first porous sheet; and winding out the base material sheet and the first porous sheet overlappingly wound up by the third core, winding up the first porous sheet by the second core, and winding up the base material sheet by the first core.