A flame-retardant rigid polyurethane foam contains a flame retardant, the foam having a ratio of the maximum peak intensity ratio (P1) of the foam after moist heat treatment of the foam for one week at a temperature of 80° C. and a humidity of 85% to the maximum peak intensity ratio (P2) of the foam before this moist heat treatment of 85% or more (P1/P2x100). The P1 and P2 each refer to the ratio of the maximum peak intensity of 1390 to 1430 cm.sup.−1 to the maximum peak intensity of 1500 to 1520 cm.sup.−1 when the infrared absorption spectrum is measured at a position 5 to 10 mm from the surface of the foam, and the average intensity of 1900 to 2000 cm.sup.−1 is adjusted to zero.

Hydrofluoroolefin (“HFO”)-containing isocyanate-reactive compositions, foam-forming compositions containing such isocyanate-reactive compositions, rigid foams made using such foam-forming compositions, and methods for producing such foams, including use of such foams as panel insulation. The isocyanate-reactive compositions include a polyol composition, a blowing agent composition, and a catalyst composition. The polyol composition includes 50% to 80% by weight, based on total weight of the polyol composition, of an aromatic polyester polyol having a functionality of 1.5 to 2.5 and an OH number of 150 to 360 mg KOH/g, and an amine-initiated polyether polyol having an OH number of more than 500 mg KOH/g and a functionality of 2.5 to 4. The blowing agent composition includes a hydrofluoroolefin and water. The catalyst composition includes a morpholine, an imidazole, a quaternary ammonium carboxylate, and a metal carboxylate.

Pest-resistant polyurethane spray foam formulations and products, including building insulation, are described. The “B” side of the formulation comprises water; a polyol composition comprising one or more polyols selected from glycerin-sucrose polyols, Mannich polyols, and aromatic polyester polyols, catalyst(s); surfactant(s); a blowing agent; and 0.5 to 5 wt.%, based on the amount of spray foam formulation, of a composition comprising a capsaicin compound. Capsaicin compounds can be successfully incorporated into spray foam formulations that process well to give high- quality foams. The foams inhibit termite infestation and can help to minimize or avoid structural damage that might otherwise go undetected.

A novel polymerizable composition, which can be used in 1K aerosol can systems for forming a foam, include a reactive precursor mixture, which is subjected to one or more deoxygenation measures so that it does not react during storage, and an alkyl metal compound, such as an organic borane compound as initiator. Since the initiation of the polymerization is enabled by oxygen, particularly oxygen from ambient air, the curing of the composition is not dependent on ambient moisture and proceeds even at low temperatures, including those below 0° C. The composition has a fast curing time when contacted with oxygen or air, and the resulting final cured product has a high quality.

A polymeric foam precursor composition including the following components: (a) a di- or tri-functional (meth)acrylate oligomer (2); (b) a di- or higher-functional thiol compound (3); and (c) a borane compound (4) as initiator.
The foam precursor composition can be isocyanate free, and the curing rate is largely moisture independent and can cure at low temperatures, below freezing point.

A flame-retardant urethane resin composition comprises a polyisocyanate compound, a polyol compound, a trimerization catalyst, a foaming agent, a foam stabilizer, and an additive, in which the trimerization catalyst is at least one selected from the group consisting of a nitrogen-containing aromatic compound, a carboxylic acid alkali metal salt, a tertiary ammonium salt, and a quaternary ammonium salt, and the additive comprises red phosphorus and at least one selected from the group consisting of a phosphoric acid ester, a phosphate-containing flame retardant, a bromine-containing flame retardant, a boron-containing flame retardant, an antimony-containing flame retardant, and a metal hydroxide.

A flame-retardant urethane resin composition comprises a polyisocyanate compound, a polyol compound, a trimerization catalyst, a foaming agent, a foam stabilizer, and an additive, in which the trimerization catalyst is at least one selected from the group consisting of a nitrogen-containing aromatic compound, a carboxylic acid alkali metal salt, a tertiary ammonium salt, and a quaternary ammonium salt, and the additive comprises red phosphorus and at least one selected from the group consisting of a phosphoric acid ester, a phosphate-containing flame retardant, a bromine-containing flame retardant, a boron-containing flame retardant, an antimony-containing flame retardant, and a metal hydroxide.

A flame-retardant urethane resin composition comprises a polyisocyanate compound, a polyol compound, a trimerization catalyst, a foaming agent, a foam stabilizer, and an additive, in which the trimerization catalyst is at least one selected from the group consisting of a nitrogen-containing aromatic compound, a carboxylic acid alkali metal salt, a tertiary ammonium salt, and a quaternary ammonium salt, and the additive comprises red phosphorus and at least one selected from the group consisting of a phosphoric acid ester, a phosphate-containing flame retardant, a bromine-containing flame retardant, a boron-containing flame retardant, an antimony-containing flame retardant, and a metal hydroxide.

This disclosure relates to silicone foam compositions for forming foamed silicone elastomers, the respective foamed silicone elastomers formed therefrom and to methods of making such compositions and foamed silicone elastomers. The silicone rubber foam composition comprises the (a) one or more organosilicon compounds having an average of at least two silicon bonded alkoxy groups per molecule selected from one or more silicone resins and/or silicone resin intermediates; (b) a Lewis acid catalyst; (c) one or more surfactants; and (d) one or more organopolysiloxane polymers having an average of at least two, alternatively at least three silicon bonded hydrogen groups per molecule.

A flame-retardant rigid polyurethane foam contains a flame retardant, the foam having a ratio of the maximum peak intensity ratio (P1) of the foam after moist heat treatment of the foam for one week at a temperature of 80? C. and a humidity of 85% to the maximum peak intensity ratio (P2) of the foam before this moist heat treatment of 85% or more (P1/P2?100). The P1 and P2 each refer to the ratio of the maximum peak intensity of 1390 to 1430 cm.sup.?1 to the maximum peak intensity of 1500 to 1520 cm.sup.?1 when the infrared absorption spectrum is measured at a position 5 to 10 mm from the surface of the foam, and the average intensity of 1900 to 2000 cm.sup.?1 is adjusted to zero.