A method of producing a polyurethane or polyisocyanurate foam is provided which involves the use of a specific combination of hydrofluoroolefin blowing agents and cell nucleators. The resulting foams have excellent long term thermal insulating performance and have reduced thickness in comparison to conventional thermal insulating boards. The rigid polyurethane and polyisocyanurate boards may be used to insulate refrigeration bodies, such as those employed in vehicles comprising refrigeration units, and cold storage containers.

The present invention relates to mixtures of 1,1,1,4,4,4-hexafluorobutene (1336mzzm) and 1-chloro-3,3,3-trifluoropropene (1233zd). The blends are useful as blowing agents for polymer foam, solvents, aerosol propellants and heat transfer media.

A flexible discontinuous process produces a series of at least two articles containing thermally insulating polyurethane foam from at least three streams (A), (B) and (C). The process involves mixing the at least three streams with different mixing ratios and injecting the mixture into cavities of the articles. A production unit can be used for performing this process.

In the phenolic resin foam laminate board (10), a surface material (2) is arranged on at least one of one side of a phenolic resin foam (1) and the back side of the one side. The phenolic resin foam (1) has a density of not less than 22 kg/m.sup.3 and not more than 50 kg/m.sup.3, a cell diameter of not less than 50 μm and not more than 170 μm, and a closed cell ratio of not less than 80%. When HCFO-1224yd(Z), aliphatic hydrocarbons having a carbon number of 6 or less, chlorinated saturated hydrocarbons having a carbon number of 5 or less, and hydrofluoroolefin are gas components, the phenolic resin foam contains only HCFO-1224yd (Z) as a gas component. A cell internal pressure of air bubble is 0.20 atm or more.

A method for preparing rigid polyurethane (PUR) foams or rigid polyisocyanurate (PIR) foams in which method the rigid PUR or PIR foam is prepared by reacting a composition (C) comprising: at least one isocyanate-reactive component (B1) having functional groups selected from hydroxyl, amine and thiol groups; at least one isocyanate component (A1) having an average functionality of less than 2.70; and at least one blowing agent [blowing agent (BA), herein after]; with the proviso that the overall average functionality [F.sub.n,avg(A), herein after] of all isocyanate components present in the composition (C) is less than 2.70; wherein the composition (C) is characterized by an isocyanate index X, wherein the rigid PUR or PIR foams are produced by depositing the composition (C) between two gas-tight facing sheets and wherein the rigid PUR or PIR foam is characterized by a difference Δλ between the initial thermal conductivity value λ.sub.ini and the aged thermal conductivity value λ.sub.aged of said rigid PUR or PIR foam wherein: when X≤200 then Δλ<1.35; and when X>200 then Δλ<[6.49−(4.46*F.sub.n,avg(A))−(0.02348*X)+(0.492*F.sub.n,avg(A)*F.sub.n,avg(A))+(0.01343*F.sub.n,avg(A)*X)+0.3].

A catalyst system useful in the production of polyurethane and/or polyisocyanurate foams using hydrohaloolefin blowing agents.

The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a precipitation-resistant metal-based catalyst used alone or in combination with an amine catalyst.

Disclosed are HCFO-containing isocyanate-reactive compositions, polyurethane foam-forming compositions containing such isocyanate-reactive compositions, rigid polyurethane foams made using such polyurethane foam-forming compositions, and methods for producing such foams, including use of such foams as insulation in the construction of refrigerated storage devices. The isocyanate-reactive composition can exhibit a long shelf life, be shelf-stable, and produce a foam with good thermal insulation properties.

Chemically modified polyesters, foamable compositions thereof that form low density foams, and methods of making the foamable compositions and foams are disclosed. The compositions comprise an amorphous copolyester, or amorphous co-polyesterpolycarbonate or amorphous co-polyesterpolyether or combination thereof. Additionally, uses for the low density foams are disclosed.

HCFO-containing isocyanate-reactive compositions, foam-forming compositions containing such isocyanate-reactive compositions, rigid PUR-PIR foams made using such foam-forming compositions, and methods for producing such foams, including use of such foams as insulation in discontinuous foam panel applications. The isocyanate-reactive composition includes a polyol blend, a blowing agent composition, and a tertiary amine catalyst. The polyol blend includes: (1) an aromatic polyester polyol having a functionality of 1.5 to less than 2.5 and an OH number of 150 to 360 mg KOH/g; (2) an aromatic polyester polyol having a functionality of at least 2.5 and an OH number greater than 360 mg KOH/g, which is present in an amount of at least 10% by weight, based on the total weight of the aromatic polyester polyol in the polyol blend; and (3) an amine-initiated polyether polyol having an OH number of at least 500 mg KOH/g and a functionality of 2.5 to 4. The blowing agent composition includes a hydrochlorofluoroolefin and a carbon dioxide generating chemical blowing agent.