Polyurethane foam-forming compositions, methods of producing polyurethane foams, polyurethane foams produced from such compositions made by such methods, as well as isocyanate-reactive compositions. The polyurethane foam-forming compositions include a polyol blend, a blowing agent composition, and a polyisocyanate. The polyol blend includes an aromatic amine-initiated polyether polyol, a saccharide-initiated polyether polyol, and an aromatic polyester polyol and has a content of —C.sub.2H.sub.4O— units of 3 to 6% by weight, based on the total weight of the polyurethane foam-forming composition. The blowing agent composition includes a hydrochlorofluoroolefin and a carbon dioxide-generating chemical blowing agent.

This invention relates to compositions comprising 1,2-dichloro-1,2-difluoroethylene (i.e., CFO-1112) and an additional component. The compositions described herein may be useful, for example, in foam blowing applications.

Textiles backed with a polyurethane cushion are produced by applying a layer of frothed polyurethane-forming mixture to a surface of the textile. The mixture contains both water and a physical blowing agent. The layer expands due to the action of the water and the physical blowing agent and cures to form an attached cushion having a density of 176 g/L or less.

The present disclosure provides azeotrope or azeotrope-like compositions including trifluoroiodomethane (CF.sub.3I) and 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca), and a method of forming an azeotrope or azeotrope-like composition comprising the step of combining 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and trifluoroiodomethane (CF.sub.3I) to form an azeotrope or azeotrope-like comprising 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and trifluoroiodomethane (CF.sub.3I) having a boiling point of about −24.46° C.±0.30° C. at a pressure of about 14.40 psia±0.30 psia.

The present disclosure provides azeotrope or azeotrope-like compositions including trifluoroiodomethane (CF.sub.3I) and 1,1,1,3,3,3-hexafluoropropane (HFC-236fa), and a method of forming an azeotrope or azeotrope-like composition comprising the step of combining 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) and trifluoroiodomethane (CF.sub.3I) to form an azeotrope or azeotrope-like comprising 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) and trifluoroiodomethane (CF.sub.3I) having a boiling point of about −22.70° C.±0.30° C. at a pressure of about 14.30 psia±0.30 psia.

Polyurethane foam-forming compositions, methods of producing polyurethane foams, polyurethane foams produced from such compositions made by such methods, as well as isocyanate-reactive compositions. The polyurethane foam-forming compositions include a polyol blend, a blowing agent composition, and a polyisocyanate. The polyol blend includes an aromatic amine-initiated polyether polyol, a saccharide-initiated polyether polyol, and an aromatic polyester polyol and has a content of —C.sub.2H.sub.4O— units of 3 to 6% by weight, based on the total weight of the polyurethane foam-forming composition. The blowing agent composition includes a hydrochlorofluoroolefin and a carbon dioxide-generating chemical blowing agent.

The present invention relates to a non-crosslinked block copolymer foam composition, characterised in that it is in the form of a polymer matrix comprising closed cells containing gas, said matrix comprising: from 90 to 99.9% by weight of said block copolymer; and from 0.01 to 10% by weight of metal carbonate, for the total weight of the foam composition. The present invention also relates to a foamable composition and a method for manufacturing said foam, as well as the use of the foam in sports shoe soles, balloons or balls, gloves, personal protection equipment, rail soles, automobile parts, construction parts, electrical and electronic equipment parts, audio equipment, sound- and/or heat-proofing, and parts used to damp vibrations.

Heterogeneous azeotrope or azeotrope-like compositions comprising trifluoroiodomethane (CF.sub.3I) and water which may include from about 47.7 wt. % to about 99.0 wt. % trifluoroiodomethane (CF.sub.3I) and from about 1.0 wt. % to about 52.3 wt. % water and having a boiling point between about 18.0° C. and about 19.0° C. at a pressure of between about 58.0 psia and about 60.0 psia. The azeotrope or azeotrope-like compositions may be used to separate impurities from trifluoroiodomethane (CF.sub.3I).

The invention relates to a non-cross-linked copolymer foam with polyamide blocks and polyether blocks, wherein: the polyamide blocks of the copolymer have an average molar mass of from 200 to 1,500 g/mol; the polyether blocks of the copolymer have an average molar mass of from 800 to 2,500 g/mol; and the weight ratio of the polyamide blocks to the polyether blocks of the copolymer is from 0.1 to 0.9. The invention also relates to a method for manufacturing said foam and items manufactured from said foam.

The invention relates to a process for manufacturing a copolymer foam containing polyamide blocks and polyether blocks, comprising the following steps: mixing the copolymer melt with a blowing agent, said copolymer having a coefficient of thermal diffusivity a and a crystallization temperature T.sub.c; providing a mold of thickness h at a temperature T.sub.m; injecting the mixture of the copolymer and of the blowing agent at a temperature T.sub.p, into the closed mold; foaming the mixture by opening the mold;
in which the maintenance time between the injection of the mixture of the copolymer and of the blowing agent into the closed mold and the opening of the mold is within the range extending from (t.sub.opt−25%) to (t.sub.opt+25%),
t.sub.opt being expressed in seconds and obtained by equation (I):

[00001]$\begin{array}{cc}{t}_{\mathrm{opt}}=-\frac{1}{{\pi }^2}\frac{h^2}{a}\ln \left(\frac{\pi }{4}\frac{T_m-T_c}{T_m-T_p}\right),& \left(I\right)\end{array}$

in which a is expressed in m.sup.2/s, h is expressed in m and T.sub.m, T.sub.c and T.sub.p are expressed in ° C.