According to an exemplary embodiment of the present invention, provided is a latex composition for dip molding, which includes a copolymer latex formed by polymerizing an isoprene monomer, an ethylenically unsaturated nitrile monomer, and an ethylenically unsaturated acid monomer, wherein a dip-molded article made of the latex composition for dip molding exhibits a durability test result of 45 minutes or more.

According to an exemplary embodiment of the present invention, provided is a latex composition for dip molding, which includes a copolymer latex formed by polymerizing an isoprene monomer, an ethylenically unsaturated nitrile monomer, and an ethylenically unsaturated acid monomer, wherein a dip-molded article made of the latex composition for dip molding exhibits a durability test result of 45 minutes or more.

According to an exemplary embodiment of the present invention, provided is a latex composition for dip molding, which includes a copolymer latex formed by polymerizing an isoprene monomer, an ethylenically unsaturated nitrile monomer, and an ethylenically unsaturated acid monomer, wherein a dip-molded article made of the latex composition for dip molding exhibits a durability test result of 45 minutes or more.

The present invention provides an latex auxiliary composition for producing a latex solution, comprising: a sulfur-free crosslinking agent, which has aluminum oxide, calcium chloride, magnesium oxide, and zirconium dioxide; and a biomass filler, which has sorbitol, polyacrylate, laurate, 1,2-glycerol diacetate, and 1,3-glycerol diacetate; wherein when the sulfur-free crosslinking agent and biomass filler are added to the latex solution, based on 100 parts of the latex, the amount of the sulfur-free crosslinking agent is 0.1˜5.0 parts, and the amount of the biomass filler is 0.1˜20.0 parts.

The present invention provides an latex auxiliary composition for producing a latex solution, comprising: a sulfur-free crosslinking agent, which has aluminum oxide, calcium chloride, magnesium oxide, and zirconium dioxide; and a biomass filler, which has sorbitol, polyacrylate, laurate, 1,2-glycerol diacetate, and 1,3-glycerol diacetate; wherein when the sulfur-free crosslinking agent and biomass filler are added to the latex solution, based on 100 parts of the latex, the amount of the sulfur-free crosslinking agent is 0.1˜5.0 parts, and the amount of the biomass filler is 0.1˜20.0 parts.

An exemplary embodiment provides a method for preparing a latex composition for dip forming, the method including: (a) preparing a monomer mixture including a conjugated diene-based monomer, an ethylenically unsaturated nitrile monomer and an ethylenically unsaturated acid monomer; (b) introducing an additive including an inorganic solvent, an emulsifier and starch into the monomer mixture; and (c) preparing a copolymer latex by polymerizing the monomer mixture, wherein a content of the starch is 0.1 to 4.9 parts by weight with respect to 100 parts by weight of the monomer mixture.

An exemplary embodiment provides a method for preparing a latex composition for dip forming, the method including: (a) preparing a monomer mixture including a conjugated diene-based monomer, an ethylenically unsaturated nitrile monomer and an ethylenically unsaturated acid monomer; (b) introducing an additive including an inorganic solvent, an emulsifier and starch into the monomer mixture; and (c) preparing a copolymer latex by polymerizing the monomer mixture, wherein a content of the starch is 0.1 to 4.9 parts by weight with respect to 100 parts by weight of the monomer mixture.

A nanoparticle includes a copolymer comprising a vinyl-aromatic monomer and a heterocyclic monomer. The copolymer is crosslinked with a multifunctional crosslinking agent polymerizable through an addition reaction. A nanoparticle and elastomer composition is disclosed. Several methods of mixing heterocyclic and non-heterocyclic monomer nanoparticles into an elastomer are also disclosed. These methods include mixing in a multi-elements static mixer and an intermeshing mixer with venting, among others.

A nanoparticle includes a copolymer comprising a vinyl-aromatic monomer and a heterocyclic monomer. The copolymer is crosslinked with a multifunctional crosslinking agent polymerizable through an addition reaction. A nanoparticle and elastomer composition is disclosed. Several methods of mixing heterocyclic and non-heterocyclic monomer nanoparticles into an elastomer are also disclosed. These methods include mixing in a multi-elements static mixer and an intermeshing mixer with venting, among others.

An example of a method, for three-dimensional (3D) printing, includes applying a build material and patterning at least a portion of the build material. The patterning includes selectively applying a wetting amount of a binder fluid on the at least the portion of the build material and subsequently selectively applying a remaining amount of the binder fluid on the at least the portion of the build material. An area density in grams per meter square meter (gsm) of the wetting amount ranges from about 2 times less to about 30 times less than area density in gsm of the remaining amount.