The present invention provides an organometal catalyst having a cationic metal complex and a borate-based bulky anion, where the metal is one or more selected from the group consisting of metals in group 13, a method for preparing the same, and a method for preparing an oligomer or a polymer using the same.

The present invention provides an organometal catalyst having a cationic metal complex and a borate-based bulky anion, where the metal is one or more selected from the group consisting of metals in group 13, a method for preparing the same, and a method for preparing an oligomer or a polymer using the same.

Adhesive hot-melt formulations with a main polymeric component, of at least one isotactic metallocene butene-1 polymer composition, that has a low viscosity, and that has a bimodal composition, directly obtained during polymerization, in two consecutive and separate reaction steps. Moreover, said hot-melts include less than 5% by weight of at least one viscosity modifier that is not solid at room temperature. Such unusually low level of said additives, surprisingly allows to attain substantially improved levels both of high adhesiveness and cohesion. The adhesive hot-melt formulations include less than 5% by weight of a polyethylene wax or of a blend of polyethylene waxes, that characterized by a highly linear/non-branched structure and by an exceptionally low Polydispersity Index. The presence of such peculiar polyethylene waxes, that are partially incompatible with the butene-1 polymer composition, allows to use the disclosed hot-melt formulations even in the presence of fibrous or perforated substrates.

Adhesive hot-melt formulations with a main polymeric component, of at least one isotactic metallocene butene-1 polymer composition, that has a low viscosity, and that has a bimodal composition, directly obtained during polymerization, in two consecutive and separate reaction steps. Moreover, said hot-melts include less than 5% by weight of at least one viscosity modifier that is not solid at room temperature. Such unusually low level of said additives, surprisingly allows to attain substantially improved levels both of high adhesiveness and cohesion. The adhesive hot-melt formulations include less than 5% by weight of a polyethylene wax or of a blend of polyethylene waxes, that characterized by a highly linear/non-branched structure and by an exceptionally low Polydispersity Index. The presence of such peculiar polyethylene waxes, that are partially incompatible with the butene-1 polymer composition, allows to use the disclosed hot-melt formulations even in the presence of fibrous or perforated substrates.

Oriented, multilayer shrink films, either clear or opaque, comprise a core layer and at least one skin layer. The core layer has a thickness greater than the thickness of the at least one skin layer. The at least one skin layer comprises at least one cyclic-olefin copolymer as the predominant component thereof. The core layer comprises a blend of a polyolefin polymer and a polybutene-1 copolymer with ethylene, the butene-1 constituting over 75% by weight of the polybutene-1 copolymer. The film has a shrinkage of at least 20% in at least one of the machine and transverse directions of formation when said film is heated to a temperature of between 80 and 100° C. Optionally the films can include a propylene-based elastomer, a styrenic based block copolymer elastomer, reclaim including the components of the film, or combinations thereof.

Oriented, multilayer shrink films, either clear or opaque, comprise a core layer and at least one skin layer. The core layer has a thickness greater than the thickness of the at least one skin layer. The at least one skin layer comprises at least one cyclic-olefin copolymer as the predominant component thereof. The core layer comprises a blend of a polyolefin polymer and a polybutene-1 copolymer with ethylene, the butene-1 constituting over 75% by weight of the polybutene-1 copolymer. The film has a shrinkage of at least 20% in at least one of the machine and transverse directions of formation when said film is heated to a temperature of between 80 and 100° C. Optionally the films can include a propylene-based elastomer, a styrenic based block copolymer elastomer, reclaim including the components of the film, or combinations thereof.

A terpolymer compositions made from or containing: A) From 80 wt % to 97 wt %; of a first propylene, ethylene, 1-butene terpolymer having: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %; ii) the content of 1-butene derived units ranging from 7.2 wt % to 14.8 wt %; and B) From 20 wt % to 3 wt %; of a second propylene, ethylene, 1-butene terpolymer having: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %; ii) the content of 1-butene derived units ranging from 14.4 wt % to 26.5 wt %; and the terpolymer composition having the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 3.0 g/10 min to 20.0 g/10 min; the sum of the amounts of A) and B) being 100 wt %.

A terpolymer compositions made from or containing: A) From 80 wt % to 97 wt %; of a first propylene, ethylene, 1-butene terpolymer having: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %; ii) the content of 1-butene derived units ranging from 7.2 wt % to 14.8 wt %; and B) From 20 wt % to 3 wt %; of a second propylene, ethylene, 1-butene terpolymer having: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %; ii) the content of 1-butene derived units ranging from 14.4 wt % to 26.5 wt %; and the terpolymer composition having the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 3.0 g/10 min to 20.0 g/10 min; the sum of the amounts of A) and B) being 100 wt %.

A terpolymer compositions made from or containing: A) From 80 wt % to 97 wt %; of a first propylene, ethylene, 1-butene terpolymer having: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %; ii) the content of 1-butene derived units ranging from 7.2 wt % to 14.8 wt %; and B) From 20 wt % to 3 wt %; of a second propylene, ethylene, 1-butene terpolymer having: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %; ii) the content of 1-butene derived units ranging from 14.4 wt % to 26.5 wt %; and the terpolymer composition having the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 3.0 g/10 min to 20.0 g/10 min; the sum of the amounts of A) and B) being 100 wt %.

The present invention relates to a blend containing at least two different polyolefins which is characterized in that it contains as a further constituent an amorphous poly-alpha-olefin which is based on the monomers ethene, propene and 1-butene and has a viscosity at 190° C. of 200 mPa*s to 200,000 mPa*s, wherein it contains polyethylene and polypropylene as at least two different polyolefins and wherein the polyethylene has a melt flow index [MFI 2.16 kg@190° C.] determined according to the method ISO 1133 reported in the description of less than 10 g/10 min, preferably of 0.01 to 2 g/10 min, and the polypropylene has a melt flow index [MFI 2.16 kg@230° C.] determined according to the method reported in the description of less than 50 g/10 min, preferably of 0.01 to 25 g/10 min, to a process for producing such blends and to the use thereof.