Patent classifications
C08L23/26
Crosslinked Polyolefin Foam and Process for Producing Same
The process disclosed includes an extruder under extrusion conditions at a temperature from 50° C. to 250° C., and a polymer composition. The polymer composition includes (A) greater than or equal to 5 wt % of a silane functionalized olefin-based polymer with first melting temperature, Tm1, (B) optionally, a nonsilane functionalized polyolefin, with second melting temperature, Tm2, (C) a highly effective silanol condensation catalyst (HEC), (D) a permeability modifier, and (E) optionally, a scorch inhibitor. The process includes introducing a physical blowing agent into the polymer composition to form a foamable composition. The foamable composition is cooled to a foaming temperature from 10° C. less than to 10° C. greater than Tm1. The foamable composition from an extruder exit die to form a foam composition. The foam composition is moisture cured to form a crosslinked foam composition having a density from 0.010 g/cc to 0.200 g/cc, and a gel content from 5% to 100%.
Crosslinked Polyolefin Foam and Process for Producing Same
The process disclosed includes an extruder under extrusion conditions at a temperature from 50° C. to 250° C., and a polymer composition. The polymer composition includes (A) greater than or equal to 5 wt % of a silane functionalized olefin-based polymer with first melting temperature, Tm1, (B) optionally, a nonsilane functionalized polyolefin, with second melting temperature, Tm2, (C) a highly effective silanol condensation catalyst (HEC), (D) a permeability modifier, and (E) optionally, a scorch inhibitor. The process includes introducing a physical blowing agent into the polymer composition to form a foamable composition. The foamable composition is cooled to a foaming temperature from 10° C. less than to 10° C. greater than Tm1. The foamable composition from an extruder exit die to form a foam composition. The foam composition is moisture cured to form a crosslinked foam composition having a density from 0.010 g/cc to 0.200 g/cc, and a gel content from 5% to 100%.
SPHERICAL PARTICLES COMPRISING NANOCLAY-FILLED-POLYMER AND METHODS OF PRODUCTION AND USES THEREOF
Methods for producing highly spherical particles that comprise: mixing a mixture comprising: (a) nanoclay-filled-polymer composite comprising a nanoclay dispersed in a thermoplastic polymer, (b) a carrier fluid that is immiscible with the thermoplastic polymer of the nanoclay-filled-polymer composite, optionally (c) a thermoplastic polymer not filled with a nanoclay, and optionally (d) an emulsion stabilizer at a temperature at or greater than a melting point or softening temperature of the thermoplastic polymer of the nanoclay-filled-polymer and the thermoplastic polymer, when included, to disperse the nanoclay-filled-polymer composite in the carrier fluid; cooling the mixture to below the melting point or softening temperature to form nanoclay-filled-polymer particles; and separating the nanoclay-filled-polymer particles from the carrier fluid.
SPHERICAL PARTICLES COMPRISING NANOCLAY-FILLED-POLYMER AND METHODS OF PRODUCTION AND USES THEREOF
Methods for producing highly spherical particles that comprise: mixing a mixture comprising: (a) nanoclay-filled-polymer composite comprising a nanoclay dispersed in a thermoplastic polymer, (b) a carrier fluid that is immiscible with the thermoplastic polymer of the nanoclay-filled-polymer composite, optionally (c) a thermoplastic polymer not filled with a nanoclay, and optionally (d) an emulsion stabilizer at a temperature at or greater than a melting point or softening temperature of the thermoplastic polymer of the nanoclay-filled-polymer and the thermoplastic polymer, when included, to disperse the nanoclay-filled-polymer composite in the carrier fluid; cooling the mixture to below the melting point or softening temperature to form nanoclay-filled-polymer particles; and separating the nanoclay-filled-polymer particles from the carrier fluid.
Composition for radar penetration cover of vehicle
Disclosed are a composition for a radar penetration cover of a vehicle which may improve dielectric properties while maintaining excellent mechanical physical properties, and the radar penetration cover including the same. The composition for a radar penetration cover includes: an amount of about 60 to 70 wt % of polybutylene terephthalate (PBT), an amount of about 10 to 20 wt % of polycarbonate (PC), and an amount of about 11.5 to 27.8 wt % of an additive including polypropylene (PP) having maleic anhydride (MAH) grafted to an end group and a glass fiber (GF), wt % based on the total weight of the composition.
Composition for radar penetration cover of vehicle
Disclosed are a composition for a radar penetration cover of a vehicle which may improve dielectric properties while maintaining excellent mechanical physical properties, and the radar penetration cover including the same. The composition for a radar penetration cover includes: an amount of about 60 to 70 wt % of polybutylene terephthalate (PBT), an amount of about 10 to 20 wt % of polycarbonate (PC), and an amount of about 11.5 to 27.8 wt % of an additive including polypropylene (PP) having maleic anhydride (MAH) grafted to an end group and a glass fiber (GF), wt % based on the total weight of the composition.
Low-water-vapor-permeability polyolefin-elastomer film and method for preparing the same
The present disclosure discloses a low-water-vapor-permeability polyolefin-elastomer film and its preparation method. The film comprises: 50-100 mass parts of a matrix resin, 0-40 mass parts of a modified resin, 0.001-2 mass parts of an activator, 0.1-3 mass parts of an organic peroxide, 0.02-5 mass parts of an assistant cross-linker, 0.02-2 mass parts of a silane coupling agent, 0.005-2 mass parts of a light stabilizer, and 0-20 mass parts of a water blocking filler. In the present disclosure, by adding the modified resin and the activator that have an active group, a cross-linking degree and a cross-linking density of the film are improved, and a water-vapor permeability is reduced; by adding the water blocking filler, the water blocking property of the film is further improved, thereby ensuring reliability of the assembly, and prolonging service life of the assembly.
Low-water-vapor-permeability polyolefin-elastomer film and method for preparing the same
The present disclosure discloses a low-water-vapor-permeability polyolefin-elastomer film and its preparation method. The film comprises: 50-100 mass parts of a matrix resin, 0-40 mass parts of a modified resin, 0.001-2 mass parts of an activator, 0.1-3 mass parts of an organic peroxide, 0.02-5 mass parts of an assistant cross-linker, 0.02-2 mass parts of a silane coupling agent, 0.005-2 mass parts of a light stabilizer, and 0-20 mass parts of a water blocking filler. In the present disclosure, by adding the modified resin and the activator that have an active group, a cross-linking degree and a cross-linking density of the film are improved, and a water-vapor permeability is reduced; by adding the water blocking filler, the water blocking property of the film is further improved, thereby ensuring reliability of the assembly, and prolonging service life of the assembly.
Fiber-sizing agent, inorganic reinforcement material, resin composition, and molded article
The purpose of the present invention is to provide a fiber-sizing agent which when applied to an inorganic reinforcement material contained in a resin composition, can provide a molded article having excellent impact resistance and high surface gloss properties. The fiber-sizing agent according to the present invention contains a modified olefin wax (A), a polyolefin resin (B), and a silane-coupling agent (C), wherein the mass ratio (A)/(B) of the modified olefin wax (A) to the polyolefin resin (B) is in the range of 0.2-10.
Fiber-sizing agent, inorganic reinforcement material, resin composition, and molded article
The purpose of the present invention is to provide a fiber-sizing agent which when applied to an inorganic reinforcement material contained in a resin composition, can provide a molded article having excellent impact resistance and high surface gloss properties. The fiber-sizing agent according to the present invention contains a modified olefin wax (A), a polyolefin resin (B), and a silane-coupling agent (C), wherein the mass ratio (A)/(B) of the modified olefin wax (A) to the polyolefin resin (B) is in the range of 0.2-10.