The composition includes a polyester resin comprising at least one α,β-unsaturated ester group, an epoxy resin, a compound comprising at least one hydroxyl group; and a photoinitiator that generates acid on exposure to actinic radiation. A method of repairing a damaged surface using the composition is also described.

The composition includes a polyester resin comprising at least one α,β-unsaturated ester group, an epoxy resin, a compound comprising at least one hydroxyl group; and a photoinitiator that generates acid on exposure to actinic radiation. A method of repairing a damaged surface using the composition is also described.

A reactive mixture comprising a Fire, Smoke and Toxicity retardant (FST) composition for making a polyisocyanurate and/or polyurethane (PIR/PUR) comprising material, said FST composition comprising: a) at least one compound having at least one ethylenically unsaturated moiety having a number average equivalent weight<160 g/mol, and b) optionally one or more radical initiator compound characterized in that the onset temperature for radical polymerization (T.sub.onset) of the ethylenically unsaturated compound with or without the radical initiator is 2° C. up to 40° C. lower than the maximum reaction temperature achieved during the process for making the PIR/PUR material (reaction exotherm (T.sub.reaction)).

A reactive mixture comprising a Fire, Smoke and Toxicity retardant (FST) composition for making a polyisocyanurate and/or polyurethane (PIR/PUR) comprising material, said FST composition comprising: a) at least one compound having at least one ethylenically unsaturated moiety having a number average equivalent weight<160 g/mol, and b) optionally one or more radical initiator compound characterized in that the onset temperature for radical polymerization (T.sub.onset) of the ethylenically unsaturated compound with or without the radical initiator is 2° C. up to 40° C. lower than the maximum reaction temperature achieved during the process for making the PIR/PUR material (reaction exotherm (T.sub.reaction)).

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.

A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

A reactive resin component contains at least one radically curable unsaturated compound and at least one silanized filler. The proportion of all inorganic solids in the reactive resin component is at least 60 wt. % and the proportion of the at least one silanized filler, which has a grain diameter of 4 μm or smaller, is 0.5 to 60 wt. %, based on the reactive resin component. The reactive resin component can be used in a reactive resin system.

A reactive resin component contains at least one radically curable unsaturated compound and at least one silanized filler. The proportion of all inorganic solids in the reactive resin component is at least 60 wt. % and the proportion of the at least one silanized filler, which has a grain diameter of 4 μm or smaller, is 0.5 to 60 wt. %, based on the reactive resin component. The reactive resin component can be used in a reactive resin system.

Disclosed herein are a cannabidiol (CBD)-containing bio-based polyurethane composite material and a preparation thereof. The composite material is prepared from a component A and a component B in a weight ratio of 100:(20-50), where the component A includes 40-60 parts by weight of a vegetable oil-based polyol, 35-50 parts by weight of polyether polyol I, 0-10 parts by weight of polyether polyol II, 0.5-5 parts by weight of CBD, 0-5 parts by weight of a natural pigment, 0.5-3 parts by weight of silicon oil, 0-5 parts by weight of a cross-linking agent, 0.2-1 part by weight of a catalyst and 0.8-4 parts by weight of water, and the component B includes 20-50 parts by weight of modified methylene diphenyl diisocyanate (MDI).