An optical sheet 10 of the present invention includes a laminate including a polarizing layer 4 containing at least one kind of a light absorbing agent and having a polarizing function, and a protective layer 1 laminated on the polarizing layer 4, in which in the polarizing layer 4, a value of a* is 0 or more and 30 or less and a value of b* is 0 or more and 30 or less in an L*a*b* color system defined by JIS Z 8781-4, and in the optical sheet 10, a size of a Q Blue value defined by Australian Standard Australia/New Zealand Standard 1067-2016 is 0.70 or more. Thus, even when the optical sheet is toned to brown, blue light can be distinguished with excellent distinguishability.

The present invention relates to azo dyes of formula (1), wherein D is a radical of formula (2) or (3), R.sub.1 and R.sub.2 independently denote hydrogen; C.sub.6-C.sub.10aryl which is unsubstituted or substituted by cyano, carboxy, hydroxy, halogen, C.sub.1-C.sub.6alkyl, or C.sub.1-C.sub.6alkoxy; C.sub.1-C.sub.12alkyl which may be interrupted one or more times by —O—, —S—, —NR.sub.4—, —CO—, —COO— or —OOC—, and is unsubstituted or substituted by cyano, carboxy, hydroxy, C.sub.6-C.sub.10aryl, or C.sub.6-C.sub.10aryloxy, which C.sub.6-C.sub.10aryl or C.sub.6-C.sub.10aryloxy is unsubstituted or substituted by cyano, carboxy, hydroxy, halogen, C.sub.1-C.sub.6alkyl, or C.sub.1-C.sub.6alkoxy; R.sub.3 and R.sub.4 are each independently of the other hydrogen, halogen, nitro, cyano, trifluoromethyl, carboxy, C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6alkoxy, C.sub.1-C.sub.6alkylcarbonyl, C.sub.6-C.sub.10arylcarbonyl, C.sub.1-C.sub.6alkoxycarbonyl, C—C.sub.6alkylsulfonyl, C.sub.1-C.sub.6alkylsulfonylamino or C.sub.1-C.sub.4alkanoylamino; and R.sub.5 is halogen, nitro, cyano, trifluoromethyl, carboxy, C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6alkoxy, C.sub.1-C.sub.6alkylcarbonyl, C.sub.6-C.sub.10arylcarbonyl, C.sub.1-C.sub.6alkoxycarbonyl, C.sub.1-C.sub.6alkylsulfonyl, C.sub.1-C.sub.6alkylsulfonylamino or C.sub.1-C.sub.4alkanoylamino; and R.sub.6, R.sub.7, R.sub.8 and R.sub.9 independently of each other are hydrogen, hydroxy, halogen, cyano, nitro or C.sub.1-C.sub.4alkanoylamino, and the radicals X independently denote N or C—H, with the proviso that at least one radical X denotes C—H, which are distinguished by their good lightfastness properties.

##STR00001##

This invention relates to a laundry care composition comprising a laundry care ingredient and a polymeric thiophene hueing agent.

This invention relates to a laundry care composition comprising a laundry care ingredient and a polymeric thiophene hueing agent.

An object that is to be achieved by the present invention is to provide an azo pigment having excellent transparency, suitable dispersibility, and a low viscosity, an ink, and the like. An azo pigment according to the present invention has a zeta potential of 80 to 30 mV in isopropanol (IPA). The content of a metal element in the azo pigment is preferably 0.05 to 2.00 parts by mass relative to 100 parts by mass of the azo pigment. The metal element is preferably an iron element. The ratio (Fe/C) of the concentration Fe (atomic %) of an iron element in the surfaces of particles of the azo pigment to the concentration C (atomic %) of a carbon element in the surfaces of the particles of the azo pigment which are determined by X-ray photoelectron spectroscopy is preferably 0.20 or less.

The present invention relates to azo dyes of formula (1), wherein D is a radical of formula (2) or (3), R.sub.1 and R.sub.2 independently denote hydrogen; C.sub.6-C.sub.10 aryl which is unsubstituted or substituted by cyano, carboxy, hydroxy, halogen, C.sub.1-C.sub.6alkyl, or C.sub.1-C.sub.6alkoxy; C.sub.1-C.sub.12alkyl which may be interrupted one or more times by O, S, NR.sub.4, CO, COO or OOC, and is unsubstituted or substituted by cyano, carboxy, hydroxy, C.sub.6-C.sub.10 aryl, or C.sub.6-C.sub.10 aryloxy, which C.sub.6-C.sub.10 aryl or C.sub.6-C.sub.10 aryloxy is unsubstituted or substituted by cyano, carboxy, hydroxy, halogen, C.sub.1-C.sub.6alkyl, or C.sub.1-C.sub.6alkoxy; R.sub.3 and R.sub.4 are each independently of the other hydrogen, halogen, nitro, cyano, trifluoromethyl, carboxy, C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6alkoxy, C.sub.1-C.sub.6alkylcarbonyl, C.sub.6-C.sub.10 arylcarbonyl, C.sub.1-C.sub.6alkoxycarbonyl, C.sub.1-C.sub.6alkylsulfonyl, C.sub.1-C.sub.6alkylsulfonylamino or C.sub.1-C.sub.4 alkanoylamino; and R.sub.5 is halogen, nitro, cyano, trifluoromethyl, carboxy, C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6alkoxy, C.sub.1-C.sub.6alkylcarbonyl, C.sub.6-C.sub.10 arylcarbonyl, C.sub.1-C.sub.6alkoxycarbonyl, C.sub.1-C.sub.6alkylsulfonyl, C.sub.1-C.sub.6alkylsulfonylamino or C.sub.1-C.sub.4 alkanoylamino; and R.sub.6, R.sub.7, R.sub.8 and R.sub.9 independently of each other are hydrogen, hydroxy, halogen, cyano, nitro or C.sub.1-C.sub.4 alkanoylamino, and the radicals X independently denote N or CH, with the proviso that at least one radical X denotes CH, which are distinguished by their good lightfastness properties. ##STR00001##

The present invention is related to a process for obtaining organic ammonium salts (OAS) and their derivatives, supramolecular surfactants (SS), which simultaneously present the properties of traceability and detergents dispersant of organic scales. Organic ammonium salts (OAS) and their derivatives supramolecular surfactants (SS) have applications as differentiators, markers, or tracers in fuels derived from hydrocarbons; and also to disperse organic scales or inhibit the gums precipitation both in injectors and intake valves of automotive vehicle engines. Organic ammonium salts (OAS) are obtained through an acid-base reaction between a molecule from the azo family and an amine. Once the OAS is obtained, it reacts with an organic compound (OC) so that through non-covalent interactions, a self-assembly process occurs that gives rise to the SS. Said process is based on green chemistry, that is, in the absence of solvents. These OAS and SS are quantified through the analytical techniques of ultraviolet-visible (UV-VIS) and high-performance liquid chromatography (HPLC) through a calibration curve. Additionally, its performance as a gum-dispersing agent in a single-cylinder engine is evaluated.

The present invention relates to azo dyes of formula ##STR00001##
wherein R.sub.1 denotes C.sub.1-C.sub.12 alkyl which is unsubstituted or substituted by one or more C.sub.1-C.sub.12 alkoxy groups, hydroxyl groups, amino groups, cyano groups or halogen atoms and which may be interrupted one or more times by the radical O, S, NR.sub.4, COO or OOC; R.sub.4 is hydrogen or C.sub.1-C.sub.12 alkyl; either R.sub.2 is cyano and R.sub.3 is halogen or R.sub.2 is halogen and R.sub.3 is cyano; and Ar represents a carbocyclic or heterocyclic aromatic radical, to the process for the preparation thereof, to mixtures containing said dyes and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fiber materials, more especially textile materials.

This invention relates to a laundry care composition comprising a laundry care ingredient and a polymeric thiophene hueing agent.

A family of covalent kinetic stabilizer compounds that selectively and covalently react with the prominent plasma protein transthyretin in preference to more than 4000 other human plasma proteins is disclosed. A contemplated compound corresponds in structure to Formula I, below, where the various substituents are defined within, and ##STR00001##
reacts chemoselectively with one or two of four Lys-15 -amino groups within the transthyretin tetramer. The crystal structure confirms the binding orientation of the compound substructure and the conjugating amide bond. A covalent transthyretin kinetic stabilizer exhibits superior amyloid inhibition potency, compared to a non-covalent counterpart, and inhibits cytotoxicity associated with amyloidogenesis.