A dye composition dissolvable within a liquid crystal host device (including: polymer dispersed liquid crystal, polymer network liquid crystal, polymer stabilized liquid crystal, liquid crystal displays and similar devices), comprising eutectic mixtures of dichroic metallomesogen molecules. The aforesaid metallomesogen molecules comprise chromophore groups synthesized by physical and chemical mixing methods.

The present invention relates to [1] a process for producing a pigment water dispersion liquid of polymer particles containing an azomethine metal complex pigment (A), said process including the step of subjecting a mixture containing the azomethine metal complex pigment (A), an uncrosslinked aromatic group-containing polymer (b) and water to dispersion treatment using a medialess disperser at an accumulated input energy of not more than 5.0 kWh/kg, [2] a pigment water dispersion liquid containing an azomethine metal complex pigment (A) and a polymer dispersant (B), in which in an optical absorption spectrum of the pigment water dispersion liquid, a ratio of a maximum absorbance (A1.sub.max) in a wavelength range of not less than 440 nm and less than 465 nm to a maximum absorbance (A2.sub.max) in a wavelength range of not less than 420 nm and less than 440 nm [(A1.sub.max)/(A2.sub.max)] is not less than 1.000, and [3] a water-based ink for ink-jet printing, containing the aforementioned pigment water dispersion liquid.

The present invention relates to [1] a process for producing a pigment water dispersion liquid of polymer particles containing an azomethine metal complex pigment (A), said process including the step of subjecting a mixture containing the azomethine metal complex pigment (A), an uncrosslinked aromatic group-containing polymer (b) and water to dispersion treatment using a medialess disperser at an accumulated input energy of not more than 5.0 kWh/kg, [2] a pigment water dispersion liquid containing an azomethine metal complex pigment (A) and a polymer dispersant (B), in which in an optical absorption spectrum of the pigment water dispersion liquid, a ratio of a maximum absorbance (A1.sub.max) in a wavelength range of not less than 440 nm and less than 465 nm to a maximum absorbance (A2.sub.max) in a wavelength range of not less than 420 nm and less than 440 nm [(A1.sub.max)/(A2.sub.max)] is not less than 1.000, and [3] a water-based ink for ink-jet printing, containing the aforementioned pigment water dispersion liquid.

A dye composition dissolvable within a liquid crystal host device (including: polymer dispersed liquid crystal, polymer network liquid crystal, polymer stabilized liquid crystal, liquid crystal displays and similar devices), comprising eutectic mixtures of dichroic metallomesogen molecules. The aforesaid metallomesogen molecules comprise chromophore groups synthesized by physical and chemical mixing methods.