A reactive dye of formula

##STR00001##

wherein M is hydrogen, an alkali metal or one equivalent of an alkaline earth metal, Z.sub.1 is vinyl, β-sulfatoethyl or the radical —NHCO—(CH.sub.2).sub.3—SO.sub.2—CH.sub.2CH.sub.2Cl; R.sub.1 denotes H or sulfo; and R.sub.2 is H, methyl, methoxy or sulfo, n is the number 3; Y is vinyl or a radical —CH.sub.2—CH.sub.2-U and U is —Cl or —OSO.sub.3H,
is suitable for dyeing and printing cellulosic or amide-group-containing fibre materials.

A process for the simultaneous tanning and dyeing of collagen containing fibrous material, wherein the said material is treated with a liquor containing at least one reactive dyestuff selected from the group of formula (1) and (2)

##STR00001## wherein A.sub.1, A.sub.2 and A.sub.3 are each independently of the others the radical of a monoazo, polyazo, metal-complexed azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore having at least one sulfo group, B is an organic bridge member, Q.sub.1, Q.sub.2, Q.sub.3 and Q.sub.4 are each independently of the others hydrogen or unsubstituted or substituted C.sub.1-C.sub.4alkyl, G.sub.1 and G.sub.2 are halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, (Z.sub.1).sub.2-3 is 2 to 3 identical or different fiber reactive radicals, Z.sub.2 and Z.sub.3 are each independently of the other identical or different fiber reactive radicals, and b is the number 0 or 1, by combining two steps of leather production, tanning and dyeing, into a single step, thus, preserving resources and reducing the environmental impact.

A process for the simultaneous tanning and dyeing of collagen containing fibrous material, wherein the said material is treated with a liquor containing at least one reactive dyestuff selected from the group of formula (1) and (2)

##STR00001## wherein A.sub.1, A.sub.2 and A.sub.3 are each independently of the others the radical of a monoazo, polyazo, metal-complexed azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore having at least one sulfo group, B is an organic bridge member, Q.sub.1, Q.sub.2, Q.sub.3 and Q.sub.4 are each independently of the others hydrogen or unsubstituted or substituted C.sub.1-C.sub.4alkyl, G.sub.1 and G.sub.2 are halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, (Z.sub.1).sub.2-3 is 2 to 3 identical or different fiber reactive radicals, Z.sub.2 and Z.sub.3 are each independently of the other identical or different fiber reactive radicals, and b is the number 0 or 1, by combining two steps of leather production, tanning and dyeing, into a single step, thus, preserving resources and reducing the environmental impact.

A reactive dye of formula ##STR00001##
wherein M is hydrogen, an alkali metal or one equivalent of an alkaline earth metal, Z.sub.1 is vinyl, ?-sulfatoethyl or the radical NHCO(CH.sub.2).sub.3SO.sub.2CH.sub.2CH.sub.2Cl; R.sub.1 denotes H or sulfo; and R.sub.2 is H, methyl, methoxy or sulfo, n is the number 3; Y is vinyl or a radical CH.sub.2CH.sub.2-U and U is Cl or OSO.sub.3H, is suitable for dyeing and printing cellulosic or amide-group-containing fibre materials.

A process for the simultaneous tanning and dyeing of collagen containing fibrous material, wherein the said material is treated with a liquor containing at least one reactive dyestuff selected from the group of formula (1) and (2) ##STR00001## wherein A.sub.1, A.sub.2 and A.sub.3 are each independently of the others the radical of a monoazo, polyazo, metal-complexed azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore having at least one sulfo group, B is an organic bridge member, Q.sub.1, Q.sub.2, Q.sub.3 and Q.sub.4 are each independently of the others hydrogen or unsubstituted or substituted C.sub.1-C.sub.4alkyl, G.sub.1 and G.sub.2 are halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, (Z.sub.1).sub.2-3 is 2 to 3 identical or different fiber reactive radicals, Z.sub.2 and Z.sub.3 are each independently of the other identical or different fiber reactive radicals, and b is the number 0 or 1, by combining two steps of leather production, tanning and dyeing, into a single step, thus, preserving resources and reducing the environmental impact.

A process for the simultaneous tanning and dyeing of collagen containing fibrous material, wherein the said material is treated with a liquor containing at least one reactive dyestuff selected from the group of formula (1) and (2) ##STR00001## wherein A.sub.1, A.sub.2 and A.sub.3 are each independently of the others the radical of a monoazo, polyazo, metal-complexed azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore having at least one sulfo group, B is an organic bridge member, Q.sub.1, Q.sub.2, Q.sub.3 and Q.sub.4 are each independently of the others hydrogen or unsubstituted or substituted C.sub.1-C.sub.4alkyl, G.sub.1 and G.sub.2 are halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, (Z.sub.1).sub.2-3 is 2 to 3 identical or different fiber reactive radicals, Z.sub.2 and Z.sub.3 are each independently of the other identical or different fiber reactive radicals, and b is the number 0 or 1, by combining two steps of leather production, tanning and dyeing, into a single step, thus, preserving resources and reducing the environmental impact.