An asymmetric pigment including a first Fabry-Perot structure; and a second Fabry-Perot structure; wherein the first Fabry-Perot structure and the second Fabry-Perot structure have a similar hue angle within +/45 degrees is disclosed. Other asymmetric pigments are also disclosed as well as methods of making the disclosed pigments.

This invention deals with effect pigment comprising a colored hectorite which is produced by ion exchange process of an initial hectorite with a cationic dye, wherein the initial hectorite can be represented by the formula

K.sub.z/n[Li.sub.xMg.sub.(3.0(x+y)ySi.sub.4O.sub.10F.sub.2](I); wherein n is the charge of K and z=x+2y with 0.2<z<0.8; x=0-0.8; y=0-0.4; K is a cation chosen from a first group consisting of Li.sup.+, Na.sup.+, K.sup.+, NH.sub.4.sup.+, Rb.sup.+, Cs.sup.+, Mg.sup.2+, Ca.sup.2+, Ba.sup.2+ or mixtures thereof or from a second group consisting of alkylammonium salts with 2 to 8 C-atoms, wherein the alkyl can be branched or linear, or from a mixture of cations from the first and the second group and represents not occupied octahedral lattice sites.

Furthermore, these colored hectorites can have a coating thereon comprising at least one layer with a high index of refraction >1.8 or a semitransparent metal and optionally an outer protective layer.

A thin film structure including a reflector layer; and a hybrid layer including an organic colored material and at least one of an organic filler and an inorganic filler; wherein a concentration of the at least one of an organic filler or an inorganic filler is in a range of from about 3 wt. % to about 30 wt. %. A method of making a thin film structure is also disclosed.

A composition including a first color shifting pigment having a first color shift that extends from a starting color at normal through a plurality of colors as a viewing angle is increased to a final color, wherein the first color shift rotates counterclockwise relative to, and about, an origin of the L*a*b* color space; and a color filter that transmits a portion of the first color shift of the first color shifting pigment and absorbs a remainder of the first color shift of the first color shifting pigment; wherein the composition has a second color shift different from the first color shift; and wherein the second color shift has a first portion that rotates counterclockwise relative to the origin and a second portion that rotates clockwise relative to the origin is disclosed. A security device including the composition is included. A method of making the composition and a method of authenticating the security device are also disclosed.

A particle including a core particle; and a vapor deposited colorant including an organic colored material that encapsulates the core particle. The particle can be a special effect pigment or a thin film interference pigment. Methods of making the particle are also disclosed.

A particle including a core particle; and a vapor deposited colorant including an organic colored material that encapsulates the core particle. The particle can be a special effect pigment or a thin film interference pigment. Methods of making the particle are also disclosed.

An asymmetric pigment including a first Fabry-Perot structure; and a second Fabry-Perot structure; wherein the first Fabry-Perot structure and the second Fabry-Perot structure have a similar hue angle within +/45 degrees is disclosed. Other asymmetric pigments are also disclosed as well as methods of making the disclosed pigments.

A thin film structure including a reflector layer; and a hybrid layer including an organic colored material and at least one of an organic filler and an inorganic filler; wherein a concentration of the at least one of an organic filler or an inorganic filler is in a range of from about 3 wt. % to about 30 wt. %. A method of making a thin film structure is also disclosed.

A particle including a core particle; and a vapor deposited colorant including an organic colored material that encapsulates the core particle. The particle can be a special effect pigment or a thin film interference pigment. Methods of making the particle are also disclosed.

A method of making a liquid electrophotographic (LEP) paste is disclosed herein. A base paste is made by forming a dispersion of a pigment and a non-polar carrier, adding a transparent resin dispersion to the pigment dispersion to form a dispersion mixture, and homogenizing the dispersion mixture. The transparent resin dispersion includes a polymer dispersed in a non-aqueous carrier. The homogenizing may be accomplished by agitating the dispersion mixture at a frequency of less than 1 kHz, thereby forming the paste.