The use of copper materials as a replacement for the more expensive coinage metals (i.e., silver, gold) in printed circuits has come to the forefront. For printing, the use of nanomaterials has allowed for significant advances through the use of nanoinks. Unfortunately, as the nanoregime is entered, the increased surface area leads to increased reactivity with atmospheric oxygen which results in a reduction in the conductivity of the printed circuits. To overcome this issue, a synthesis method uses a room temperature reduction of a copper organometallic precursor by the simple addition of catechol-based surfactants to prevent oxidation and agglomeration of the final copper nanoparticles. The selection of these catechol-based surfactants is based on non-aqueous solubility, high surface affinity, and anti-oxidative potential as surface ligands.

The invention relates to coated effect pigments, wherein the coating comprises a binder which is suitable for powder paints. They comprise a crystalline and an amorphous fraction which is determined by C.sup.13 NMR MAS relaxation measurements, the relaxation of the .sup.13C cores being fitted as a biexponential relaxation according to the formula (II) and the degree of crystallinity c being in a range between 40 to 85%, and relaxation having a short average relaxation time T.sub.1.sup.s and a long average relaxation time T.sub.1.sup.l, and T.sub.1.sup.l being in a range of from 65 to 130 s. The effect pigments coated according to the invention have at least one endothermic peak with a maximum from a range of T.sub.max=100 to 150° C. and an enthalpy ΔH associated with said peak from a range of 15 J/g to 80 J/g in DSC at a feed speed of 5° C./min, the enthalpy being calculated relative to the amount of the binder. The binders are applied to the effect pigment by way of spontaneous precipitation.

A black IR reflective or transmissive pigment from which LiDAR responsive black coatings can be formed where the pigment displays a Blackness M.sub.y value similar to non-IR reflective carbon black. The CuO particles display small crystallites of less than 18 nm and an (−111)/(111) reflectance intensity ratio of less than 1.2. A method of forming the CuO particles includes precipitation of CuCO3 or CuCO.sub.3/Cu(OH).sub.2 using an alkali carbonate as a precipitant and calcining the precipitate at about 300° C. to about 400° C.

An apparatus is disclosed for producing flakes, the apparatus comprising: a) a support structure for supporting each of two supply cylinders, made of a first material from which flakes are to be produced, and a fatiguing rod assembly including at least one fatiguing rod made of a second material, each fatiguing rod having a diameter smaller than an initial diameter of the two supply cylinders; b) a compression mechanism for urging the surfaces of the two supply cylinders into contact with each fatiguing rod, and c) a drive mechanism for causing the supply cylinders to rotate while making rolling line contact with each fatiguing rod.

The contact pressure between the supply cylinders and each fatiguing rod is set sufficiently high to modify the surface of the supply cylinders by fatigue and result in separation of flakes of the first material from the surfaces of the supply cylinders.

A thin film structure including a reflector layer; and a hybrid layer including an organic colored material and at least one of an organic filler and an inorganic filler; wherein a concentration of the at least one of an organic filler or an inorganic filler is in a range of from about 3 wt. % to about 30 wt. %. A method of making a thin film structure is also disclosed.

The disclosure relates to a composition containing a base material and metal effect pigments (1) contained in the base material, wherein the metal effect pigments (1) are provided with a three dimensional shape selected from the following group: cube, pyramid having triangular outer surfaces, and tetrahedron. Furthermore, metal effect pigments (1) and a method for producing metal effect pigments (1) are provided.

A method for manufacturing platelet-shaped effect pigments includes the steps of a) providing a carrier substrate; b) applying aqueous washing ink droplets to the carrier substrate in first regions forming a first motif; c) applying a reflective coating to the carrier substrate such that a reflective coating is deposited on the carrier substrate in the form of a regular contiguous grid in second regions forming a second motif outside the first regions forming the first motif, wherein the first regions form the first motif and have the washing ink droplets form regular islands within the regular contiguous grid, and a reflective coating is deposited above the washing ink droplets in the first regions forming the first motif; and d) removing the washing ink droplets in the first regions together with the reflective coating present thereon and isolating the removed reflective coating in the form of platelet-shaped effect pigments.

The invention relates to a surface-modified effect pigment comprising particular additives and to the production thereof. The present invention further provides a nail varnish composition comprising a) at least one effect pigment that has been surface-modified with a starting material (additive), where the effect pigment comprises a substrate in platelet form and optionally at least one coating applied to the substrate, b) at least one hydrocarbon resin as binder, and c) at least one solvent or solvent mixture, where the starting material (additive) for surface modification of the effect pigment is at least one compound taken from the group consisting of phosphoric ester-containing, phosphonic ester-containing, phosphonic acid-containing, fatty acid-containing and/or silane-containing compounds or mixtures thereof.

The present invention relates to security, or decorative elements, comprising a transparent, or translucent substrate, which may contain indicia or other visible features in or on its surface, and on at least part of the substrate surface, a first layer, comprising transition metal particles having an average diameter of from 5 nm to 500 nm and a binder, on at least part of the first layer a second layer, comprising an organic material and having a refractive index of from 1.2 to 2.3 and having a thickness of from 20 to 1000 nm, wherein the transition metal is silver, copper, gold and palladium, wherein the weight ratio of transition metal particles to binder in the first layer is in the range from 20:1 to 1:2 in case the binder is a polymeric binder, or wherein the weight ratio of transition metal particles to binder in the first layer is in the range from 5:1 to 1:15 in case the binder is an UV curable binder. The security or decorative element show a certain color in transmission and a different color in reflection and a color flop on the coating side. The color in reflection and the color flop of the security or decorative elements are controlled by adjusting the refractive index and thickness of the second layer.

The invention relates to a surface-modified effect pigment comprising particular additives and to the production thereof. The present invention further provides a nail varnish composition comprising a) at least one effect pigment that has been surface-modified with a starting material (additive), where the effect pigment comprises a substrate in platelet form and optionally at least one coating applied to the substrate, b) at least one hydrocarbon resin as binder, and c) at least one solvent or solvent mixture, where the starting material (additive) for surface modification of the effect pigment is at least one compound taken from the group consisting of phosphoric ester-containing, phosphonic ester-containing, phosphonic acid-containing, fatty acid-containing and/or silane-containing compounds or mixtures thereof.