A modified metal oxide particle material includes: a metal oxide particle material having, on a surface thereof, a functional group other than a phenyl group; and a modifying material formed of a silicon-containing compound having a phenyl group. The modifying material is adhered to the surface of the metal oxide particle material. When the modified metal oxide particle material is washed with methyl ethyl ketone, a ratio (C/H) of a carbon content C (% by mass) to a surface area H (m.sup.2) per 1 g is 0.05 or less, after the washing. The ratio (C/H) is reduced by 0.1 or more, and the modifying material is removed by 50% or more by mass, after the washing compared with before the washing.

A modified metal oxide particle material includes: a metal oxide particle material having, on a surface thereof, a functional group other than a phenyl group; and a modifying material formed of a silicon-containing compound having a phenyl group. The modifying material is adhered to the surface of the metal oxide particle material. When the modified metal oxide particle material is washed with methyl ethyl ketone, a ratio (C/H) of a carbon content C (% by mass) to a surface area H (m.sup.2) per 1 g is 0.05 or less, after the washing. The ratio (C/H) is reduced by 0.1 or more, and the modifying material is removed by 50% or more by mass, after the washing compared with before the washing.

A surface functionalizing method for use in high-throughput in situ synthesis of nucleic acids by 3D inkjet printing. The method includes subjecting a surface of a substrate to hydroxyl enrichment treatment; adding hydrophobic molecules to the surface of the substrate, the hydrophobic molecules being not reactive with phosphoramidite monomers; spraying, by a multi-channel piezoelectric inkjet head assembly, an etching ink to a predetermined area on the surface of the substrate for micro-etching, the etching ink being prepared with a fluoride compound reactive with the hydrophobic molecules; and adding hydrophilic molecules to the surface of the substrate. By using the method, a functionalized surface with given areas being patterned can be formed on the surface of the substrate, and then a same multi-channel piezoelectric inkjet head assembly can be directly used for subsequent high-resolution printing of phosphoramidite monomers and synthesis of nucleic acids.

A method of preparing functionalised graphene is disclosed. The method includes the step of functionalising graphene with a chemical linker when the graphene is in a substantially dry condition.

A method of preparing functionalised graphene is disclosed. The method includes the step of functionalising graphene with a chemical linker when the graphene is in a substantially dry condition.

A process can be used for increasing the molecular weight of low molecular weight α,ω-polysiloxanediols. The process involves heating the low molecular weight α,ω-polysiloxanediols in the presence of acetic anhydride at temperatures of 80° C. to 220° C., preferably at temperatures of 100 to 200° C., and particularly preferably at temperatures of 120-180° C., for 1 h to 24 h, preferably for 2 h to 16 h, and particularly preferably for 3 h to 12 h. The molar amount of the silanol groups used is greater than that of the acetic anhydride used.

A process can be used for increasing the molecular weight of low molecular weight α,ω-polysiloxanediols. The process involves heating the low molecular weight α,ω-polysiloxanediols in the presence of acetic anhydride at temperatures of 80° C. to 220° C., preferably at temperatures of 100 to 200° C., and particularly preferably at temperatures of 120-180° C., for 1 h to 24 h, preferably for 2 h to 16 h, and particularly preferably for 3 h to 12 h. The molar amount of the silanol groups used is greater than that of the acetic anhydride used.

An electron beam curable paint comprises: a dispersion solution of inorganic nanomaterial, a dispersion solution of inorganic nanoultraviolet absorbent, a polyfunctional monomer and an acrylate prepolymer, wherein the dispersion solution of the inorganic nanomaterial is selected from one or two of a dispersion solution of silicon dioxide and a dispersion solution of aluminum oxide, and the dispersion solution of the inorganic ultraviolet absorbent is a dispersion solution of titanium dioxide or a dispersion solution of zinc oxide. The silicon dioxide, the aluminum oxide, the titanium dioxide and the zinc oxide are respectively surface modified and are dissolved in acrylate monomer to form the dispersion solution of the inorganic material without agglomeration.

An electron beam curable paint comprises: a dispersion solution of inorganic nanomaterial, a dispersion solution of inorganic nanoultraviolet absorbent, a polyfunctional monomer and an acrylate prepolymer, wherein the dispersion solution of the inorganic nanomaterial is selected from one or two of a dispersion solution of silicon dioxide and a dispersion solution of aluminum oxide, and the dispersion solution of the inorganic ultraviolet absorbent is a dispersion solution of titanium dioxide or a dispersion solution of zinc oxide. The silicon dioxide, the aluminum oxide, the titanium dioxide and the zinc oxide are respectively surface modified and are dissolved in acrylate monomer to form the dispersion solution of the inorganic material without agglomeration.

Provided is a method for preparing a modified filler. The method includes in sequence providing an acidified aqueous slurry of an untreated inorganic filler which has not been previously dried; an emulsifier material; and a hydrophobating agent having the following structural formula (I):
R.sub.a.sup.−M-X.sub.(4−a)  (I)
wherein: R is C.sub.6 to C.sub.22 alkyl, M is silicon, titanium or zirconium, X is OR′ or halogen, R′ is C.sub.1 to C.sub.4 alkyl, and a is 1;
washing and/or filtering the acidified aqueous slurry to obtain a modified filler; and, optionally, drying the modified filler. Polymeric compositions and articles also are provided.