An aqueous energy curable inkjet ink that includes (A) a non-photopolymerizable resin, (B) a water-soluble photopolymerizable monomer, (C) a pigment having an average particle size of 50 to 300 nm, and (D) at least 25 wt. % water, based on a total weight of the aqueous energy curable inkjet ink. A printed article including the aqueous energy curable inkjet ink in dried and cured form, and a method of forming a printed image with an inkjet printhead are also provided.

A curable composition which comprises (A) an organopolysiloxane represented by formula (1)

##STR00001##

(wherein R.sup.1 represents an alkyl group, R.sup.2 represents an alkyl or aryl group, R.sup.3 represents a hydrogen atom or methyl group, Me represents a methyl group, m is an integer of 1-10, and a and b are integers of 1 or larger, a+b being an integer of 3-120), (B) a photopolymerization initiator, and (C) a hydrosilylation catalyst and which has a surface tension at 23° C. of 23-30 mN/m and a viscosity at 23° C. of 5-80 mPa.Math.s.

A curable composition which comprises (A) an organopolysiloxane represented by formula (1)

##STR00001##

(wherein R.sup.1 represents an alkyl group, R.sup.2 represents an alkyl or aryl group, R.sup.3 represents a hydrogen atom or methyl group, Me represents a methyl group, m is an integer of 1-10, and a and b are integers of 1 or larger, a+b being an integer of 3-120), (B) a photopolymerization initiator, and (C) a hydrosilylation catalyst and which has a surface tension at 23° C. of 23-30 mN/m and a viscosity at 23° C. of 5-80 mPa.Math.s.

A radiation-curable ink jet composition contains a polymerizable compound, a white pigment, and inorganic particles different from the white pigment. The polymerizable compound includes a monofunctional polymerizable compound. The content of the monofunctional polymerizable compound is 80 mass % or more with respect to the total mass of the polymerizable compound contained in the radiation-curable ink jet composition.

A radiation-curable ink jet composition contains a polymerizable compound, a white pigment, and inorganic particles different from the white pigment. The polymerizable compound includes a monofunctional polymerizable compound. The content of the monofunctional polymerizable compound is 80 mass % or more with respect to the total mass of the polymerizable compound contained in the radiation-curable ink jet composition.

Described herein are methods and compositions for forming three-dimensional objects via material jetting processes, the methods including the repeated steps of selectively depositing a liquid thermoset material onto a surface from a nozzle of at least one jetting head in a first specified direction and exposing at least a portion of the liquid thermoset material to a source of actinic radiation in order to form a three-dimensional object from the cured thermoset material, wherein the jetting head is configured to eject droplets of the liquid thermoset material from the nozzle at prescribed elevated operating temperatures, and wherein the liquid thermoset material is chosen so as to possessing prescribed viscosity and rheological characteristics.

Described herein are methods and compositions for forming three-dimensional objects via material jetting processes, the methods including the repeated steps of selectively depositing a liquid thermoset material onto a surface from a nozzle of at least one jetting head in a first specified direction and exposing at least a portion of the liquid thermoset material to a source of actinic radiation in order to form a three-dimensional object from the cured thermoset material, wherein the jetting head is configured to eject droplets of the liquid thermoset material from the nozzle at prescribed elevated operating temperatures, and wherein the liquid thermoset material is chosen so as to possessing prescribed viscosity and rheological characteristics.

An inkjet ink set consisting of a black inkjet ink, a cyan inkjet ink and two inkjet inks A and B, optionally complemented by a white ink and/or a colourless ink, wherein the inkjet ink A has a hue angle H* between 70 and 85 and a chroma C* between 30 and 80; the inkjet ink B has a hue angle H* between 20 and 40 and a chroma C* between 30 and 80; and the CIE L* a* b* coordinates were determined on polyethylene coated white paper for a 2° observer under a D50 light source.

An inkjet ink set consisting of a black inkjet ink, a cyan inkjet ink and two inkjet inks A and B, optionally complemented by a white ink and/or a colourless ink, wherein the inkjet ink A has a hue angle H* between 70 and 85 and a chroma C* between 30 and 80; the inkjet ink B has a hue angle H* between 20 and 40 and a chroma C* between 30 and 80; and the CIE L* a* b* coordinates were determined on polyethylene coated white paper for a 2° observer under a D50 light source.

An actinic radiation-curable inkjet ink according to the present invention contains an actinic radiation polymerizable compound and a linear styrene (meth)acrylic acid ester copolymer dissolved therein. The styrene (meth)acrylic acid ester copolymer has a softening point of 30 to 120° C., and a content of the styrene (meth)acrylic acid ester copolymer is 1 to 50 wt % based on a total mass of the actinic radiation-curable inkjet ink.