An aqueous energy curable inkjet ink that includes (A) a non-photopolymerizable resin, (B) a water-soluble photopolymerizable monomer, (C) a pigment having an average particle size of 50 to 300 nm, and (D) at least 25 wt. % water, based on a total weight of the aqueous energy curable inkjet ink. A printed article including the aqueous energy curable inkjet ink in dried and cured form, and a method of forming a printed image with an inkjet printhead are also provided.

An aqueous energy curable inkjet ink that includes (A) a non-photopolymerizable resin, (B) a water-soluble photopolymerizable monomer, (C) a pigment having an average particle size of 50 to 300 nm, and (D) at least 25 wt. % water, based on a total weight of the aqueous energy curable inkjet ink. A printed article including the aqueous energy curable inkjet ink in dried and cured form, and a method of forming a printed image with an inkjet printhead are also provided.

An object is to provide a nonaqueous inkjet ink composition offering excellent solid filling property and anti-mottling property, as well as excellent ink stability, discharge stability, and scratch resistance, even when printed at high speed on printing targets whose printing face is constituted by a polyvinyl chloride, ethylene-vinyl acetate-based copolymer, or other vinyl-based polymer, etc. As a solution, a nonaqueous inkjet ink composition is provided that contains acrylic-based resin, organic coloring pigment and/or carbon black, alumina, pigment dispersant, and organic solvent, wherein the organic solvent comprises propylene carbonate, diethylene glycol dialkyl ether, and dipropylene glycol alkyl ether acetate, and alumina is contained by 5 to 30 parts by mass relative to 100 parts by mass representing the total of organic coloring pigment and carbon black.

Latexes are provided which may comprise water and resin particles comprising a polymerization product of reactants comprising a dioxane/dioxolane monomer and an additional monomer, wherein the dioxane/dioxolane monomer is an ester of (meth)acrylic acid with an alcohol comprising a dioxane moiety, an ester of (meth)acrylic acid with an alcohol comprising a dioxolane moiety, or both.

An actinic radiation-curable inkjet ink according to the present invention contains an actinic radiation polymerizable compound and a linear styrene (meth)acrylic acid ester copolymer dissolved therein. The styrene (meth)acrylic acid ester copolymer has a softening point of 30 to 120° C., and a content of the styrene (meth)acrylic acid ester copolymer is 1 to 50 wt % based on a total mass of the actinic radiation-curable inkjet ink.

The invention relates to an ink based on near-infrared light polymerization. The method and technology of direct writing three-dimensional printing belong to the field of material processing technology area. The method is: direct writing nozzles move in three-dimensional space or stationery, the ink is squeezed out of the direct writing nozzle, receiving the near-infrared light irradiation, after curing, complete the three-dimensional object forming and curing. The solidifying time t does not exceed the ratio of near-infrared light diameter d.sub.1 and the ink extrusion speed vi, that is, t≤d.sub.1/v.sub.i. Since near-infrared light has a better medium mass penetration, can penetrate the structure during molding to promote both internal and external to a higher degree of curing, so as to achieve cross-scale structure 3D printing, and the method provided by the present invention accurately controls solidifying process of the ink and therefore achieve the DIW array 3D structure real-time curing.

The invention relates to an ink based on near-infrared light polymerization. The method and technology of direct writing three-dimensional printing belong to the field of material processing technology area. The method is: direct writing nozzles move in three-dimensional space or stationery, the ink is squeezed out of the direct writing nozzle, receiving the near-infrared light irradiation, after curing, complete the three-dimensional object forming and curing. The solidifying time t does not exceed the ratio of near-infrared light diameter d.sub.1 and the ink extrusion speed vi, that is, t≤d.sub.1/v.sub.i. Since near-infrared light has a better medium mass penetration, can penetrate the structure during molding to promote both internal and external to a higher degree of curing, so as to achieve cross-scale structure 3D printing, and the method provided by the present invention accurately controls solidifying process of the ink and therefore achieve the DIW array 3D structure real-time curing.

An inkjet recording method contains the sequential steps of: applying an aqueous pre-coat composition to a substrate, or applying and drying the aqueous pre-coat composition to the substrate; and subsequently applying and drying an aqueous ink composition. The aqueous pre-coat composition contains at least an aggregating agent. The aqueous ink composition contains at least a pigment, a polymer dispersant, and resin fine particles. The aggregating agent is selected from a pyrolytic cation resin, an organic acid, or a multivalent metal salt. A neutralizer for the polymer dispersant is selected from an organic amine. In the step of drying the aqueous ink composition, a temperature at which the aqueous ink composition is dried is set to be equal to or higher than a pyrolytic temperature of the aggregating agent.

A pretreatment liquid for an impermeable base material includes an anionic resin, and an aqueous medium, in which the anionic resin has a Clog P value of 1.40 or greater, and a content of a structural unit derived from an alkyl (meth)acrylate containing a chain alkyl group having 2 or more carbon atoms in the anionic resin is less than 5% by mass with respect to a total mass of the anionic resin.

A pretreatment liquid for an impermeable base material includes an anionic resin, and an aqueous medium, in which the anionic resin has a Clog P value of 1.40 or greater, and a content of a structural unit derived from an alkyl (meth)acrylate containing a chain alkyl group having 2 or more carbon atoms in the anionic resin is less than 5% by mass with respect to a total mass of the anionic resin.