An object is to provide a nonaqueous inkjet ink composition offering excellent solid filling property and anti-mottling property, as well as excellent ink stability, discharge stability, and scratch resistance, even when printed at high speed on printing targets whose printing face is constituted by a polyvinyl chloride, ethylene-vinyl acetate-based copolymer, or other vinyl-based polymer, etc. As a solution, a nonaqueous inkjet ink composition is provided that contains acrylic-based resin, organic coloring pigment and/or carbon black, alumina, pigment dispersant, and organic solvent, wherein the organic solvent comprises propylene carbonate, diethylene glycol dialkyl ether, and dipropylene glycol alkyl ether acetate, and alumina is contained by 5 to 30 parts by mass relative to 100 parts by mass representing the total of organic coloring pigment and carbon black.

An object is to provide a nonaqueous inkjet ink composition offering excellent solid filling property and anti-mottling property, as well as excellent ink stability, discharge stability, and scratch resistance, even when printed at high speed on printing targets whose printing face is constituted by a polyvinyl chloride, ethylene-vinyl acetate-based copolymer, or other vinyl-based polymer, etc. As a solution, a nonaqueous inkjet ink composition is provided that contains acrylic-based resin, organic coloring pigment and/or carbon black, alumina, pigment dispersant, and organic solvent, wherein the organic solvent comprises propylene carbonate, diethylene glycol dialkyl ether, and dipropylene glycol alkyl ether acetate, and alumina is contained by 5 to 30 parts by mass relative to 100 parts by mass representing the total of organic coloring pigment and carbon black.

Disclosed are an aqueous UV curable ink and the method of preparing the same. In particular, the disclosure relates to a UV curable aqueous dispersant and a method of preparing the same; a UV curable aqueous ink composition and a method of preparing the same; and a method of forming an image on a recording medium. The UV curable aqueous dispersant according to the disclosure, and the UV curable aqueous ink composition including the same have no limitations in selecting a material, and improve the texture and fastness of an object, which is subjected to printing, in the fields of textile.

Disclosed are an aqueous UV curable ink and the method of preparing the same. In particular, the disclosure relates to a UV curable aqueous dispersant and a method of preparing the same; a UV curable aqueous ink composition and a method of preparing the same; and a method of forming an image on a recording medium. The UV curable aqueous dispersant according to the disclosure, and the UV curable aqueous ink composition including the same have no limitations in selecting a material, and improve the texture and fastness of an object, which is subjected to printing, in the fields of textile.

To provide a copolymer including: a structural unit represented by the following General Formula (1) where X represents a hydrogen atom or a cation; a structural unit expressed by the following Structural Formula (1); and a structural unit represented by the following General Formula (2) where R is a hydrogen atom or a methyl group, L is a single bond or —(CH.sub.2).sub.n—O—CO— where n is an integer in a range of from 2 through 18, and a carbonyl carbon atom in the —(CH.sub.2).sub.n—O—CO— is bound to naphthyl.

##STR00001##

A copolymer including a structural unit represented by General Formula (1) below, and a structural unit represented by General Formula (2) below,

##STR00001##

where, in General Formula (1), R.sup.1 is a hydrogen atom or a methyl group, L.sup.1 is an alkylene group having 2 or greater carbon atoms but 5 or less carbon atoms, and X is a hydrogen atom or a cation,

##STR00002##

where, in General Formula (2), R.sup.2 is a hydrogen atom or a methyl group and L.sup.2 is an alkylene group having 2 or greater carbon atoms but 18 or less carbon atoms.

A copolymer including a structural unit represented by General Formula (1) below, and a structural unit represented by General Formula (2) below,

##STR00001##

where, in General Formula (1), R.sup.1 is a hydrogen atom or a methyl group, L.sup.1 is an alkylene group having 2 or greater carbon atoms but 5 or less carbon atoms, and X is a hydrogen atom or a cation,

##STR00002##

where, in General Formula (2), R.sup.2 is a hydrogen atom or a methyl group and L.sup.2 is an alkylene group having 2 or greater carbon atoms but 18 or less carbon atoms.

The present disclosure provides a white ink including an aqueous ink vehicle, from 5 wt % to 50 wt % of a white metal oxide pigment having an average particulate size from 100 nm to 2,000 nm, from 0.1 wt % to 4 wt % of anionic oxide particulates having an average particulate size from 1 nm to 100 nm, from 2 wt % to 30 wt % of latex particulates having a glass transition temperature from 0 C to 130 C, and a non-ionic or predominantly non-ionic dispersant having an acid number not higher than 100 mg KOH/g based on dry polymer weight. The white metal oxide pigment and anionic oxide particulates are present in the white ink at a weight ratio from 5:1 to 200:1.

The present invention relates to [1] a process for producing pigment-containing modified polymer particles, including the step of reacting pigment-containing polymer particles (A) containing a functional group and a compound (B) containing a reactive group capable of reacting with the functional group of the polymer particles (A) in a medium under such a condition that a ratio [(B)/(A)] of total moles of the reactive group of the compound (B) to total moles of the functional group of the polymer particles (A) is from 0.10 to 0.62; [2] a pigment water dispersion including an aqueous medium and the modified polymer particles produced by the aforementioned process which are dispersed in the aqueous medium; and [3] an ink including the aforementioned pigment water dispersion and an organic solvent. The modified polymer particles are free from formation of coarse particles upon production of pigment particles, so that an ink obtained by using the modified polymer particles can be prevented from suffering from increase in viscosity thereof when the ink is being concentrated by evaporation of water from the ink, and is excellent in rub fastness when printed on a low-water absorbing recording medium.

By use of an ultraviolet curable inkjet ink comprising a colorant, a polymerizable monomer having a specific structure, ethoxyphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, and at least one type selected from the group consisting of an acylphosphine oxide photopolymerization initiator different than the ethoxyphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, a benzophenone photopolymerization initiator, and an indane photopolymerization initiator, wherein the ratio of the content of the polymerizable monomer having the specific structure and the content of the ethoxyphenyl(2,4,6-trimethylbenzoyl)phosphine oxide is 2:1 to 8.5:1 by mass ratio, the content of a monofunctional monomer in the ultraviolet curable inkjet ink is 25% by mass or less, a printed matter having curability and coating film flexibility can be obtained regardless of the amount applied to a recording medium, and the discharge stability is also excellent.