A solvent-free undercoat composition for corrosion control at welds and other repair sites on plastic-sheathed steel pipes with and without cathodic protection, including a component K1: a water-based rubber dispersion for formation of a barrier layer for isolating the metallic repair site from oxygen, water vapor and water penetrating from externally; a component K2: a water-based resin dispersion for adhesion on the metallic surface of the repair site and on the nonpolar surfaces of the plastic sheathing; a component K3: an aqueous emulsion of prehydrolyzed organofunctional silanes for accelerating the drying, for improving the adhesion to the metallic surface, particularly at elevated temperatures, and for increasing the resistance to cathodic disbondment.

A solvent-free undercoat composition for corrosion control at welds and other repair sites on plastic-sheathed steel pipes with and without cathodic protection, including a component K1: a water-based rubber dispersion for formation of a barrier layer for isolating the metallic repair site from oxygen, water vapor and water penetrating from externally; a component K2: a water-based resin dispersion for adhesion on the metallic surface of the repair site and on the nonpolar surfaces of the plastic sheathing; a component K3: an aqueous emulsion of prehydrolyzed organofunctional silanes for accelerating the drying, for improving the adhesion to the metallic surface, particularly at elevated temperatures, and for increasing the resistance to cathodic disbondment.

A solvent-free undercoat composition for corrosion control at welds and other repair sites on plastic-sheathed steel pipes with and without cathodic protection, including a component K1: a water-based rubber dispersion for formation of a barrier layer for isolating the metallic repair site from oxygen, water vapor and water penetrating from externally; a component K2: a water-based resin dispersion for adhesion on the metallic surface of the repair site and on the nonpolar surfaces of the plastic sheathing; a component K3: an aqueous emulsion of prehydrolyzed organofunctional silanes for accelerating the drying, for improving the adhesion to the metallic surface, particularly at elevated temperatures, and for increasing the resistance to cathodic disbondment.

A solvent-free undercoat composition for corrosion control at welds and other repair sites on plastic-sheathed steel pipes with and without cathodic protection, including a component K1: a water-based rubber dispersion for formation of a barrier layer for isolating the metallic repair site from oxygen, water vapor and water penetrating from externally; a component K2: a water-based resin dispersion for adhesion on the metallic surface of the repair site and on the nonpolar surfaces of the plastic sheathing; a component K3: an aqueous emulsion of prehydrolyzed organofunctional silanes for accelerating the drying, for improving the adhesion to the metallic surface, particularly at elevated temperatures, and for increasing the resistance to cathodic disbondment.

Crosslinkable random copolymers comprising atom transfer radical polymerization (ATRP) initiators and crosslinked copolymer films formed from the copolymers are provided. The random copolymers, which are polymerized from one or more alkyl halide functional inimers and one or more monomers having a crosslinkable functionality, are characterized by pendant ATRP initiating groups and pendant crosslinkable groups.

Crosslinkable random copolymers comprising atom transfer radical polymerization (ATRP) initiators and crosslinked copolymer films formed from the copolymers are provided. The random copolymers, which are polymerized from one or more alkyl halide functional inimers and one or more monomers having a crosslinkable functionality, are characterized by pendant ATRP initiating groups and pendant crosslinkable groups.

Crosslinkable random copolymers comprising atom transfer radical polymerization (ATRP) initiators and crosslinked copolymer films formed from the copolymers are provided. The random copolymers, which are polymerized from one or more alkyl halide functional inimers and one or more monomers having a crosslinkable functionality, are characterized by pendant ATRP initiating groups and pendant crosslinkable groups.

Crosslinkable random copolymers comprising atom transfer radical polymerization (ATRP) initiators and crosslinked copolymer films formed from the copolymers are provided. The random copolymers, which are polymerized from one or more alkyl halide functional inimers and one or more monomers having a crosslinkable functionality, are characterized by pendant ATRP initiating groups and pendant crosslinkable groups.

Crosslinkable random copolymers comprising atom transfer radical polymerization (ATRP) initiators and crosslinked copolymer films formed from the copolymers are provided. The random copolymers, which are polymerized from one or more alkyl halide functional inimers and one or more monomers having a crosslinkable functionality, are characterized by pendant ATRP initiating groups and pendant crosslinkable groups.