Methods of coating a substrate are disclosed. The methods comprise applying shear force to a coating composition either before or during application of the coating composition to the substrate. The coating composition comprises a water-borne or solvent-borne film-forming resin and a catalyst associated with a carrier, wherein at least some of the catalyst can be released from the carrier upon application of the shear force. Also provided are coated articles prepared by the methods.

Methods of coating a substrate are disclosed. The methods comprise applying shear force to a coating composition either before or during application of the coating composition to the substrate. The coating composition comprises a water-borne or solvent-borne film-forming resin and a catalyst associated with a carrier, wherein at least some of the catalyst can be released from the carrier upon application of the shear force. Also provided are coated articles prepared by the methods.

A method of manufacturing a semiconductor device, includes forming a sacrificial film made of a polymer having a urea bond on a substrate by supplying an amine and an isocyanate to a surface of the substrate, wherein the sacrificial film is provided in a specific region of the substrate; performing a predetermined process on the substrate on which the sacrificial film is formed; and removing the sacrificial film by heating the substrate to depolymerize the polymer, wherein a carbon bonded to a nitrogen atom contained in an isocyanate group of the isocyanate is a secondary or tertiary non-aromatic carbon.

An erosion resistant article such as rotor blades for helicopters and wind turbines having the leading edge surface protected from damage from high speed impingement of rain or sand with a protective coating formed from specific polyurethane or polyurea coating having a defined set of minimum physical properties where the protective coating can be applied as a liquid coating and cured in place or as a preformed complementary shaped covering to protect the leading edge against erosion damage in service.

An erosion resistant article such as rotor blades for helicopters and wind turbines having the leading edge surface protected from damage from high speed impingement of rain or sand with a protective coating formed from specific polyurethane or polyurea coating having a defined set of minimum physical properties where the protective coating can be applied as a liquid coating and cured in place or as a preformed complementary shaped covering to protect the leading edge against erosion damage in service.

Self-healing polymers used to fabricate electrical devices or to coat electrical devices that have a metal or polymer substrate. The self-healing polymers can be made from modified polymers including polyurethanes, polyureas, polyamides and polyesters and, optionally, cross-linking agents and one or more catalysts. The self-healing polymers can be used to make cable ties, tape, conduit fittings and explosion-proof sealant materials.

Self-healing polymers used to fabricate electrical devices or to coat electrical devices that have a metal or polymer substrate. The self-healing polymers can be made from modified polymers including polyurethanes, polyureas, polyamides and polyesters and, optionally, cross-linking agents and one or more catalysts. The self-healing polymers can be used to make cable ties, tape, conduit fittings and explosion-proof sealant materials.

The present invention relates to a one-component processing method and system for preparing polyurea materials. This method and system involves a polymerization process using cyclic oligomeric polyurea precursors. These cyclic oligomeric precursors have dynamic urea bonds such as hindered urea bonds (HUBs). These cyclic oligomeric precursors exhibit dynamic properties to reversibly dissociate .sub.in situ yielding isocyanate and amine components which polymerize to yield the polyureas, such as linear, branched or cross-linked polyureas. This method and system has advantages over conventional methods that utilize two-component systems. Such two-component systems require the segregation of the isocyanate and amine components to prevent premature or too rapid polymerization. The resulting polyureas are useful for a variety of applications including coatings.

The present invention relates to a one-component processing method and system for preparing polyurea materials. This method and system involves a polymerization process using cyclic oligomeric polyurea precursors. These cyclic oligomeric precursors have dynamic urea bonds such as hindered urea bonds (HUBs). These cyclic oligomeric precursors exhibit dynamic properties to reversibly dissociate .sub.in situ yielding isocyanate and amine components which polymerize to yield the polyureas, such as linear, branched or cross-linked polyureas. This method and system has advantages over conventional methods that utilize two-component systems. Such two-component systems require the segregation of the isocyanate and amine components to prevent premature or too rapid polymerization. The resulting polyureas are useful for a variety of applications including coatings.

The present invention relates to an aqueous polyurethane dispersion, a method for the preparation thereof, a product comprising the same, and use thereof for a coating composition, an impregnating composition, an adhesive or a sealant. The aqueous polyurethane dispersion comprises a polyurethane obtained by reacting a system comprising the following components: A1) at least one polyisocyanate having an isocyanate functionality of not less than 2; A2) at least two different polytetramethylene ether glycols A2a) and A2b), the A2a) having a number average molecular weight of not more than 1500 g/mol, the A2b) having a number average molecular weight of more than 1500 g/mol; and A3) at least one anionic or potentially anionic hydrophilic agent having a number average molecular weight of 32 g/mol to 400 g/mol and containing hydroxyl and carboxyl functions; B) at least one amino-functional anionic or potentially anionic hydrophilic agent; and C) at least one amino-functional compound having a number average molecular weight of 32 g/mol to 400 g/mol and containing no hydrophilic group; wherein the ratio of the number average molecular weight of the A2a) to the number average molecular weight of the A2b) is 1:9 to less than 1:1, and the weight of the A3) amounts to 20% to 70% of the weight of the hydrophilic agents of the system, wherein the hydrophilic agents of the system are components A3 and B.