Free-standing non-fouling polymers and polymeric compositions, monomers and macromonomers for making the polymers and polymeric compositions, objects made from the polymers and polymeric compositions, and methods for making and using the polymers and polymeric compositions.

Free-standing non-fouling polymers and polymeric compositions, monomers and macromonomers for making the polymers and polymeric compositions, objects made from the polymers and polymeric compositions, and methods for making and using the polymers and polymeric compositions.

A gas barrier film formed of a cured product of a mixture including a polycarboxylic acid, a polyamine compound, and a polyvalent metal compound, in which in an infrared absorption spectrum of the gas barrier film, an area ratio of an amide bond represented by B/A is equal to or less than 0.380, an area ratio of a carboxylic acid represented by C/A is equal to or less than 0.150, and an area ratio of carboxylate represented by D/A is equal to or more than 0.520.

A gas barrier film formed of a cured product of a mixture including a polycarboxylic acid, a polyamine compound, and a polyvalent metal compound, in which in an infrared absorption spectrum of the gas barrier film, an area ratio of an amide bond represented by B/A is equal to or less than 0.380, an area ratio of a carboxylic acid represented by C/A is equal to or less than 0.150, and an area ratio of carboxylate represented by D/A is equal to or more than 0.520.

An anti-settling agent composition for aqueous coating materials, comprising [A] a polyamide which is obtained by polymerizing a diamine having 2-12 carbon atoms and an excess amount, relative to diamine, of either a dicarboxylic acid having 4-36 carbon atoms or a mixture of a dicarboxylic acid having 4-36 carbon atoms and a monocarboxylic acid having 2-22 carbon atoms, and [B] a hydrophobic organic compound which is a hydrocarbon modified with 1-3 hydroxyl groups and/or carboxyl groups and having 10-54 carbon atoms, and which has a freezing point of 20° C. or less or does not have a definite freezing point. The anti-settling agent is able to be easily dispersed in a coating material even if directly added into the coating material without being diluted when added into the coating material, and which imparts the coating material with excellent anti-settling properties.

An anti-settling agent composition for aqueous coating materials, comprising [A] a polyamide which is obtained by polymerizing a diamine having 2-12 carbon atoms and an excess amount, relative to diamine, of either a dicarboxylic acid having 4-36 carbon atoms or a mixture of a dicarboxylic acid having 4-36 carbon atoms and a monocarboxylic acid having 2-22 carbon atoms, and [B] a hydrophobic organic compound which is a hydrocarbon modified with 1-3 hydroxyl groups and/or carboxyl groups and having 10-54 carbon atoms, and which has a freezing point of 20° C. or less or does not have a definite freezing point. The anti-settling agent is able to be easily dispersed in a coating material even if directly added into the coating material without being diluted when added into the coating material, and which imparts the coating material with excellent anti-settling properties.

Free-standing non-fouling polymers and polymeric compositions, monomers and macromonomers for making the polymers and polymeric compositions, objects made from the polymers and polymeric compositions, and methods for making and using the polymers and polymeric compositions

Free-standing non-fouling polymers and polymeric compositions, monomers and macromonomers for making the polymers and polymeric compositions, objects made from the polymers and polymeric compositions, and methods for making and using the polymers and polymeric compositions

The invention is related to a cost-effective method for making a silicone hydrogel contact lens having a crosslinked hydrophilic coating thereon. A method of the invention involves heating a silicone hydrogel contact lens in an aqueous solution in the presence of a watersoluble, highly branched, thermally-crosslinkable hydrophilic polymeric material having positively-charged azetidinium groups, to and at a temperature from about 40° C. to about 140° C. for a period of time sufficient to covalently attach the thermally-crosslinkable hydrophilic polymeric material onto the surface of the silicone hydrogel contact lens through covalent linkages each formed between one azetidinium group and one of the reactive functional groups on and/or near the surface of the silicone hydrogel contact lens, thereby forming a crosslinked hydrophilic coating on the silicone hydrogel contact lens. Such method can be advantageously implemented directly in a sealed lens package during autoclave.

The invention is related to a cost-effective method for making a silicone hydrogel contact lens having a crosslinked hydrophilic coating thereon. A method of the invention involves heating a silicone hydrogel contact lens in an aqueous solution in the presence of a watersoluble, highly branched, thermally-crosslinkable hydrophilic polymeric material having positively-charged azetidinium groups, to and at a temperature from about 40° C. to about 140° C. for a period of time sufficient to covalently attach the thermally-crosslinkable hydrophilic polymeric material onto the surface of the silicone hydrogel contact lens through covalent linkages each formed between one azetidinium group and one of the reactive functional groups on and/or near the surface of the silicone hydrogel contact lens, thereby forming a crosslinked hydrophilic coating on the silicone hydrogel contact lens. Such method can be advantageously implemented directly in a sealed lens package during autoclave.