Provided are a resin composition for a tackifier or an adhesive and a preparation method thereof. Provided is a resin composition for a tackifier or an adhesive, which includes a hydrogenated petroleum resin with a controlled hydrogenation rate to have excellent compatibility with polyolefin and to exhibit high transparency while having improved quality including adhesive property.

The invention relates to a method for preparing hydrogenated petroleum resin. More specifically, the invention relates to a method for preparing hydrogenated petroleum resin having aromaticity of 10% or more and exhibiting excellent color and thermal stability, through a hydrogenation reaction in a slurry reactor, using a selective hydrogenation catalyst having excellent selectivity to olefinic double bonds in petroleum resin.

A UV-crosslinkable HMPSA composition comprises 10-24% by weight of a block copolymer comprising a styrenic block and a polybutadiene block comprising at least 25% by weight of the 1,2-vinyl unit; 43-65% by weight of a tackifying resin obtained by polymerization, then complete or partial hydrogenation of a C9 fraction, having a softening point of 80-150° C.; 10-25% by weight of a petroleum-derived hydrocarbon oil; and an appropriate amount of a photoinitiator (D). A self-adhesive article comprises a carrier layer (b) coated with a self-adhesive layer (a) comprising the HMPSA composition in the crosslinked state.

A UV-crosslinkable HMPSA composition comprises 10-24% by weight of a block copolymer comprising a styrenic block and a polybutadiene block comprising at least 25% by weight of the 1,2-vinyl unit; 43-65% by weight of a tackifying resin obtained by polymerization, then complete or partial hydrogenation of a C9 fraction, having a softening point of 80-150° C.; 10-25% by weight of a petroleum-derived hydrocarbon oil; and an appropriate amount of a photoinitiator (D). A self-adhesive article comprises a carrier layer (b) coated with a self-adhesive layer (a) comprising the HMPSA composition in the crosslinked state.

A hot melt adhesive composition contains a 1-butene homopolymer, an ethylene-based polymer having a melting point of lower than 80° C., an α-olefin copolymer having a melting point 80° C. or higher, a tackifying resin, wax, and a liquid softener, in which the ethylene-based polymer includes at least one type of copolymer selected from the group consisting of an ethylene-α-olefin copolymer and an ethylene-vinyl acetate copolymer.

A hot melt adhesive composition contains a 1-butene homopolymer, an ethylene-based polymer having a melting point of lower than 80° C., an α-olefin copolymer having a melting point 80° C. or higher, a tackifying resin, wax, and a liquid softener, in which the ethylene-based polymer includes at least one type of copolymer selected from the group consisting of an ethylene-α-olefin copolymer and an ethylene-vinyl acetate copolymer.

The invention relates to a method for producing a hydrocarbon resin, in which method a monomer mixture which contains an aromatic component containing indene and/or C.sub.1-4 alkylindene and a cyclic diolefin component containing a cyclic diolefin compound is polymerized by heating to a polymerization temperature of at least 180° C. to obtain a product stream containing hydrocarbon resin, wherein oligomers which contain units originating from the cyclic diolefin compound and/or units originating from the aromatic component are separated from the product stream and returned to the monomer mixture, and wherein the hydrocarbon resin is heated in an annealing step to a temperature of 150° C. to 300° C. for a period of 15 minutes to 240 hours. The invention also relates to a hydrocarbon resin that is obtainable by the method, to a hydrogenated hydrocarbon resin, and to the use of the hydrocarbon resin and the hydrogenated hydrocarbon resin.

The invention relates to a method for producing a hydrocarbon resin, in which method a monomer mixture which contains an aromatic component containing indene and/or C.sub.1-4 alkylindene and a cyclic diolefin component containing a cyclic diolefin compound is polymerized by heating to a polymerization temperature of at least 180° C. to obtain a product stream containing hydrocarbon resin, wherein oligomers which contain units originating from the cyclic diolefin compound and/or units originating from the aromatic component are separated from the product stream and returned to the monomer mixture, and wherein the hydrocarbon resin is heated in an annealing step to a temperature of 150° C. to 300° C. for a period of 15 minutes to 240 hours. The invention also relates to a hydrocarbon resin that is obtainable by the method, to a hydrogenated hydrocarbon resin, and to the use of the hydrocarbon resin and the hydrogenated hydrocarbon resin.

A hot melt adhesive for use on porous substrates, wherein the hot melt adhesive has about 10% to about 70% by weight of a polypropylene homopolymer having a DSC melting point of less than 100° C.; about 10% to about 60% of a first tackifying resin having a Ring & Ball Softening Point of about 95° C. to about 140° C.; about 0% to about 65% of a second tackifying resin that is different than the first tackifying resin; about 5% to about 50% of a plasticizer; about 1% to about 40% by weight of a secondary polymer which is either a semi crystalline polymer or wax with an enthalpy of fusion of greater than 30 Joules/gram; about 0.1% to about 5% of a stabilizer or antioxidant; wherein the components total 100% by weight of the composition, and the viscosity of the composition is equal to or less than about 20,000 centipoise (cP) at 163° C. (325° F.).

A hot melt adhesive for use on porous substrates, wherein the hot melt adhesive has about 10% to about 70% by weight of a polypropylene homopolymer having a DSC melting point of less than 100° C.; about 10% to about 60% of a first tackifying resin having a Ring & Ball Softening Point of about 95° C. to about 140° C.; about 0% to about 65% of a second tackifying resin that is different than the first tackifying resin; about 5% to about 50% of a plasticizer; about 1% to about 40% by weight of a secondary polymer which is either a semi crystalline polymer or wax with an enthalpy of fusion of greater than 30 Joules/gram; about 0.1% to about 5% of a stabilizer or antioxidant; wherein the components total 100% by weight of the composition, and the viscosity of the composition is equal to or less than about 20,000 centipoise (cP) at 163° C. (325° F.).